• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.1
• /
• pp.38.3-38.3
• /
• 2019

We investigate the stellar population properties of nine passive spiral galaxies in the CALIFA survey. They have NUV-r > 5 and no/weak nebular emission lines in their spectra. They lie in the redshift range of 0.001 < z < 0.021 and have stellar mass range of 10.2 < ${\log}(M{\star}/M{\odot})$ < 10.8. We analyze the stellar populations out to two effective radius, using the best-fitting model to the measured absorption line-strength indices in the Lick/IDS system. We compare the passive spirals with S0s selected in the same mass range. S0s cover a wide range in age, metallicity, and [${\alpha}/Fe$], and stellar populations of the passive spirals are encompassed in the spread of the S0 properties. However, the distribution of passive spirals are skewed toward higher values of metallicity, lower [${\alpha}/Fe$], and younger ages at all radii. These results show that passive spirals are possibly related to S0s in their stellar populations. We infer that the diversity in the stellar populations of S0s may result from different evolutionary pathways of S0 formation, and passive spirals may be one of the possible channels.

• Journal of Powder Materials
• /
• v.27 no.6
• /
• pp.477-483
• /
• 2020

Metal-organic frameworks (MOFs) are of significant interest because of their high porosity, which facilitates their utilization in gas storage and catalysis. To enhance their current properties in these applications, it is necessary to elucidate the interactions between molecules in a confined environment that differ from those in bulk conditions. Herein, we study the confined molecular interaction by investigating the solvent-dependent photophysical properties of two different-sized molecules inside MOF-5. Ruthenium tris-bipyridine (Rubpy) and coumarin 153 (C153) are encapsulated in MOF-5. Rubpy with MOF-5 (Rubpy@MOF) is prepared by building MOF-5 around it, resulting in limited space for solvent molecules in the pores. The smaller C153 is encapsulated in the preformed MOF-5 (C153@MOF) by simply soaking the MOF in a concentrated C153 solution. C153@MOF permits more space for solvent molecules in the pore. Their characteristic absorption and emission spectra are examined to elucidate the confined molecular interactions. Rubpy@MOF and C153@MOF exhibit different spectral shifts compared to the guest molecules under bulk conditions. This discrepancy is attributed to the different micro-environments inside the pores, derived from confined host-guest interactions in the interplay of solvent molecules.

• Food Science of Animal Resources
• /
• v.42 no.4
• /
• pp.672-688
• /
• 2022

The objective of this study was to explore the potential of front face fluorescence spectroscopy (FFFS) as rapid, non-destructive and inclusive technique along with multi-variate analysis for predicting meat adulteration. For this purpose (FFFS) was used to discriminate pure minced beef meat and adulterated minced beef meat containing (1%, 2%, 3%, 4%, 5%, 10%, 20%, 30%, 40%, 50%, 60%, 70%, 80%, 90%, and 100%) of chicken meat as an adulterant in uncooked beef meat samples. Fixed excitation (290 nm, 322 nm, and 340 nm) and fixed emission (410 nm) wavelengths were used for performing analysis. Fluorescence spectra were acquired from pure and adulterated meat samples to differentiate pure and binary mixtures of meat samples. Principle component analysis, partial least square regression and hierarchical cluster analysis were used as chemometric tools to find out the information from spectral data. These chemometric tools predict adulteration in minced beef meat up to 10% chicken meat but are not good in distinguishing adulteration level from 1% to 5%. The results of this research provide baseline for future work for generating spectral libraries using larger datasets for on-line detection of meat authenticity by using fluorescence spectroscopy.

• Journal of the Korean Vacuum Society
• /
• v.7 no.s1
• /
• pp.106-117
• /
• 1998

Fluorocarbonated-SiO2 films were deposited on p-type Si(100) substrate using FSi$(OC_2H_5)_3$ (FTES), and $O_2$ mixture gases by a helicon plasms source. High density $O_2$/FTES/Ar plasma of ~$10^{12} \textrm{cm}^{-3}$ is obtained at low pressure (<3mTorr) with RF power above 900 W in the helicon plasma source. Optical emission spectroscopy (OES) is used to study the relation between the relative densities of the radicals and the film properties. The FTES and $O_2$ gases are greatly dissociated at the helicon mode that is launched at the above threshold plasma density. FTIR and XPS spectra shows that the film has Si-F, and C-F bonds during the formation process of the film which may lower the dielectric constant greatly. The relative dielectric constant, leakage current density, and dielectric breakdown voltage are about 2.8, $8\times10^{-9}\textrm{A/cm}^2$, and > 12 MV/cm, respectively.

• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.2
• /
• pp.73.3-73.3
• /
• 2019

The AGN unification model suggested the presence of obscuring material, a dusty torus, to explain the various types of AGN. IR SED model fitting is a crucial tool to probe the structure and properties of the dusty torus. We use a sample of 16 local quasi-stellar objects in Martinez-Paredes et al. (2017) with obtained NIR and MIR high-angular resolution (~0.3") imaging data from EMIR, CIRCE and CanariCam on the 10.4-m Gran Telescopio CANARIAS (GTC) while 4 objects have NIR high-angular resolution photometry from NICMOS/HST from the literature. The unresolved NIR emission from the NIR image analysis and low-resolution Spitzer/IRS spectra are used to construct NIR-MIR SEDs covering a larger spectral range. We investigate the sensitivity of the geometrical (e.g. viewing angle) and physical parameters (e.g. optical depth) of the clumpy dusty torus model of Nenkova et al. and the clumpy disk+outflow model of Hoenig et al. We aim to investigate the minimal dataset needed to well constrain the parameters of the models and derive the properties of the dusty torus. These results will allow us to plan future observations for a larger sample of high luminosity AGNs with the James Webb Space Telescope and the Giant Magellan Telescope.

• The Bulletin of The Korean Astronomical Society
• /
• v.44 no.2
• /
• pp.36.3-36.3
• /
• 2019

We present a multiwavelength study of an ultraluminous X-ray source (ULX) in NGC 5252, which is known as a candidate for an intermediate-mass black hole. The ULX, located 22 arcsec away from the center of NGC 5252, was first discovered with the Chandra X-Ray Observatory. In the optical spectra, the strong narrow emission lines are found at the position of the ULX. It reveals that the ULX is likely associated with NGC 5252. The VLBA data of the ULX yields that the black hole mass of the ULX is smaller than 106 solar mass, inferred from the black hole fundamental plane. From the near-infrared imaging data, we find that the stellar mass associated with the ULX is smaller than ~107.9 solar mass, implying that the ULX can be a remnant of a merging dwarf. We also find that K-band luminosity of the ULX is two orders of magnitude smaller than typical active galactic nuclei at a given [OIII] luminosity. It may suggest the ULX lacks the dusty torus possibly due to the disappearance of dusty material during the recoiling process.

• Advances in nano research
• /
• v.14 no.6
• /
• pp.557-573
• /
• 2023

The rapid growth of zinc-oxide (ZnO) nanostructures (NSs) on woven carbon fiber (WCF) is reported in this study employing a microwave-aided chemical bath deposition process. The effects of different process parameters such as molar concentration, microwave duration and microwave power on morphologies and growth rate of the ZnO on WCF were studied. Furthermore, an attempt has been taken to study influence of different type of growth solutions on ZnO morphologies and growth rates. The surface functionalization of WCF fabrics is achieved by successful growth of crystalline ZnO on fiber surface in a very short duration through one-step microwave synthesis. The morphological, structural and compositional studies of ZnO-modified WCF are evaluated using field-emission scanning electron microscopy, X-ray diffraction and energy dispersive X-ray spectroscopy respectively. Good amount of zinc and oxygen has been seen in the surface of WCF. The presence of the wurtzite phase of ZnO having crystallite size 30-40 nm calculated using the Debye Scherrer method enhances the surface characteristics of WCF fabrics. The UV-VIS spectroscopy is used to investigate optical properties of ZnO-modified WCF samples by absorbance, transmittance and reflectance spectra. The variation of different parameters such as dielectric constants, optical conductivity, refractive index and extinction coefficient are examined that revealed the enhancement of optical characteristics of carbon fiber for wide applications in optoelectronic devices, carbon fiber composites and photonics.

• Korean Journal of Materials Research
• /
• v.20 no.5
• /
• pp.262-266
• /
• 2010

ZnO nanostructures were grown on an Au seed layer by a hydrothermal method. The Au seed layer was deposited by ion sputter on a Si (100) substrate, and then the ZnO nanostructures were grown with different precursor concentrations ranging from 0.01 M to 0.3M at $150^{\circ}C$ and different growth temperatures ranging from $100^{\circ}C$ to $250^{\circ}C$ with 0.3 M of precursor concentration. FE-SEM (field-emission scanning electron microscopy), XRD (X-ray diffraction), and PL (photoluminescence) were carried out to investigate the structural and optical properties of the ZnO nanostructures. The different morphologies are shown with different growth conditions by FE-SEM images. The density of the ZnO nanostructures changed significantly as the growth conditions changed. The density increased as the precursor concentration increased. The ZnO nanostructures are barely grown at $100^{\circ}C$ and the ZnO nanostructure grown at $150^{\circ}C$ has the highest density. The XRD pattern shows the ZnO (100), ZnO (002), ZnO (101) peaks, which indicated the ZnO structure has a wurtzite structure. The higher intensity and lower FWHM (full width at half maximum) of the ZnO peaks were observed at a growth temperature of $150^{\circ}C$, which indicated higher crystal quality. A near band edge emission (NBE) and a deep level emission (DLE) were observed at the PL spectra and the intensity of the DLE increased as the density of the ZnO nanostructures increased.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
• /
• v.9 no.1
• /
• pp.1022-1025
• /
• 2005

The effect of substrate surface to the formation of ZnO nanostructures has been investigated using Si (111), $Al_2O_3$(C-plane) $Al_2O_3$(A-plane), and $Al_2O_3$(R-plane) substrates. The growth temperature was controlled from 500$^{\circ}C$ ${\sim}$ 600$^{\circ}C$, and the luminescence properties were investigated by a series of photoluminescence (PL) measurements at the elevating temperatures. ZnO nanostructures grown on Si substrate show strong UV emission intensity along with green emission positioned at 3.22 eV and 2.5 eV, respectively. However, green emission was not observed from the ZnO nanostructures grown on $Al_2O_3$ substrates. It is explained in terms of the difference of the surface energy between Si and $Al_2O_3$. Also, the origin of UV emissions has been discussed by using the temperature-dependent PL. The distinction of the PL spectra is interpreted in terms of the difference of the impurity included in the nanostructures.

• Journal of the Korean Society of Radiology
• /
• v.13 no.4
• /
• pp.645-652
• /
• 2019

Phosphor with phosphorus doped with rare earth ions was investigated by searching Sr and Eu phosphors suitable for substitution of Eu ions with similar ionic radius to polyphosphate host. The $NaSr(PO_3)_3$ phosphor was synthesized by the solid state method and the $NaSr(PO_3)_3:Eu^{2+}$ phosphor was prepared by the carbon thermal reduction method. Both of the phosphors were identified by X - ray diffraction. The excitation and emission spectra of $NaSr(PO_3)_3:Eu^{3+}$ increased fluorescence intensity and intensity quenching with increasing $Eu^{3+}$ concentration. The higher the $Eu^{3+}$ concentration in the emission spectrum, the higher the local symmetry of $Eu^{3+}$ environment. The mechanism of concentration quenching, in which fluorescence decreases due to the energy transfer between $Eu^{2+}$ ions with the closest critical distance between $Eu^{2+}$ ions with increasing $Eu^{2+}$ ion concentration, was confirmed in the emission spectrum of $NaSr(PO_3)_3:Eu^{2+}$ concentration. It is possible to change the fluorescent region through the post-processing of single rare earth ion added phosphors, and it is possible to change the fluorescence by applying the energy transfer and concentration quenching mechanism according to the local symmetry of $Eu^{3+}$ will be used for high phosphor development.