• Title/Summary/Keyword: Emission Control Area

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Enhanced Field Emission Behavior from Boron-Doped Double-walled Carbon Nanotubes Synthesized by Catalytic Chemical Vapor Deposition

  • Kang, J.H.;Jang, H.C.;Choi, J.M.;Lyu, S.C.;Sok, J.H.
    • Journal of Magnetics
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    • v.17 no.1
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    • pp.9-12
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    • 2012
  • Attempts to dope carbon nanotube (CNT) with impurities in order to control the electronic properties of the CNT is a natural course of action. Boron is known to improve both the structural and electronic properties. In this report, we study the field emission properties of Boron-doped double-walled CNT (DWCNT). Boron-doped DWCNT films were fabricated by catalytic decomposition of tetrahydrofuran and triisopropyl borate over a Fe-Mo/MgO catalyst at $900^{\circ}C$. We measured the field emission current by varying the doping amount of Boron from 0.8 to 1.8 wt%. As the amount of doped boron in the DWCNT increases, the turn-on-field of the DWCNT decreases drastically from 6 V/${\mu}m$ to 2 V/${\mu}m$. The current density of undoped CNT is 0.6 mA/$cm^2$ at 9 V, but a doped-DWCNT sample with 1.8 wt% achieved the same current density only at only 3.8 V. This shows that boron doped DWCNTs are potentially useful in low voltage operative field emitting device such as large area flat panel displays.

Analysis of the Emission Benefits of Using Alternative Maritime Power (AMP) for Ships

  • Kim, Kyunghwa;Roh, Gilltae;Chun, Kangwoo
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.3
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    • pp.381-394
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    • 2019
  • The marine industry contributes a large proportion of the air pollutant emissions along coastal regions, and this air pollution has been strongly linked to cardiovascular diseases and other illnesses. To alleviate the problem, many ports have installed alternative maritime power (AMP) facilities that enable onboard marine auxiliary engines with generators (gensets) to be shut down while a ship is at berth. This study compared the emissions from conventional gensets with those from AMP facilities, focusing on four emission types: greenhouse gases (GHG), sulphur oxides (SOX), nitrogen oxides (NOX), and particulate matter (PM). Both direct (combustion / operation) and indirect (upstream) emissions were considered together for the emission comparison. The results showed that AMP has lower emissions than conventional onboard gensets, and this benefit is highly dependent on the electricity generation mix onshore. On average, GHG emissions could be reduced by about 18.3 %, while the other emissions (SOX, NOX, and PM) would decrease more dramatically (88.4 %, 90.1 %, and 91.5 %, respectively). Additionally, future benefits of the AMP would increase due to the expansion of renewable energies. Thus, this study supports the potential of AMP as a promising solution for environmental concerns at ports worldwide.

Carbon nanotube field emission display

  • Chil, Won-Bong;Kim, Jong-Min
    • Electrical & Electronic Materials
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    • v.12 no.7
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    • pp.7-11
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    • 1999
  • Fully sealed field emission display in size of 4.5 inch has been fabricated using single-wall carbon nanotubes-organic vehicle com-posite. The fabricated display were fully scalable at low temperature below 415$^{\circ}C$ and CNTs were vertically aligned using paste squeeze and surface rubbing techniques. The turn-on fields of 1V/${\mu}{\textrm}{m}$ and field emis-sion current of 1.5mA at 3V/${\mu}{\textrm}{m}$ (J=90${\mu}{\textrm}{m}$/$\textrm{cm}^2$)were observed. Brightness of 1800cd/$m^2$ at 3.7V/${\mu}{\textrm}{m}$ was observed on the entire area of 4.5-inch panel from the green phosphor-ITO glass. The fluctuation of the current was found to be about 7% over a 4.5-inch cath-ode area. This reliable result enables us to produce large area full-color flat panel dis-play in the near future. Carbon nanotubes (CNTs) have attracted much attention because of their unique elec-trical properties and their potential applica-tions [1, 2]. Large aspect ratio of CNTs together with high chemical stability. ther-mal conductivity, and high mechanical strength are advantageous for applications to the field emitter [3]. Several results have been reported on the field emissions from multi-walled nanotubes (MWNTs) and single-walled nanotubes (SWNTs) grown from arc discharge [4, 5]. De Heer et al. have reported the field emission from nan-otubes aligned by the suspension-filtering method. This approach is too difficult to be fully adopted in integration process. Recently, there have been efforts to make applications to field emission devices using nanotubes. Saito et al. demonstrated a car-bon nanotube-based lamp, which was oper-ated at high voltage (10KV) [8]. Aproto-type diode structure was tested by the size of 100mm $\times$ 10mm in vacuum chamber [9]. the difficulties arise from the arrangement of vertically aligned nanotubes after the growth. Recently vertically aligned carbon nanotubes have been synthesized using plasma-enhanced chemical vapor deposition(CVD) [6, 7]. Yet, control of a large area synthesis is still not easily accessible with such approaches. Here we report integra-tion processes of fully sealed 4.5-inch CNT-field emission displays (FEDs). Low turn-on voltage with high brightness, and stabili-ty clearly demonstrate the potential applica-bility of carbon nanotubes to full color dis-plays in near future. For flat panel display in a large area, car-bon nanotubes-based field emitters were fabricated by using nanotubes-organic vehi-cles. The purified SWNTs, which were syn-thesized by dc arc discharge, were dispersed in iso propyl alcohol, and then mixed with on organic binder. The paste of well-dis-persed carbon nanotubes was squeezed onto the metal-patterned sodalime glass throuhg the metal mesh of 20${\mu}{\textrm}{m}$ in size and subse-quently heat-treated in order to remove the organic binder. The insulating spacers in thickness of 200${\mu}{\textrm}{m}$ are inserted between the lower and upper glasses. The Y\ulcornerO\ulcornerS:Eu, ZnS:Cu, Al, and ZnS:Ag, Cl, phosphors are electrically deposited on the upper glass for red, green, and blue colors, respectively. The typical sizes of each phosphor are 2~3 micron. The assembled structure was sealed in an atmosphere of highly purified Ar gas by means of a glass frit. The display plate was evacuated down to the pressure level of 1$\times$10\ulcorner Torr. Three non-evaporable getters of Ti-Zr-V-Fe were activated during the final heat-exhausting procedure. Finally, the active area of 4.5-inch panel with fully sealed carbon nanotubes was pro-duced. Emission currents were character-ized by the DC-mode and pulse-modulating mode at the voltage up to 800 volts. The brightness of field emission was measured by the Luminance calorimeter (BM-7, Topcon).

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Design Standard of Activated Carbon Vessel for the Intermittent Emission Sources of Volatile Organic Compounds (휘발성 유기화합물의 간헐적 배출원에 대한 활성탄 흡착 시스템 설계기준)

  • Lee, Si-Hyun;Lim, Jeong-Whan;Rhim, Young-Jun;Kim, Sang-Do;Woo, Kwang-Je;Son, Mi-Sook;Park, Hee-Jae;Seo, Man-Cheol;Ryu, Seung-Kon
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.2
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    • pp.250-260
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    • 2007
  • It was investigated that the emission characteristics of volatile organic compounds (VOCs) from small and medium companies located on industrial complexes in Metropolitan area. The emission characteristics are intermittent sources in which VOCs emissions are highly depends on the working condition. Optimized ventilation system to improve air quality in working area for the three typical companies were installed. Adsorption characteristics of major VOCs such as MEK, IPA, and toluene emitted front the companies were investigated for design of the activated carbon vessel as a VOCs control facility in each company. Concentration of total hydrocarbon and gas amounts needed to ventilation were also used as a design parameter. Mixed adsorbent to improve adsorption characteristics of problematic solvents like IPA and the design guideline of the activated carbon vessel have been suggested.

Ozone Simulations over the Seoul Metropolitan Area for a 2007 June Episode, Part I: Evaluating Volatile Organic Compounds Emissions Speciated for the SAPRC99 Chemical Mechanism (2007년 6월 수도권 오존모사 I - 광화학측정자료를 이용한 SAPRC99 화학종별 휘발성유기물질 배출량 입력자료 평가)

  • Kim, Soon-Tae
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.5
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    • pp.580-602
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    • 2011
  • Volatile organic compound (VOC) emissions in the 2007 CAPSS (Clean Air Protection Supporting System) emissions inventory are chemically speciated for the SAPRC99 (Statewide Air Pollution Research Center 99) mechanism, following the Source Classification Code (SCC) matching method to borrow the U.S.EPA's chemical speciation profiles. CMAQ simulations with High-order Direct Decoupled Method (HDDM) are in turn applied to evaluate uncertainty in the method by comparing the simulated model VOC species to the observations in the Seoul Metropolitan Area (SMA) for a 2007 June episode. Simulations under-predicted ALK1 to ALK4 in SAPRC99 by a factor of 2 to 5 and over-predicted ALK5 by a factor of 7.5 while ARO1, ARO2, OLE1, and ethylene (ETH) are comparable to the observations, showing relative difference by 10 to 30%. OLE2 emissions are roughly 4 times overestimated. Emission rates for individual VOC model species are revised referring to the ratio of simulated to observed concentrations. Impact of the VOC emission changes on the overall ozone prediction was insignificant for the days of which 1-hr maximum ozone are lower than 100 ppb. However, simulations showed ozone difference by 5 to 10 ppb when high ozone above 120 ppb was observed in the vicinity of Seoul. This result suggests that evaluations on individual model VOC emissions be necessary to lead ozone control plans to the right direction. Moreover, the simulated ratios of ARO1 and ARO2 to $NO_x$ are roughly 50% lower than the observed ones, which imply that adjustment in $NO_x$ and VOC emission rates may be required to mimic the real VOC/$NO_x$ condition over the area.

Study on characteristics of SCC and AE signals for the weld HAZ of HT-60 steel under corrosion control (부식제어하에서 HT-60강 용접부의 SCC 및 AE 신호 특성에 관한 연구)

  • 나의균;고승기
    • Proceedings of the KWS Conference
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    • 1999.05a
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    • pp.241-244
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    • 1999
  • The purpose of this study is to examine the characteristics of stress corrosion cracking(SCC) and acoustic emission(AE) signals for the weld HAZ of HT-60 steel under corrosion control in synthetic seawater. Corrosive environment was controlled by potentiostat, and SCC experiment was conducted using a slow strain rate test method at strain rate of 10$^{-5}$ /sec. In order to verify the miroscopic fracture behaviour of the weldment during SCC phenomena, AE test was done simultaneously. Besides, correlationship between mechanical parameters and AE ones was investigated. In case of the parent, reduction of area(ROA) at -0.5V was samller than any other applied voltage such as -0.8V and -1.1V. In addition, reduction of area for the PWHT specimens at -0.8mV was larger than that of the weldment due to the softening effect according to PWHT. In case of the weldment, a lots of events was produced because of the singularities of the weld HAZ compared with the parent.

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Relationship between PM10 and O3 concentration and allergy symptoms among residents in the Gwangyang area (광양지역의 PM10, O3농도와 거주자의 알레르기 증상과의 연관성)

  • Oh, Yujin;Choi, Jihee;Park, Heejin;Kim, Taejong;Kim, Geun-Bae;Son, Bu-Soon
    • Journal of odor and indoor environment
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    • v.16 no.3
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    • pp.277-286
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    • 2017
  • The objectives of this study were to investigate the effects of $PM_{10}$ and $O_3$ concentration on the symptoms of allergic diseases. The questionnaire was used to determine whether or not symptoms of allergic diseases were present from September to October 2012. The air pollution concentration data used was the corresponding point CEM (continuous emission monitoring) data. The average concentration of $PM_{10}$ was $56.09{\mu}g/m^3$ in the control area, and the concentration in the exposed area was $40.44{\mu}g/m^3$. In the two areas, concentration of $O_3$ was 28.73 ppb and 28.74 ppb, respectively. The total average concentrations of $PM_{10}$ and $O_3$ were $45.66{\mu}g/m^3$ and 28.73 ppb in the Gwangyang area. The rate of asthma diagnosis was higher in the control area (9.6%) than in the exposed area (4.1%), but the rate of allergy eye disease was higher in the exposed area (23.9%) than in the control area (16.5%). There was a significant difference in the symptoms of some allergic diseases when the relative concentration of $PM_{10}$ and $O_3$ were high and low.

Implementation of a CAN Based Real-Time Simulator for FCHEV (하이브리드 연료전지 자동차의 CAN기반 실시간 시뮬레이터 구현)

  • Shim, Seong-Yong;Lee, Nam-Su;Ahn, Hyun-Sik;Kim, Do-Hyun
    • Proceedings of the KIEE Conference
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    • 2004.11c
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    • pp.410-413
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    • 2004
  • In this paper, a simulator system for Fuel Cell Hybrid Electric Vehicles(FCHEV) is implemented using DSP boards with CAN bus. The subsystems of a FCHEV i.e., the fuel cell system, the battery system, the vehicle dynamics with the transmission mechanism are coded into 3 DSP boards. The power distribution control algorithm and battery SOC control are also coded into a DSP board. The real-time monitoring program is also developed to examine the control performance of power control and SOC control algorithms.

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Analyzing the Impact of Emission Control Area (ECA) Enforcement on Ferry Companies' Financial Performance : Network SBM DEA and BTR model (배출규제해역(ECA) 시행이 페리 선사의 재무성과에 미치는 영향: Network SBM DEA 및 BTR 모형 분석)

  • Lee, Suhyung;Lim, Hyunwoo
    • Journal of Korea Port Economic Association
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    • v.38 no.3
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    • pp.29-51
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    • 2022
  • The International Maritime Organization (IMO) designated the Emission Control Area (ECA) in Northern Europe to reduce the NOx and SOx emissions from ships in the coastal areas. This study used Network slack-based measure (SBM) Data Envelopment Model (DEM) and Bootstrop Truncated Regression (BTR) model to analyze the ECA's impact on ferry companies' financial performances based on the financial data from eight ferry carriers in Northern Europe, the Mediterranean and North America from 2004 to 2017. To alleviate the problem of arbitrary variable selection in DEA, the variable selection criteria proposed by Dyson et al. (2001) were applied; the size of the company was considered through the Network SBM DEA model; and the company's profit-generating process was divided into stages to measure financial performance in more detail. In addition, the BTR model was applied to derive results that minimize the bias of the data. The study found that ECA regulations did not always negatively affect the shipping companies' financial performance. Rather, a steady increase in efficiency was observed for Northern European ferry companies which were subject to the strongest regulations. For North American ferry companies, government subsidies were found to have a significant impact on efficiency, and relatively small impact on efficiency due to the ECA and oil prices. For the Mediterranean ferry companies, efficiency values have decreased since the implementation of ECA regulation despite the lowest level of regulation in the region.

Development of Nitrogen Cooling Equipment for Personalized Local Area (개인 맞춤형 국소부위 질소 냉각 장비 개발)

  • Lee, Young-Ji;Lee, Joo-Hyun;Lee, Seung-Ho
    • Journal of IKEEE
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    • v.24 no.3
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    • pp.913-916
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    • 2020
  • In this paper, we propose the development of nitrogen cooling equipment for personalized local area. The proposed equipment consists of a cold air supply module, a body, and nitrogen injection with the following characteristics. First, it automatically controls the amount and time of cold air supply by utilizing information measuring skin temperature with volumetric temperature sensors, so it can have a competitive edge in function by ensuring complete safety. Second, if the distance measuring sensor is applied to the skin for more than a certain distance, it can block the cold air or control the discharge of nitrogen in conjunction with the control GUI to improve the efficiency of higher cooling therapy while providing safe management. Third, by installing a control module that can control the supply of nitrogen, the cost of maintenance can be minimized by minimizing the loss of nitrogen. Experiments at an external testing agency to evaluate the performance of the proposed equipment showed that the accuracy of the temperature sensor was measured in the range of ±3.8%, which is lower than the world's highest level(±5%), with a range of 110℃ to -160℃ similar to the world's highest level. Distance accuracy was measured in the range of ±3.0%, lower than the world's highest level(±5%), and weight accuracy in the range of ±0.1%, lower than the world's highest level(±5%). In addition, emission control was measured in four stages, higher than the world's highest level(stage 1) and nitrogen use was measured at 0.8L/min below the world's highest(6L/min). Therefore, the effectiveness of the methods proposed in this paper was demonstrated because they produced the same results as the world's highest levels.