• Title/Summary/Keyword: Electronic conductivity

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Fabrication and Characterization of LIPON Electrolyte Thin Film for All Solid State Thin Film Battery (박막전지용 LIPON 전해질 박막의 제조 및 특성 평가)

  • 손봉희;전은정;남상철;조원일;윤영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.228-231
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    • 1999
  • The preparation and electrical properties of LIPON electrolyte were investigated in order to fabricate all solid state thin film battery. The LIPON thin film was deposited by r.f. sputtering of Li$_3$PO$_4$ target in O$_2$-N$_2$ mixtures. The LIPON deposited at N$_2$+10% O$_2$ ratio had a conductivity at 25 $^{\circ}C$ of 1.8${\times}$10$\^$-6/S/cm. The ion conductivity of the LIPON films decreased as the O$_2$ content of the process gas increased.

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The Change of Contamination Performance of Polymeric Insulators for Outdoor Use (Salt fog 내에서 옥외용 고분자 절연물의 내오손 성능 변화)

  • 김정호;문중섭;박용판;김동명;원호상
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.505-508
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    • 1999
  • In this study, weight loss, ESDD, surface conductivity and leakage current were measured at the different saline solutions by salt fog method. The magnitude of leakage current was higher at higher conductivity of 2 S/m saline water, but weight loss ESDD and surface conductivity which are indices of degradation were lower. This is considered that the current includes mainly ohmic component which doesn\`t contribute to surface degradation. In addition, it is shown that FFT could be useful in measuring initial transition from hydrophobic to hydrophilic surface.

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Electrical Conductivity and Optical Properties of Elongated Conducting Polymer (연신도전성고분자의 전기전도와 광학적 특성)

  • 박대희;강성화;임기조
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.59-62
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    • 1994
  • Tact Electrical conductivity. optical absorption spectra of poly(p-phenylene vinylene) and their dependence on stretching are discussed in detail. The conductivity in the parallel direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching is higher over one order in magnitude than that in the perpendicular direction to the stretching. The photocurrent spectrum for the ligh polarized parallel to the chain direction is much enhanced in lower photon energy compared with that for the light polarized perpendicular to that direction. The result may be originated in the difference of energies which is needed to photogenerate carriers wi th the light polarized parallel and perpendicular to the chain stretched direction.

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Surface Structure and Electrical Properties of Polyurethane LB Monolayers (폴리우레탄 LB단분자막의 표면구조 이미지와 전기적 특성)

  • 서정열;김도균;정상범;유승엽;신훈규;박재철;권영수
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.320-323
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    • 2000
  • We attempted to fabricate polyurethane derivatives (PU-CN, PU-DCM) LB films by using LB method. Also, we investigated the monolayer behavior at the air-water interface by surface pressure-area ($\pi$-A) isotherms. And, the surface morphologies and the physicochemical properties of LB films were investigated by atomic force microscopy (AFM) and UV-vis spectroscopy, respectively. Also, the electrical properties of polyurethane derivatives LB films were investigated by using the conductivity and the dielectric constant. In the AFM images, we conclude that surface morphology of PU-DCM LB films is smooth and homogeneous and has optimal hydrophobicity and good stability, whereas PU-CN LB films give rougher surfaces with more excess material. In the I-V characteristics, the conductivity is different as to the polyurethane derivatives, it is considered that this phenomena could be described by the difference of lumophore pendant which was adhered at PU main chain.

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Electrical Conductivity Characteristics of DNA by Relative Humidity (습도 변화에 따른 DNA의 전도 특성)

  • Lee, Jong-Hwan;Kim, Kyoung-Seob;Kim, Nam-Hoon;Roh, Yong-Han
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.101-102
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    • 2007
  • In order to characterize an electrical conductivity of ${\lambda}$-DNA by relative humidity, I-V characteristics through DNA on Au electrode with $1{\mu}m$ gap were measured as a function of the relative humidity. The electrical conductivity increased and the resistance decreased with an increase of humidity. The maximum effect of the humidity on the electrical property of DNA was obtained with the range from 43 to 82%. The hysteresis loop in I-V characteristics of DNA was disappeared above 92% of the humidity while the applying voltage was changed.

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Son Conduction Properties of PVDF/PAN based for Lithium Polymer Battery (리튬 폴리머전지용 PVDF/PAN계 전해질의 이온 전도 특성)

  • 이재안;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.374-377
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    • 1999
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PVDF/PAN electrolytes as a function of a mixed ratio. PVDF/PAN based polymer electrolyte films were prepared by thermal gellification method of preweighed PVDF/PAN, plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10-3S/cm. 20PVDF5PANLiCIO$_4$PC$\sub$10//EC$\sub$10/ electrolyte shows the better conductivity of the others. 20P7DF5PANLiCI$_4$PC$\sub$10//EC$\sub$10/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5ANLICIO$_4$/PC $\sub$10//EC$\sub$10/ electrolyte is 0.48

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Electrical Conductivity and Electromagnetic Interference Shielding Characteristics of Polyaniline Films with Adding Material (첨가물질에 따른 폴리아닐린 필름의 전기전도도 및 전자기파 차폐특성)

  • 김재욱
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.1
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    • pp.1-6
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    • 1998
  • Polyaniline free standing films are prepared by various processing. The properties of these films such as electrical conductivity and electromagnetic shielding efficiency are investigated. The conductivities of films doped with a camphorsulfonic acid and a silver are found to be 170/cm and 190S/cm, respectively, indicating metallic behavior. The films added silver, which are casted from hydrochloric acid and dodecylbenzensulfonic acid, show that the electromagnetic shielding efficiency are obtained 42∼52dB and 46∼56dB in the frequency range of 10MHz∼1GHz, respectively. This suggests that the films added silver, which is casted from dodecylbenzensulfonic acid, can be used as electromagnetic shielding material.

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Synthesis and Electrical Properties of Polypyrrole Nanotubules (Polypyrrole Nanotubules의 합성과 전기적 특성)

  • 조영재;김현철;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.544-547
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    • 2000
  • Polypyrrole (PPy) was chemically synthesized within the pores of nanoporous polycarbonate (PC) Particle Track-etched Membranes (nano-PTM). Hollow tubules are formed because polypyrrole initially deposits on the surface of the pores walls. By running successive syntheses, we have obtained wires (filled tubules). The redox property of PPy nanotubules was investigated by cyclic voltammetry. The redox potential was lowered as much as 0.5V vs. Ag/AgC1, comparing with electrosynthesized PPy film. It suggests that an electron hopping mechanism of PPy nanotubules was improved. Electric conductivity of PPy nanotubules and nanowire was evaluated. We obtained good electric conductivity of PPy nanotubules even in the neutral state. The conductivity and activation energy were $10^1$ order at the room temperature and 25.3 meV respectively.

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Proton Conductivity and Methanol Transport Behaviour of PVdF/SPEEK/$TiO_2$ Hybrid Membrane (PVdF/SPEEK/$TiO_2$ 하이브리드 막의 프로톤 전도도 및 메탄올 전이현상)

  • You, Sun-Kyung;Kalappa, Preshantha;Park, Soo-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.409-411
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxidenanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of inorganic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nation membrane.

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Capacity Change of Supercapacitor by Surface Treatment of Carbon Nanotubes (카본 나노튜브의 표면 처리에 의한 수퍼캐패시터 용량 변화)

  • Kim, Yong-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.6
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    • pp.532-536
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    • 2009
  • In this study, the capacity change of supercapacitor was investigated by surface treatments of carbon nanotubes as electrode materials with various methods, such as ball-milling, $KMnO_4$ and $H_2SO_4/HNO_3$ acid mixture. Surface treatments generated a number of defects on the surface of carbon nanotubes by attacking on $\pi$ bond in graphene layer, at which carboxyl groups were introduced. These hydrophilic groups could enhance the capacity by increasing the wettability of carbon nanotube surfaces. However, a drawback of the surface treatment was the decrease of conductivity by the loss of conduction path in graphene layer due to the defect formation. The surface treatment condition should be therefore optimized between hydrophilicity increase and conductivity decrease.