• 제목/요약/키워드: Electronic and thermal properties

검색결과 1,077건 처리시간 0.025초

Thermoelectric Properties of n-Type Half-Heusler Compounds Synthesized by the Induction Melting Method

  • Du, Nguyen Van;Lee, Soonil;Seo, Won-Seon;Dat, Nguyen Minh;Meang, Eun-Ji;Lim, Chang-Hyun;Rahman, Jamil Ur;Kim, Myong Ho
    • Transactions on Electrical and Electronic Materials
    • /
    • 제16권6호
    • /
    • pp.342-345
    • /
    • 2015
  • The n -type Hf0.25Zr0.25Ti0.5NiSn0.998Sb0.002 Half-Heusler (HH) alloy composition was prepared by using the induction melting method in addition to the mechanical grinding, annealing, and spark plasma sintering processes. Analysis of X-ray diffraction (XRD) results indicated the formation of a pure phase HH structured compound. The electrical and thermal properties at temperatures ranging from room temperature to 718 K were investigated. The electrical conductivity increased with increasing temperatures and demonstrated nondegenerate semiconducting behavior, and a large reduction in the thermal conductivity to the value of 2.5 W/mK at room temperature was observed. With the power factor and thermal conductivity, the dimensionless figure of merit was increased with temperature and measured at 0.94 at 718 K for the compound synthesized by the induction melting process.

열형센서용 니켈 산화막의 형성 및 특성분석 (Formation of Ni Oxide Thin Film and Analysis of Its Characteristics for Thermal Sensors)

  • 이응안;서정환;노상수
    • 한국전기전자재료학회논문지
    • /
    • 제18권2호
    • /
    • pp.169-173
    • /
    • 2005
  • Ni oxide thin films were formed through annealing treatment in the atmosphere after Ni thin films deposited by a r.f. magnetron sputtering method and then electric and material properties were analyzed for application to thermal sensors. Resistivity of Ni thin films decreased after annealing treatment at 30$0^{\circ}C$ and 40$0^{\circ}C$ for five hours due to crystallization of Ni thin films but the value increased over 45$0^{\circ}C$ because of Ni thin film's oxidation. Resistivity values of Ni thin films were in the range of 10.5 $\mu$Ωcm/$^{\circ}C$ to 2.84${\times}$10$^4$$\mu$Ωcm/$^{\circ}C$ according to the degree of Ni oxidation. Also temperature coefficient of resistance(TCR) values of Ni oxide thin films depended on the degree of Ni oxidation such as 2,188 ppm/$^{\circ}C$ to 5,630 ppm/$^{\circ}C$ in the temperature range of 0 $^{\circ}C$∼150 $^{\circ}C$. The results demonstrate that Ni oxide thin films of annealing treatment at 40$0^{\circ}C$ for 5hours could be more advantageous than pure Ni thin films and Pt thin films from a point of output properties and TCR, applied to thermal sensors.

플라즈마 디스플레이 패널의 감광성 격벽을 위한 B2O3-Al2O3-SiO2 유리계의 굴절률과 밀도 (Refractive Indices and Densities of B2O3-Al2O3-SiO2 Glass System for Photosensitive Barrier Ribs of Plasma Display Panel)

  • 원주연;황성진;이상호;김형순
    • 한국전기전자재료학회논문지
    • /
    • 제22권6호
    • /
    • pp.506-511
    • /
    • 2009
  • For the application of the photosensitive barrier ribs with optimal properties such as glass transition temperature, refractive index and coefficient thermal expansion, the boro-silicate glasses was studied. The glass transition temperature, coefficient thermal expansion, and refractive index of the glasses based on the $B_2O_3-Al_2O_3-Al_2O_3-SiO_2$ glass system have been investigated with the different ratio of BaO/$Na_2O$ and $B_2O_3/Na_2O$. Increasing the ratio of $B_2O_3/Na_2O$ was led to the increase of coefficient thermal expansion and the decrease of glass transition temperature. The increase of refractive index of boro-silicate glasses increased with the density of glasses. We suggest the empirical equation for the prediction of refractive index with the glass density, $n=0.123{\rho}+1.182$ with 0.042 as the standard deviation in the boro-silicate glass system. The aim of the present paper is to give a basic result of the thermal and optical properties for designing the composition of photosensitive barrier ribs in PDP.

Ni/CGO Cermet Anode의 특성 최적화 (Property Optimization of Ni/CGO Cermet Anodes)

  • 최종혁;김남진;이덕열
    • 한국전기전자재료학회논문지
    • /
    • 제12권1호
    • /
    • pp.94-102
    • /
    • 1999
  • Ni/CGO cermets were fabricated as the anode for SOFC which uses CGO as the electrolyte. And their electrical conductivity, electrochemical reactivity, and thermal expansion coefficient were optimized through the variation of NiO/CGO particle size ration and their composition. The electrical conductivity of the cermet was increased abruptly at a certain Ni content and the percolation concentration was decreased with the decreasing particle size ratio. Anodic overpotential was also decreased with the decreasing particle size ratio. For a fixed ratio it showed a minimum value at 50 wt.%. Thermal expansion coefficient was increased monotonically with increasing Ni contents, however it did not depend on the size ratio. With three properties taken into account, the cermet of particle size ration of 0.03 and composition of 50 wt.% was judged to be optimal as the anode.

  • PDF

적외선 광학렌즈 제작을 위한 GeSe의 벌크 제작 및 특성 연구 (A Study on the Properties and Fabrication of Bulk Forming GeSe Based Chalcogenide Glass for Infrared Optical Lens)

  • 배동식;여종빈;박정후;이현용
    • 한국전기전자재료학회논문지
    • /
    • 제26권9호
    • /
    • pp.641-645
    • /
    • 2013
  • Chalcogenide glass has superior property of optical transmittance in the infrared region. Glass made using Ge-Se how many important optical applications. We have determined the composite formular of $Ge_{0.25}Se_{0.75}$ to be the GeSe chalcogenide glass composition appropriate for IR lenses. Also, the optical, thermal and physical characteristics of chalcogenide glass depended on the composition ratio. GeSe bulk sample is produced using the traditional melt-quenching method. The optical, structural, thermal and physical properties of the compound were measured by using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Differential scanning calorimeter (DSC), and Scanning electron microscope (SEM) respectively.

Ga$_2$O$_3$첨가에 따른 다성분계 Optical Glass Fiber의 특성에 관한 연구 (The Study on Properties of Multicomponent Optical Glass Fiber by Adding Ga$_2$O)

  • 윤상하;강원호
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1996년도 추계학술대회 논문집
    • /
    • pp.128-134
    • /
    • 1996
  • In this study, the thermal and optical properties of multicomponent glass optical fiber by adding heavy metal oxide Ga$_2$O$_3$were investigated. The fiber samples were made by rod in tube method. The optical loss of fiber was measured in 0.3~1.8${\mu}{\textrm}{m}$ wavelength region. As Ga$_2$O$_3$increased up to 20wt%, the transition and softening temperature of bulk glass were increased from 495$^{\circ}C$ to 579$^{\circ}C$ and from 548$^{\circ}C$ to 641$^{\circ}C$respectively. Whereas the thermal expansion coefficient was decreased from 102 to 79.1$\times$10$^{-7}$ $^{\circ}C$. The refractive index was increased from 1.621 to 1.665, and IR cut-off wavelength was enlarged from 4.64${\mu}{\textrm}{m}$ to 6.1${\mu}{\textrm}{m}$. The optical loss of fiber was decreased and more remarkably decreased in 1.146${\mu}{\textrm}{m}$~1.8${\mu}{\textrm}{m}$ wavelength region.

  • PDF

실리콘 나노선/다중벽 탄소나노튜브 Core-Shell나노복합체의 합성 (Synthesis of Si Nanowire/Multiwalled Carbon Nanotube Core-Shell Nanocomposites)

  • 김성원;이현주;김준희;손창식;김동환
    • 한국재료학회지
    • /
    • 제20권1호
    • /
    • pp.25-30
    • /
    • 2010
  • Si nanowire/multiwalled carbon nanotube nanocomposite arrays were synthesized. Vertically aligned Si nanowire arrays were fabricated by Ag nanodendrite-assisted wet chemical etching of n-type wafers using $HF/AgNO_3$ solution. The composite structure was synthesized by formation of a sheath of carbon multilayers on a Si nanowire template surface through a thermal CVD process under various conditions. The results of Raman spectroscopy, scanning electron microscopy, and high resolution transmission electron microcopy demonstrate that the obtained nanocomposite has a Si nanowire core/carbon nanotube shell structure. The remarkable feature of the proposed method is that the vertically aligned Si nanowire was encapsulated with a multiwalled carbon nanotube without metal catalysts, which is important for nanodevice fabrication. It can be expected that the introduction of Si nanowires into multiwalled carbon nanotubes may significantly alter their electronic and mechanical properties, and may even result in some unexpected material properties. The proposed method possesses great potential for fabricating other semiconductor/CNT nanocomposites.

${N_2}O$ 가스로 열산화된 게이트 유전체의 특성 (Properties of the gate dielectrics by thermal oxidation in ${N_2}O$ gas)

  • 김창일;장의구
    • E2M - 전기 전자와 첨단 소재
    • /
    • 제6권1호
    • /
    • pp.55-62
    • /
    • 1993
  • 수소 관련된 species를 포함하지 않고 자기제한특성으로 초박막 성장을 용이하게 제어할 수 있는 N$_{2}$O 가스 분위기에서 실리콘의 산화는 질화된 산화막의 재산화공정 보다 훨씬 간단한 공정이다. N$_{2}$O산화로 형성된 Si-SiO$_{2}$ 계면에서 nitrogen-rich층은 산화막 구조를 강화할 뿐만 아니라 게이트 유전체의 질을 개선하고 산화율을 감소시키는 산화제의 확산 장벽으로 작용한다. 초박막 oxynitride 게이트 유전체가 종래의 열산화 방법으로 제작되었고 oxynitride막의 특성이 AES와 I-V 특성 측정의 결과를 분석하여 연구하였다.

  • PDF

Sn-complexes를 이용한 OLED의 발광 특성 향상에 관한 연구 (Improvement of Luminance Properties of Blue OLEO using $SnDP(HPB)_2$)

  • 김동은;최규채;권영수
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 2008년도 춘계학술대회 논문집 센서 박막재료연구회 및 광주 전남지부
    • /
    • pp.121-122
    • /
    • 2008
  • Blue emitting materials have been explored by various researchers. However, blue-emitting materials with high luminous efficiency, good color purity, and thermal stability are still much desired. In this study, we synthesized a new blue luminescent material, $SnDP(HPB)_2$ which is low molecular compound and thermal stability. The PL spectrum of $SnDP(HPB)_2$ was observed blue at the wavelength of 447nm. The ionization potential(IP) and the electron affinity(EA) of $SnDP(HPB)_2$ was measured to be 6.7 eV and 3.0 eV, respectively. The fundamental structure of the OLED was ITO/NPB/$SnDP(HPB)_2/Alq_3$/LiF/Al. As a Result, we obtained to enhance the performance of blue OLED.

  • PDF

고온인가에 따른 에폭시 복합체의 열화 및 유전특성평가 (Estimation of Degradation and Dielectric Properties for Epoxy Composites doe to Applying High Temperature)

  • 왕종배;이준웅;김재환
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1995년도 추계학술대회 논문집
    • /
    • pp.175-178
    • /
    • 1995
  • Distribution of relaxation time is presented in the Cole-Cole arc diagram with frequency parameter. In the case of estimation of activation energy for main chains, maximum loss frequencies of ${\alpha}$ peaks, f$\sub$m/(${\alpha}$) display curved change according to the WLF type with variations of temperature. Structural change by the filling of filler and degradation by the thermal aging can be estimated from the WLF factors, C$_1$and C$_2$in Log f$\sub$m/-1/T curves which reflect the variations of free volume and thermal expansivity of composites.

  • PDF