• Title/Summary/Keyword: Electronic Potential

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Electrochemical Properties of Polypyrrole-Glucose Oxidase Enzyme Electrode Depending on Dopant Size (Polypyrrole-Glucose Oxidase 효소전극의 배위자 크기에 따른 전기 화학적 특성)

  • 김현철;구할본;사공건
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.745-748
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-T S. Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Surface Properties of Epoxy Composites by Plasma Treatment (플라즈마처리에 따른 에폭시 복합재료의 표면특성)

  • 임경범;이백수;이덕출
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.10
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    • pp.821-827
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    • 2001
  • In this study performed to identify a degradation mechanism in macromolecular insulating material, the contact angel, surface potential decay, surface resistivity, and XPS analysis were compared after exposure of FRP laminate to plasma discharge. In the case of contact angle, the surface of specimen untreated showed weak hydrophobic property of 73。. However, the contact angle was decreased to 20。in the plasma-treated specimen. In the case of chemical changes arising form plasma treatment, carboxl radicals were generated mainly in the surface treated, which was rapidly changed to the hydrophilic one. In the corona potential decay study to determine the electrical changes of the surface, positive charges were rapidly decreased when compared with negative charges, leading to negative property in the surface of specimen not treated. However, in the case of the hydrophilic surface, lots of carboxl radicals acting as positive polarity were generated, resulting in positive surface. Owing to such positive surface, charges of negative polarity applied were rapidly decreased.

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Synthesis and Electron Transport of Novel Stilbenequinone(II) (Stilbenequinone의 합성과 전자 수송(II))

  • Cho, Chong-Rae;Kim, Myoung-Hwan;Yang, Jong-Heon;Kim, Beom-Jun;Chung, Su-Tae;Son, Se-Mo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.1002-1005
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    • 2002
  • We have synthesized novel stilbenequinone derivatives(ASQ, PSQ) and investigated the properties of their electron drift mobility. Characteristics of the ionization potential Ip and electron affinity Ea of the ASQ were investigated by determining both oxidation and reduction potentials. There were estimated Ip = 7.1 eV and Ea = 3.6 eV. The electron drift mobility of ASQ mixture(R:t-Bu 10wt%) was $1.5{\times}10^{-5}cm^2/V{\cdot}sec$ at $6.15{\times}10^{5}V/cm$ and $1.3{\mu}m$ thickness.

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Study on Photoelectrochemical Etching of Single Crystal 6H-SiC (단결정 6H-SiC의 광전화학습식식각에 대한 연구)

  • 송정균;정두찬;신무환
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.2
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    • pp.117-122
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    • 2001
  • In this paper, we report on photoelectrochemical etching process of 6H-SiC semiconductor wafer. The etching was performed in two-step process; anodization of SiC surface to form a deep porous layer and thermal oxidation followed by an HF dip. Etch rate of about 615${\AA}$/min was obtained during the anodization using a dilute HF(1.4wt% in H$_2$O) electrolyte with the etching potential of 3.0V. The etching rate was increased with the bias voltage. It was also found out that the adition of appropriate portion of H$_2$O$_2$ into the HF solution improves the etching rate. The etching process resulted in a higherly anisotropic etching characteristics and showed to have a potential for the fabrication of SiC devices with a novel design.

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The State of the Art in BIPV Technology (건물일체형 태양광 발전 (BIPV) 기술 동향)

  • Yoon, Jong-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.1
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    • pp.1-7
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    • 2014
  • The current downturn of BIPV sector has an enormous potential to rebound and expand into the PV sector for construction market in the foreseeable future. Solar technology has already gained a significant market due to lack of natural resources in the Korean domestic market. Given the technical infrastructure of state-of-the-art fusion technology, the competitiveness of software-driven BIPV market in the world can be ver attractive and have the potential to develop as a key national technology. To do this, from the viewpoint of complexity, technical R&D, national political aspect, social aspect, economic aspect and institutional support systems need to be parallelly formulated. A dedicated BIPV sector has not yet been established, especially policy and institutional framework have very crucial impact on the establishment of BIPV sector.

Simulation on Surface Tracking Pattern using the Dielectric Breakdown Model

  • Kim, Jun-Won;Roh, Young-Su
    • Journal of Electrical Engineering and Technology
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    • v.6 no.3
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    • pp.391-396
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    • 2011
  • The tracking pattern formed on the dielectric surface due to a surface electrical discharge exhibits fractal structure. In order to quantitatively investigate the fractal characteristics of the surface tracking pattern, the dielectric breakdown model has been employed to numerically generate the surface tracking pattern. In dielectric breakdown model, the pattern growth is determined stochastically by a probability function depending on the local electric potential difference. For the computation of the electric potential for all points of the lattice, a two-dimensional discrete Laplace equation is solved by mean of the successive over-relaxation method combined to the Gauss-Seidel method. The box counting method has been used to calculate the fractal dimensions of the simulated patterns with various exponent $\eta$ and breakdown voltage $\phi_b$. As a result of the simulation, it is found that the fractal nature of the surface tracking pattern depends strongly on $\eta$ and $\phi_b$.

Electrochemical Properties of Polypyrrole Enzyme Electrode Immobilized Glucose Oxidase with Different Ligand (포도당 산화효소를 고정화한 Polypyrrole 효소전극의 배위자 변화에 다른 전기화학적 특성)

  • Kim, Hyun-Cheol;Gu, Han-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.529-532
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    • 2001
  • We synthesized polypyrrole (PPy) by electrolysis of the pyrrole monomer solution containing support electrolyte KCl and/or p-toluene sulfonic acid sodium salt (p-TS). The electrochemical behavior was investigated using cyclic voltammetry and AC impedance. In the case of using electrolyte p-TS, the redox potential was about -0.3 V vs. Ag/ AgCl reference electrode, while the potential was about 0 V for using electrolyte KCl. It is considered as the backbone forms a queue effectively by doping p-TS Therefore, it is possible to be arranged regularly. That leads to improvement in the electron hopping. The AC impedance plot gave a hint of betterment of mass transport. PPy doped with p-TS has improved in mass transport, or diffusion. That is because the PPy doped with p-TS has a good orientation, and is more porous than PPy with KCl.

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Optimal Design of Grid Cathode Structure in Spherically Convergent Beam Fusion Device (구형 집속 빔 핵융합 장치에서 그리드 음극 구조의 최적 설계)

  • Ju, Heung-Jin;Park, Jeong-Ho;Hwang, Hwui-Dong;Choi, Seung-Kil;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.4
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    • pp.381-387
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    • 2008
  • Neutron production rate in spherically convergent beam fusion(SCBF) device as a portable neutron source strongly depends on the ion current and the grid cathode structure. In this paper, as the process of design and analysis, Design of Experiment(DOE) based on the results by Finite Element Method-Flux Corrected Transport(FEM-FCT) method is employed to calculate the ion current. This method is very useful to find optimal design conditions in a short time. Number of rings, radius of rings, and distance between the grid cathode and center are selected as control factors. From the results in the optimized model, the higher ion current is calculated and deeper potential well is also observed.

Fuel Cell Performance by the Impedance Method (연료전지의 임피던스방법 적용 연구)

  • Kim, Gwi-Yeol
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.510-511
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    • 2008
  • Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. And, The research and development for the solid oxide fuel cell have been promoted rapidly and extensively in recent years, because of their high efficiency and future potential. Therefore this paper describes the manufacturing method and characteristics of anode electrode for solid oxide fuel cell, by the way, Ni-YSZ materials are used as anode of high temperature widely. So in this experiments, we investigated the optimum content of Ni, by the impedance characteristics, overvoltage. As a result, the performance of Ni-YSZ anode(40vol%) was better excellent than the others.

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Application of Potential-pH Diagram and Potentiodynamic Polarization of Tungsten

  • Seo, Yong-Jin;Park, Sung-Woo;Lee, Woo-Sun
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.3
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    • pp.108-111
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    • 2006
  • The oxidizer-induced corrosion state and microstructure of surface passive metal-oxide layer greatly influenced on the removal rate of tungsten film according to the slurry chemical composition of different mixed oxidizers. In this paper, the actual polishing mechanism and pH-potential equilibrium diagram obtained from potentiodynamic polarization curve were electrochemically compared. An electrochemical corrosion effect implies that slurries with the highest removal rate (RR) have the high dissolution rate.