• Title/Summary/Keyword: Electron life time

Search Result 185, Processing Time 0.024 seconds

Electrochemical Impedance Spectroscopy Analysis on the Dye-sensitized Solar Cell with Different $TiO_2$ thicknesses ($TiO_2$ 두께에 따른 염료감응형 태양전지의 전기화학적 임피던스 분석)

  • Kim, Hee-Je;Lee, Jeong-Gee;Seo, Hyun-Woong;Son, Min-Kyu;Kim, Jin-Kyoung;Prabalkar, K.;Shin, In-Young
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.58 no.12
    • /
    • pp.2425-2430
    • /
    • 2009
  • Dye-sensitized solar cell(DSC) is composed of a dye-adsorbed nanoporous $TiO_2$ layer on fluorine-doped tin oxide(FTO) glass substrate, electrolyte, and platinium doped counter electrode. Among these, a dye-absorbed nanoporous $TiO_2$ layer plays an important role in the performance of the DSC because the injected electrons from excited dye molecules move through this layer. And the condition of $TiO_2$ layer such as the morphology and thickness affects on the electron movement. Therefore, the performances and the efficiency of DSC change as the thickness of $TiO_2$ layer is different. Electrochemical Impedance Spectroscopy(EIS) is the powerful analysis method to study the kinetics of electrochemical and photoelectrochemical processes occurring in the DSC especially the injected electron movements. So we analyzed the DSCs with different $TiO_2$ thicknesses by using EIS to understand the influence of the $TiO_2$ thickness to the performance of the DSC clearly. Finally, we got the EIS analysis on the DSC with different $TiO_2$ thickness from the internal resistance of the DSC, the electron life time and the amount of dye molecules.

Determination of Residual Concentration and Half-life Time in Soils of Imidazole Fungicide Prochloraz (Imidazole계 살균제 Prochloraz의 토양 중 잔류량과 반감기분석)

  • Choi, Yong Hwa;Han, Seong Soo;Kim, Il Kwang
    • Analytical Science and Technology
    • /
    • v.15 no.1
    • /
    • pp.67-71
    • /
    • 2002
  • The residual analysis and half-life time of imidazole fungicide prochloraz in soils (silty clay) were investigated by gas chromatography equipped electron capture detector (GC-ECD). The soil samples were extracted acetone/hexane(1:1) solvent and analyzed after separated by $LC-NH_2$ Sep-Pak solid column. Linear sensitivity of standard calibration curve was Y = 268.8600X + 0.0664, $R^2=0.9998$ between 0.05~1.00 ng. The detection limit was 0.02 mg/L and the average recoveries were 94.5~97.3% from the standard additional experiments with 0.10 and 0.40 mg/L. The half-life time was 24.4 days in room laboratory and 7.6 days in the field test soil.

A Study on the Characteristics change of WSix Thin Films by S/H Life Time (S/H Life Time에 따른 WSix의 특성 변화에 관한 연구)

  • 정양희;강성준
    • Journal of the Korea Institute of Information and Communication Engineering
    • /
    • v.6 no.5
    • /
    • pp.689-695
    • /
    • 2002
  • Film compositions are needed in semiconductor manufacturing for such diverse application as production tool qualifications and process development. Surface and interface information is generally provided with Auger electron spectroscopy(AES). In this paper, WSix films were analyzed for structural, electrical, and compositional properties of tungsten silicide thin films produced by low pressure chemical vapor deposition as a function of temperature, DCS post flow, shower head life time, and the silicon to tungsten ratios have been investigated. We find that Si/W composition ratio is increased in the surface and interface of WSix thin films by the DCS post flow process and increasing deposition temperature, respectively. The results obtained in this study are also applicable to process control of WSix deposition for memory device fabrication.

Nitrate Removal by Immobilized Denitrifying Bacteria in Recirculating Aquaculture System (순환여과식 양식 시스템에 있어서의 고정화 탈진균에 의한 질산염 제거)

  • 김상희;김필균;김중균
    • Journal of Life Science
    • /
    • v.9 no.6
    • /
    • pp.698-703
    • /
    • 1999
  • For the nitrate removal in recirculating aquaculture system, a denitrifying bacterium, Pseudomonas fluorescens, was isolated from municipal sewage and the cells were immobilized in modified-polyvinly alchol (PVA) gel beads. The immobilized cells in both the fixed-and fluidized-bed reactors showed 98% of denitrification efficiency with 6hr HRT, and the removal efficiency of total organic carbon (TOC) was above 90%. Form scanning electron microscopy (SEM) observation, it was known that biofilm formed in fixed-bed reactor was thicker than that formed in fluidized-bed reactor as operation time passed.

  • PDF

Note on Drassyllus shaanxiensis of Ground Gnaphosid Spiders (Arachnida: Araneae: Gnaphosidae) in Korea

  • Kim, Byung-Woo;Lee, Won-Cheol;Kwon, Jung-Gyun
    • Animal Systematics, Evolution and Diversity
    • /
    • v.24 no.1
    • /
    • pp.33-38
    • /
    • 2008
  • A ground gnaphosid spider, Drassyllus shaanxiensis Platnick and Song, 1986 is reported for the first time in Korea. This species is described with detailed illustrations, leg spination, trichobothrium patterns, and SEM photographs of male palpal organ and female epigynum.

Novel Host materials for Phosphorescent OLEDs with long lifetime

  • Kim, Young-Hoon;Yu, Eun-Sun;Kim, Nam-Soo;Jung, Sung-Hyun;Kim, Hyung-Sun;Lee, Ho-Jae;Kang, Eui-Su;Chae, Mi-Young;Chang, Tu-Won
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2008.10a
    • /
    • pp.549-552
    • /
    • 2008
  • We have developed a novel bipolar host material with both electron and hole transporting characteristics. Since CGH(Cheil Green Host) has some electron transporting characteristics, it shows increased luminance efficiency in device including TCTA and without HBL(hole blocking layer:BAlq). Maximum power efficency of CGH was 27.4lm/W at the device structure ITO/DNTPD(60)/NPB(20)/TCTA(10)/EML(30)/Alq3(20)/LIF(1)/Al. We measured device performance again without HBL. The result of CGH showing 26.0lm/W is outstanding compared to that of CBP showing 19.1lm/W without holeblocking layer. We also measured lifetime and found to be 205hr at 3000nit, that is significant result compared to the life time of CBP device showing 82hr. CGH shows high device performance with holeblocking layer. Moreover, it shows better device performance and life time than those of CBP without holeblocking.

  • PDF

Novel Organic Electron Injectors for the Enhancement of Lifetime, Efficiency and Reduction in Operating Voltage in OLEDs

  • Kathirgamanathan, Poopathy;Arkley, Vincent;Surendrakumar, S.;Paramaswara, G.;Ganeshamurugan, S.;Antipan-Lara, J.;Ravichandran, S.;Kumaraverl, M.;Chan, Y.F.
    • 한국정보디스플레이학회:학술대회논문집
    • /
    • 2007.08b
    • /
    • pp.1206-1209
    • /
    • 2007
  • Both PM-OLEDs and AM-OLEDs are now in production. However, manufacturers are still concerned about life-time, voltage drift, operating voltage and efficiency in order to develop larger displays. Most material suppliers seem to be focussing on emitters and the benefits of introducing suitable charge transporters have been largely unexplored. OLED-T has developed a novel organic electron injector (Trade Name: EI-101) which evaporates at a very low temperature of $300^{\circ}C$ as opposed to the conventional LiF which requires $580^{\circ}C$. EI-101 has been found to increase the lifetime by up to 12%, reduce the voltage drift by up to 61% and increase the efficiency by up to 15%. The material can be handled in air and in situ Q-mass spectroscopy on extended thermal evaporation has confirmed its high stability for use in mass production.

  • PDF

Photochemical Response Analysis on Different Seeding Date and Nitrogen (N) level for Maize (Zea mays L.) (옥수수의 파종시기 및 질소수준별 광화학적 반응 해석)

  • Park, So-Hyun;Yoo, Sung-Yung;Lee, Min-Ju;Park, Jong-Yong;Song, Ki-Tae;Kim, Tae Wan;Lee, Byung-Moo
    • KOREAN JOURNAL OF CROP SCIENCE
    • /
    • v.60 no.1
    • /
    • pp.1-7
    • /
    • 2015
  • The photochemical characteristics were analyzed in the context of sowing time and different levels of fertilized nitrogen during the maize (Zea mays L.) growth. When maize was early sawn, the fluorescence parameters related with electron-transport, in photosystem II (PSII) and PSI, were effectively enhanced with the higher level of fertilized nitrogen. Highest values were observed in maize leaves grown in double N-fertilized plot. The photochemical parameters were declined in the progress of growth stage. In early growth stage, the fluorescence parameters were highest, and then reduced to about half of the parameters related with electron transport on PSII and PSI at middle and late growth stages. In 1/2 N plot, the photochemical energy dissipation was measured to 13% in term of active reaction center per absorbed photon resulting in decrease in performance index and driving force of electron. This decrease induced to lower the photochemical effectiveness. In 2 N plots, the electron transport flux from $Q_A$ to $Q_B$ per cross section and the number of active PSII RCs per cross section were considerably enhanced. It was clearly indicated that the connectivity between photosynthetic PSII and PSI, i.e. electron transport, was far effective.

Evaluation of Low Cycle Fatigue Damage of Gas Turbine Blades Used for a Long Time (장시간 사용된 가스터빈 블레이드의 저주기피로 손상도 평가)

  • Heo, In Kang;Kim, Jae Hoon
    • Journal of the Korean Society of Safety
    • /
    • v.33 no.3
    • /
    • pp.8-14
    • /
    • 2018
  • Ni-base superalloy has excellent resistance to extreme environments such as high temperatures and high stresses and are used as materials for large gas turbines. In this paper, the specimens were taken from the blade that were used for a long time, and their life span was studied by microstructure analysis and avoidance of cursing. The microstructural analysis of the specimens was carried out using a OM and SEM to observe the coarsening, carbides on gamma prime. Low-cycle fatigue tests were performed on new material and airfoil of long time-used blade. The test was conducted under various deformation conditions and temperature conditions of $760^{\circ}C$ and $870^{\circ}C$. The low cycle fatigue test was carried out using the Coffin-Manson equation and the fatigue life was predicted. After the test, crack path and fracture surface were analyzed using SEM.

Morphology and distribution of some marine diatoms, family Rhizosoleniaceae, genus Rhizosolenia, in Korean coastal waters

  • Yun, Suk-Min;Lee, Sang-Deuk;Lee, Jin-Hwan
    • ALGAE
    • /
    • v.26 no.2
    • /
    • pp.141-152
    • /
    • 2011
  • The present study describes the morphology, taxonomy, and distribution of species belonging to the diatom genus Rhizosolenia in Korea's marine coastal waters. From September 2008 to February 2010, we collected phytoplankton samples at 30 sites along the Korean coastline and studied them by light and scanning electron microscopy. We found 6 rhizosolenid genera in our samples: Rhizosolenia, Dactyliosolen, Guinardia, Pseudosolenia, Proboscia, and Neocalyptrella. In the present paper, we studied the following rhizosolenid species and compared them with congeners: R. pungens, R. fallax, R. imbricata, Rhizosolenia sp. 1, and Rhizosolenia sp. 2. The morphology of R. pungens exhibits important diagnostic characteristics in its girdle segment structure in the column and in its external process. To distinguish R. fallax and R. imbricata, the most important characteristics are the striation and the velum structure. R. pungens occurred in our samples all along the Korean coast. Only rarely did we find R. imbricata in the samples and at low abundance. We recorded R. fallax, Rhizosolenia sp. 1 and Rhizosolenia sp. 2 for the first time in Korean waters, but they rarely occurred.