• Title/Summary/Keyword: Electrokinetic

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초음파동전기세척 복합기법에 의한 오염부지 복원기술

  • 정하익;김상근;송봉준;강동우;이경국
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.183-185
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    • 2004
  • In this study, the combined electrokinetic and ultrasonic remediation technique, ultrasonically enhanced electrokinetic technique, was studied for the removal of heavy metal and organic substance in contaminated soils. The electrokinetic technique has been applied to remove mainly the heavy metal and the ultrasonic technique has been to remove mainly organic substance in contaminated soil. The laboratory soil flushing tests combined electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of these both techniques. A series of laboratory experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants of heavy metal and organic substance. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of electrokinetic ultrasonic remediation technique.

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Comparison of Improving Dewatering Process at Clay-Sandy Soil based on Pulse-Electrokinetic Technology and Continuous-Electrokinetic Technology (펄스동전기법과 연속처리동전기법을 이용한 점토성-사질토의 탈수화 효율 비교)

  • Shin, Sanghee
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.4
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    • pp.37-41
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    • 2014
  • Pulse electrokinetic technology is proposed for improving the dewatering-process from clay-sandy soil. Proposed electrokinetic technology is to be the dewatering process due to fluid movement of current flow for the stability of clay-sandy soils. Samples produced in this study were completed to verify the proposed performance for 7 days by gradually increasing the pressure to the final pressure of 30 psi ($2.11kgf/cm^2$) through the compression process. In this study, pulse electrokinetic treatment and conventional continuous electrokinetic treatment are tested and observed, respectively. The condition of continuous electrokinetic treatment is a continuous process during 48 hours. And the condition of pulse electrokinetic treatment system is to interrupt the power three times for 48 hours, every 8 hours. These treatments are that the voltage gradient is 3 V/cm. As a result, the efficiency of pulse electrokinetic is similar to the continuous electrokinetic. The power consumption efficiency of pulse electrokinetic is better than continuous electrokinetic.

Numerical simulation of electrokinetic dissipation caused by elastic waves in reservoir rocks

  • Zhang, Xiaoqian;Wang, Qifei;Li, Chengwu;Sun, Xiaoqi;Yan, Zheng;Nie, Yao
    • Geomechanics and Engineering
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    • v.19 no.1
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    • pp.11-20
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    • 2019
  • The use of electrokinetic dissipation method to study the fluid flow law in micro-pores is of great significance to reservoir rock microfluidics. In this paper, the micro-capillary theory was combined with the coupling model of the seepage field and the current field under the excitation of the harmonic signal, and the coupling theory of the electrokinetic effect under the first-order approximation condition was derived. The dissipation equation of electrokinetic dissipation and viscous resistance dissipation and its solution were established by using Green's function method. The physical and mathematical models for the electrokinetic dissipation of reservoir rocks were constructed. The microscopic mechanism of the electrokinetic dissipation of reservoir rock were theoretically clarified. The influencing factors of the electrokinetic dissipation frequency of the reservoir rock were analyzed quantitatively. The results show that the electrokinetic effect transforms the fluid flow profile in the pores of the reservoir from parabolic to wavy; under low-frequency conditions, the apparent viscosity coefficient is greater that one and is basically unchanged. The apparent viscosity coefficient gradually approaches 1 as the frequency increases further. The viscous resistance dissipation is two orders of magnitude higher than the electrokinetic effect dissipation. When the concentration of the electrolyte exceeds 0.1mol/L, the electrokinetic dissipation can be neglected, while for the electrolyte solution (<$10^{-2}M$) in low concentration, the electrokinetic dissipation is very significant and cannot be ignored.

Removal of heavy metal and organic matter by electrokinetic ultrasonic remediation technology

  • Chung, Ha-Ik;Oh, In-Kyu
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.210-214
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    • 2002
  • In this study, the coupled effect of electrokinetic and ultrasonic remediation technology was investigated for removing of heavy metal and organic matter at the same time. The laboratory tests were conducted using specially designed and fabricated electrokinetic and ultrasonic devices. The electrokinetic technique was applied to remove mainly the heavy metal and the ultrasonic technique was applied to remove mainly organic substance in contaminated soil. Diesel fuel and Cd were used as a surrogate contaminant for this test. A series of laboratory experiments involving electrokinetic and electrokinetic+ultrasonic flushing test were carried out. An increase in permeability and contaminant removal rate was observed in electrokinetic+ultrasonic flushing test.

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Enhanced Electrokinetic remediation of low permeability soil contaminated with phenanthrene (Phenanthrene으로 오염된 저투수성 지반의 향상된 Electrokinetic 정화 처리)

  • 김강호;한상재;김수삼
    • Journal of Soil and Groundwater Environment
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    • v.7 no.4
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    • pp.3-9
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    • 2002
  • In this study, electrokinetic remediation tests were performed with spiked fine-grained soil by phenanthrene which is representative hydrophobic organic contaminant of petroleum hydrocarbon. And also, the enhanced method was used with surfactant concentration variation and elapsed time to achieve more higher removal efficiency than conventional electrokinetic treatment. In conventional electrokinetic treatment, most phenanthrene was not transported. But, in the enhanced method used by the surfactant, phenanthrene moved form anode to cathode region and accumulated in cathode region. Also, the transportation rate of phenanthrene was increased with surfactant concentration increasement and elapsed time.

토질조건에 따른 납 오염토양의 Electrokinetic 정화 효율

  • 김병일;조용실;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.04a
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    • pp.34-37
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    • 2002
  • In this study, electrochemical characteristics variation and removal efficiency with initial pH and mineral compositions during electrokinetic remediation of lead contaminated soils were investigated. Test results showed that heavy metal transportation affected by soil characteristics and electrochemical characteristics varied during electrokinetic remediation. Therefore, in the application of enhanced electrokinetic remediation technique to increase removal efficiency, discrete selection of enhanced technique with characteristics of targeted soil were needed.

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토양의 종류에 따른 초음파토양세척의 투수특성 분석

  • 정하익;송봉준;이용수;유준;강동우
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.09a
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    • pp.258-261
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    • 2004
  • In this study, the combined electrokinetic and ultrasonic remediation technique onto simple soil flushing was studied for the enhancement of water and liquid flows and the removal of contaminants in contaminated soils. The ultrasonic technique has been used to increase liquid flow and remove pollutants in contaminated soil. The laboratory soil flushing tests combined electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of these both techniques. A series of laboratory permeability experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests.

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WASHING-ELECTROKINETIC DECONTAMINATION FOR CONCRETE CONTAMINATED WITH COBALT AND CESIUM

  • Kim, Gye-Nam;Yang, Byeong-Il;Choi, Wang-Kyu;Lee, Kune-Woo;Hyeon, Jay-Hyeok
    • Nuclear Engineering and Technology
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    • v.41 no.8
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    • pp.1079-1086
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    • 2009
  • A great volume of radioactive concrete is generated during the operation and the decommissioning of nuclear facilities. The washing-electrokinetic technology in this study, which combined an electrokinetic method and a washing method, was developed to decontaminate the concrete generated in nuclear facilities. The results of only an electrokinetic decontamination for the concrete showed that cobalt was removed to below 1% from the concrete due to its high pH. Therefore, the washing-electrokinetic technology was applied to lower the pH of the concrete. Namely, when the concrete was washed with 3 M of hydrochloric acid for 4 hours (0.17 day), the $CaCO_3$ in the concrete was decomposed into $CO_2$ and the pH of the concrete was reduced to 3.7, and the cobalt and cesium in the concrete were removed by up to 85.0% and 76.3% respectively. Next, when the washed concrete was decontaminated by the electrokinetic method with 0.01M of acetic acid in the 1L electrokinetic equipment for 14.83 days, the cobalt and the cesium in the concrete were both removed by up to 99.7% and 99.6% respectively. The removal efficiencies of the cobalt and cesium by 0.01M of acetic acid were increased more than those by 0.05M of acetic acid due to the increase of the concrete zeta potential. The total effluent volume generated from the washing-electrokinetic decontamination was 11.55L (7.2ml/g).

Removal of Heavy Metal and Organic Substance in Contaminated Soils by Electrokinetic and Ultrasonic Remediation (동전기 및 초음파 복원기술에 의한 오염지반내의 중금속 및 유기오염물질 제거)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
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    • v.19 no.3
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    • pp.83-91
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    • 2003
  • The electrokinetic technique has been applied to remove mainly the heavy metal and the ultrasonic technique to remove mainly organic substance in contaminated soil. In this study, the combined electrokinetic and ultrasonic remediation technique was studied far the removal of heavy metal and organic substance in contaminated soils. This study emphasized the coupled effects of electrokinetic and ultrasonic techniques on migration as well as remediation of contaminants in soils. The laboratory soil flushing tests combining electrokinetic and ultrasonic technique were conducted using specially designed and fabricated devices to determine the effect of both of these techniques. A series of laboratory experiments involving the simple, electrokinetic, ultrasonic, and electrokinetic & ultrasonic flushing test were carried out. A soil admixed with sand and kaolin was used as a test specimen, and Pb and ethylene glycol were used as contaminants of heavy metal and organic substance. An increase in out flow, permeability and contaminant removal rate was observed in electrokinetic and ultrasonic flushing tests. Some practical implications of these results are discussed in terms of technical feasibility of in situ implementation of electrokinetic ultrasonic remediation technique.

Remediation of cesium-contaminated fine soil using electrokinetic method

  • Kim, Ilgook;Kim, June-Hyun;Kim, Sung-Man;Park, Chan Woo;Yang, Hee-Man;Yoon, In-Ho
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.189-193
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    • 2020
  • In this study, electrokinetic remediation equipment was used to remove cesium (Cs) from clay soil and waste solution was treated with sorption process. The influence of electrokinetic process on the removal of Cs was evaluated under the condition of applied electric voltage of 15.0-20.0 V. In addition to monitoring the Cs removal, electrical current and temperature of the electrolyte during experiment were investigated. The removal efficiency of Cs from soil by electrokinetic method was more than 90%. After electrokinetic remediation, Cs was selectively separated from soil waste solution using sorbents. Various adsorption agents such as potassium nickel hexacyanoferrate (KNiHCF), Prussian blue, sodium tetraphenylborate (NaTPB), and zeolite were compared and KNiHCF showed the highest Cs removal efficiency. The Cs adsorption on KNiHCF reached equilibrium in 30 min. The maximum adsorption capacity was 120.4 mg/g at 0.1 g/L of adsorbent dosage. These results demonstrated that our proposed process combined electrokinetic remediation of soil and waste solution treatment with metal ferrocyanide can be a promising technique to decontaminate Cs-contaminated fine soil.