• Title/Summary/Keyword: Electrode surface area ratio ($A_c/A_a$)

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Electricity generation from surface floating air cathode microbial fuel cell according to the wastewater flow-rate and the ratio of cathode surface area to anode surface area (표면부유 공기양극 미생물연료전지에서 유량 및 전극 면적비에 따른 전력생산 특성)

  • Yoo, Kyu-Seon;Song, Young-Chae;Woo, Jung-Hui;Chung, Jae-Woo;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.4
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    • pp.591-596
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    • 2011
  • Surface floating air cathode microbial fuel cell (MFC) having horizontal flow was developed for the application of MFC technology. RVC (Reticulated vitreous carbon) coated with anyline was used as anode electrode and carbon cloth coated with Pt (5.0 g Pt/$m^2$, GDE LT250EW, E-TEK) was used as cathode electrode. As results of continuous operation with changing the flow rate from 4.3 mL/min to 9.5 mL/min, maximum power density of 4.5 W/$m^3$ was acquired at 5.4 mL/min, which was at 0.35 m/hr of flow velocity under anode electrode. When the ratio of cathode surface area to anode surface area($A_c/A_a$) was changed to 1.0, 0.5, and 0.25, the maximum power density of 2.7 W/$m^3$ was shown at the ratio of 1.0. As the ratio decreased from 1.0 to 0.25, the power density also decreased, which is caused by increasing the internal resistance resulted from reducing the surface area to contact with oxygen. Actually, internal resistances of the ratio of 1.0, 0.5, and 0.25 were 63.75${\Omega}$, 142.18${\Omega}$, and 206.12${\Omega}$, respectively.

Enhancement of the Bright Room Contrast Ratio in a Plasma Display Panel (플라스마 디스플레이 패널에서 명실 콘트라스트 개선)

  • Moon, C.H.
    • Journal of the Korean Vacuum Society
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    • v.19 no.1
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    • pp.28-35
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    • 2010
  • A new electrode structure in a plasma display panel was designed in a way to increase the bright room contrast ratio (BRCR). The area of the black matrix pattern to get a low reflection from the panel surface was enlarged using the new electrode design concept. The electrical characteristics such as firing voltage, voltage margin and power consumption were measured. The luminance of the panel was measured and the luminous efficiency was calculated. It was found that the new electrode structure was very effective to enhance the BRCR.

Characteristics of Carbon-Doped Mo Thin Films for the Application in Organic Thin Film Transistor (유기박막트랜지스터 응용을 위한 탄소가 도핑된 몰리브덴 박막의 특성)

  • Dong Hyun Kim;Yong Seob Park
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.6
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    • pp.588-593
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    • 2023
  • The advantage of OTFT technology is that large-area circuits can be manufactured on flexible substrates using a low-cost solution process such as inkjet printing. Compared to silicon-based inorganic semiconductor processes, the process temperature is lower and the process time is shorter, so it can be widely applied to fields that do not require high electron mobility. Materials that have utility as electrode materials include carbon that can be solution-processed, transparent carbon thin films, and metallic nanoparticles, etc. are being studied. Recently, a technology has been developed to facilitate charge injection by coating the surface of the Al electrode with solution-processable titanium oxide (TiOx), which can greatly improve the performance of OTFT. In order to commercialize OTFT technology, an appropriate method is to use a complementary circuit with excellent reliability and stability. For this, insulators and channel semiconductors using organic materials must have stability in the air. In this study, carbon-doped Mo (MoC) thin films were fabricated with different graphite target power densities via unbalanced magnetron sputtering (UBM). The influence of graphite target power density on the structural, surface area, physical, and electrical properties of MoC films was investigated. MoC thin films deposited by the unbalanced magnetron sputtering method exhibited a smooth and uniform surface. However, as the graphite target power density increased, the rms surface roughness of the MoC film increased, and the hardness and elastic modulus of the MoC thin film increased. Additionally, as the graphite target power density increased, the resistivity value of the MoC film increased. In the performance of an organic thin film transistor using a MoC gate electrode, the carrier mobility, threshold voltage, and drain current on/off ratio (Ion/Ioff) showed 0.15 cm2/V·s, -5.6 V, and 7.5×104, respectively.

Effect of microporosity on nitrogen-doped microporous carbons for electrode of supercapacitor

  • Cho, Eun-A;Lee, Seul-Yi;Park, Soo-Jin
    • Carbon letters
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    • v.15 no.3
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    • pp.210-213
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    • 2014
  • Nitrogen-doped microporous carbons were prepared using a polyvinylidene fluoride/melamine mixture. The electrochemical performance of the nitrogen-doped microporous carbons after being subjected to different carbonization conditions was investigated. The nitrogen to carbon ratio and specific surface area decreased with an increase in the carbonization temperature. However, the maximum specific capacitance of 208 F/g was obtained at a carbonization temperature of $800^{\circ}C$ because it produced the highest microporosity.

Preparation and Characterization of Carbon Nanotubes-Based Composite Electrodes for Electric Double Layer Capacitors

  • Seo, Min-Kang;Park, Soo-Jin
    • Bulletin of the Korean Chemical Society
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    • v.33 no.5
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    • pp.1523-1526
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    • 2012
  • In this work, we prepared activated multi-walled carbon nanotubes/polyacrylonitrile (A-MWCNTs/C) composites by film casting and activation method. Electrochemical properties of the composites were investigated in terms of serving as MWCNTs-based electrode materials for electric double layer capacitors (EDLCs). As a result, the A-MWCNTs/C composites had much higher BET specific surface area, and pore volume, and lower volume ratio of micropores than those of pristine MWCNTs/PAN ones. Furthermore, some functional groups were added on the surface of the A-MWCNTs/C composites. The specific capacitance of the A-MWCNTs/C composites was more than 4.5 times that of the pristine ones at 0.1 V discharging voltage owing to the changes of the structure and surface characteristics of the MWCNTs by activation process.

Electrochemical Behaviors of Carbon Aerogel Electrodes for Electric Double Layer Capacitors (전기이중층 커패시터용 탄소 에어로겔 전극의 전기화학적 거동 연구)

  • Yang, Jae-Yeon;Seo, Min-Kang;Kim, Byoung-Suhk
    • Composites Research
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    • v.33 no.6
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    • pp.336-340
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    • 2020
  • In this study, carbon aerogels (CA) were prepared by sol-gel polycondensation of resorcinol and furfural in isopropanol using hexamethylenetetramine as a catalyst, and then directly drying the organic gels under isopropanol freeze-drying conditions, followed by carbonization under a nitrogen atmosphere. The preparation conditions of the CA were explored by changing the mole ratio of resorcinol to furfural. The effect of the preparation conditions on the pore structure of the CA was studied by nitrogen adsorption isotherms. The characteristics of the CA were studied by scanning and transition electron microscopy, and infrared spectrometry. The accessibility of pores and performance of the CA as an electrode in electric double layer capacitors were also electrochemically investigated. As a result, BET surface area and specific capacitance increased with the molar ratio of resorcinol to catalyst (R/C) ratio; the maximum values of 765 ㎡/g and 132 F/g were achieved at the R/C ratio of 200, respectively. Consequently, it was confirmed that increasing the R/C ratio increased the average pore size of the CA electrode, which improved the rate capability of the system.

Observation of Corrosion Behavior with Aluminum 5052 Alloy by Modulating Anodization Time (양극산화 공정시간에 따른 알루미늄 5052 합금의 산화피막 성장 및 내식성 관찰)

  • Ji, HyeJeong;Choi, Dongjin;Jeong, Chanyoung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.67-67
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    • 2018
  • The 5xxx series aluminum alloys are recently used in not only marine system but also automotive area because of a low density material, good mechanical properties and better resistance to corrosion. However, Aluminum alloys are less resistant than the purest aluminum such as 1xxx aluminum alloy. Electrochemical anodization technique has attracted in the area of surface treatment because of a simple procedure, a low-cost efficiency than other techniques such as lithography and a large volume of productivity, and so on. Here, The relationship between the corrosion behavior and the thickness of aluminum anodic oxide have been studied. Prior to anodization, The 5052 aluminum sheets ($30{\times}20{\times}1mm$) were degreased by ultra-sonication in acetone and ethanol for 10 minutes and eletropolished in a mixture of perchloric acid and ethanol (1:4, volume ratio) under an applied potential of 20V for 60 seconds to obtain a regular surface. During anodization process, Aluminum alloy was used as a working electrode and a platinum was used as a counter electrode. The two electrodes were separated at a distance of 5cm. The applied voltage of anodization is conducted at 40V in a 0.3M oxalic acid solution at $0^{\circ}C$ with appropriate magnetic stirring. The surface morphology and the thickness of AAO films was observed with a Scanning Electron Microscopy (SEM). The corrosion behavior of all samples was evaluated by an open-circuit potential and potentio-dynamic polarization test in 3.5wt% NaCl solution. Thus, The corrosion resistance of 5052 aluminum alloy is improved by the formation of an anodized oxide film as function of increase anodization time which artificially develops on the metal surface. The detailed electrochemical behavior of aluminum 5052 alloy will be discussed in view of the surface structures modified by anodization conditions such as applied voltages, concentration of electrolyte, and temperature of electrolyte.

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Simultaneous Removal of Gas and Dust by Activated Carbon Coated Electrode

  • Kim, Kwang Soo;Park, Jung O;Lee, Ju Haeng;Jun, Tae Hwan;Kim, Ilho
    • Environmental Engineering Research
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    • v.18 no.4
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    • pp.229-234
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    • 2013
  • This study aimed to develop a new dust collecting system equipped with an activated carbon (A.C.) coated electrode. Before fabrication, pre-treatment of A.C. was performed to remove metal ions within the A.C. to enlarge its specific surface area. Then, pre-treated A.C., black carbon, polyvinyl acetate (PVAc), and methanol were mixed to make a gel compound, which was coated onto aluminum plates to fabricate electrodes. The optimal mixing ratio of A.C., black carbon, PVAc, and methanol was found to be 10 g: 2 g: 3 g: 20 mL. After fabrication, the electrodes were used in the batch-type experiment for $NH_3$ and $H_2S$ removal. The reduction rates of the gases were high at the beginning and slowly reduced with time. Dust collection experiments were conducted in continuous flow, with various voltages applied. Compared to 5 kV, dust removal efficiency was 1.5 times higher when 10 kV was applied. Increasing the number of electrodes applied also increased the collecting efficiency. The correlation coefficient between actual collecting efficiency and trend line was higher than 99%. Consequently, the novel dust collection system equipped with A.C. coated electrode appears to be a promising substitute for existing dust-control devices.

Mesoporous Control Effect of Porous Carbon Nanofibers for Electrical Double-Layer Capacitors (전기 이중층 커패시터를 위한 다공성 탄소나노섬유의 메조 기공 제어 효과)

  • Jo, Hyun-Gi;Shin, Dong-Yo;Ahn, Hyo-Jin
    • Korean Journal of Materials Research
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    • v.29 no.3
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    • pp.167-174
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    • 2019
  • To improve the performance of carbon nanofibers as electrode material in electrical double-layer capacitors (EDLCs), we prepare three types of samples with different pore control by electrospinning. The speciments display different surface structures, melting behavior, and electrochemical performance according to the process. Carbon nanofibers with two complex treatment processes show improved performance over the other samples. The mesoporous carbon nanofibers (sample C), which have the optimal conditions, have a high sepecific surface area of $696m^2g^{-1}$, a high average pore diameter of 6.28 nm, and a high mesopore volume ratio of 87.1%. In addition, the electrochemical properties have a high specific capacitance of $110.1F\;g^{-1}$ at a current density of $0.1A\;g^{-1}$ and an excellent cycling stability of 84.8% after 3,000 cycles at a current density of $0.1A\;g^{-1}$. Thus, we explain the improved electrochemical performance by the higher reaction area due to an increased surface area and a faster diffusion path due to the increased volume fraction of the mesopores. Consequently, the mesoporous carbon nanofibers are demonstrated to be a very promising material for use as electrode materials of high-performance EDLCs.

A Study on Synthesis of $La_{x}Sr_{1-x}GaO_{3}$ Electrode Material for High Temperature Steam Electrolysis (고온 수증기 전해용 $La_{x}Sr_{1-x}GaO_{3}$ 전극 재료의 합성 연구)

  • Park, Mi-Sun;Ryu, Si-Ok;Woo, Sang-Kook;Park, Young-Tae;Choi, Ho-Sang
    • Journal of Hydrogen and New Energy
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    • v.20 no.5
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    • pp.432-438
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    • 2009
  • In this paper, we synthesized LSG powder by Modified-GNP method. Lanthanum, strontium and gallium (LSG) were selected in the preparation of an oxygen-electrode (anode) for High Temperature Steam Electrolysis system (HTSE). The used amount and concentration of nitric acid were varied to find out an appropriate composition for oxygen-electrode (anode). In order to optimize the molar ratio of La and Sr, ratio of La to Sr was varied that 2:8, 5:5 and 8:2. The combined LSGs were calcined for 2 hours at $700^{\circ}C$ and were sintered in a furnace for 4 hours at $1200^{\circ}C$. The phase and crystallinity of LSG powder were determined by XRD. The surface morphology was observed through SEM photograph, and the specific surface area was investigated with BET. The thermochemical property was determined by TG/DTA. The synthesized preparation was obtained of $La_{0.8}Sr_{0.2}GaO_{3}$ formula for 3M nitric acid, which was the best perovskite phase.