• Title/Summary/Keyword: Electrode life

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Failure analysis of capacitor for sub-module in HVDC (HVDC 서브모듈용 커패시터의 고장 분석)

  • Kang, Feel-soon;Song, Sung-Geun
    • Journal of IKEEE
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    • v.22 no.4
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    • pp.941-947
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    • 2018
  • In general, capacitors have a large influence on the life of the system due to frequent charging and discharging. In this paper, we analyze the cause of the core failure of high voltage, high current HVDC sub-module film capacitor and analyze the precautions of the capacitor design and manufacturing process. First, the cause of the fault, the failure mode, and the effect are analyzed through the FMEA of the capacitor. To quantitatively evaluate the causes and effects of faults that have the greatest effect on the failure of a capacitor, a fault tree for the capacitor is presented and the failure rate is analyzed according to the design parameters and the driving conditions. It is verified that the main cause of capacitor failure is the capacitance change, and it is necessary to minimize the temperature rise, corona occurrence, electrode expansion, and insulation distance decrease during capacitor design and manufacturing process in order to reduce the failure rate of the capacitor.

Development of an ionic wind dust collector towards coronavirus reduction in subway stations (지하철 역사 내 코로나 바이러스 저감을 위한 이온풍 집진기 개발)

  • Shin, Dongho;Kim, Younghun;Han, Bangwoo
    • Particle and aerosol research
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    • v.18 no.1
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    • pp.1-8
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    • 2022
  • Since 2019, the corona virus has been continuously affect human life. In particular, in the indoor space where people live, infection by airborne transmission of viruses is a problem. Among them, the spread in the subway, which is the main mode of transport for humans, can be serious. To solve this problem, our research team developed an ionic wind collector to collect and remove corona virus using an ionic wind collector and ozone. In order to apply the ionic wind collector to the subway, it must operate in two modes. Because large amounts of ozone are harmful to the human body. There is a mode that collects bio-aerosol from the air using ionic wind and a mode that inactivates viruses floating in the air by generating a large amount of ozone. As the applied voltage increased, the cleaning ability of the ionic wind collector increased, and the farther the distance between the discharge electrode and the ground plate, the higher the cleaning ability even at low current. In addition, clean air delivery rate (CADR) of an ionic wind collector was up to 5.5 m3/min. As a result of measuring the amount of ozone generated, it was confirmed that 50 ppb to 250 ppb was generated, and it was confirmed that ozone generation was controllable in the ionic wind dust collector.

Effect of LiCoO2-Coated Cathode on Performance of Molten Carbonate Fuel Cell

  • Kim, Dohyeong;Kim, Hyung Tae;Song, Shin Ae;Kim, Kiyoung;Lim, Sung Nam;Woo, Ju Young;Han, Haksoo
    • Journal of Electrochemical Science and Technology
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    • v.13 no.1
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    • pp.112-119
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    • 2022
  • Molten carbonate fuel cells (MCFCs) are environmentally friendly, large-capacity power generation devices operated at approximately 650℃. If MCFCs are to be commercialized by improving their competitiveness, their cell life should be increased by operating them at lower temperatures. However, a decrease in the operating temperature causes a reduction in the cell performance because of the reduction in the electrochemical reaction rate. The cell performance can be improved by introducing a coating on the cathode of the cell. A coating with a high surface area expands the triple phase boundaries (TPBs) where the gas and electrolyte meet on the electrode surface. And the expansion of TPBs enhances the oxygen reduction reaction of the cathode. Therefore, the cell performance can be improved by increasing the reaction area, which can be achieved by coating nanosized LiCoO2 particles on the cathode. However, although a coating improves the cell performance, a thick coating makes gas difficult to diffuse into the pore of the coating and thus reduces the cell performance. In addition, LiCoO2-coated cathode cell exhibits stable cell performance because the coating layer maintains a uniform thickness under MCFC operating conditions. Therefore, the performance and stability of MCFCs can be improved by applying a LiCoO2 coating with an appropriate thickness on the cathode.

Electrochemical Properties of Sub-micron Size Si Anode Materials Distributed by Wet Sedimentation Method (습식 분급으로 입도 조절된 서브 마이크론 크기의 Si 음극활물질의 전기화학적 특성 분석)

  • Jin-Seong Seo;Hyun-Su Kim;Byung-Ki Na
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.39-44
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    • 2023
  • In this study, the particle size of Si polycrystals was controlled through wet-sedimentation method, and changes in the capacity and cyclic characteristics of the Si anode material according to the particle size were observed. After wet-sedimentation of Si particles pulverized by a vibration mill, the non-uniform particle distribution of Si was uniformly controlled. The d50 of a sample in which Si was sedimented for 24 hours decreased to 0.50 ㎛. As a result of the electrochemical characteristic analysis, the Rct value representing the resistance in the electrode was significantly reduced due to the decrease in particle size. The unclassified Si sample exhibited a discharge capacity of 2,869 mAh/g in the first cycle, and decreased to 85.7 mAh/g after 100 cycles. The sample in which Si was classified for 24 hours showed a capacity of 3,394 mAh/g initially, and maintained a capacity of 1,726 mAh/g after 100 cycles. As the size of the Si particles decreased, the discharge capacity increased and the cycle life was also increased.

Exploiting Natural Diatom Shells as an Affordable Polar Host for Sulfur in Li-S Batteries

  • Hyean-Yeol Park;Sun Hyu Kim;Jeong-Hoon Yu;Ji Eun Kwon;Ji Yang Lim;Si Won Choi;Jong-Sung Yu;Yongju Jung
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.198-206
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    • 2024
  • Given the high theoretical capacity (1,675 mAh g-1) and the inherent affordability and ubiquity of elemental sulfur, it stands out as a prominent cathode material for advanced lithium metal batteries. Traditionally, sulfur was sequestered within conductive porous carbons, rooted in the understanding that their inherent conductivity could offset sulfur's non-conductive nature. This study, however, pivots toward a transformative approach by utilizing diatom shell (DS, diatomite)-a naturally abundant and economically viable siliceous mineral-as a sulfur host. This approach enabled the development of a sulfurlayered diatomite/S composite (DS/S) for cathodic applications. Even in the face of the insulating nature of both diatomite and sulfur, the DS/S composite displayed vigorous participation in the electrochemical conversion process. Furthermore, this composite substantially curbed the loss of soluble polysulfides and minimized structural wear during cycling. As a testament to its efficacy, our Li-S battery, integrating this composite, exhibited an excellent cycling performance: a specific capacity of 732 mAh g-1 after 100 cycles and a robust 77% capacity retention. These findings challenge the erstwhile conviction of requiring a conductive host for sulfur. Owing to diatomite's hierarchical porous architecture, eco-friendliness, and accessibility, the DS/S electrode boasts optimal sulfur utilization, elevated specific capacity, enhanced rate capabilities at intensified C rates, and steadfast cycling stability that underscore its vast commercial promise.

Effects of Draw-In Bridge Exercise with Taping or Visual Feedback on Abdominal Muscle Activity (테이핑 또는 시각적 피드백을 병행한 드로우-인 교각운동이 복부 근활성도에 미치는 영향)

  • Won-Sik Bae;Hwa-Gyeong Lee
    • Journal of The Korean Society of Integrative Medicine
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    • v.12 no.2
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    • pp.177-186
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    • 2024
  • Purpose : The purpose of this study was to use oral instruction and taping to induce abdominal draw-in in the previous study, but there is a lack of research on the comparison of effects. Therefore, in this study, we would like to study how the effect of oral instruction, taping, and no feedback can affect muscle activity when performing abdominal draw-in pier exercises. Methods : Before the experiment, group A trained piers and applied only draw-in piers, group B applied taping feedback, and group C were divided into three groups per week for six weeks, and three sets of contractions for five seconds per group were performed five times, and a minute break was provided between each exercise. As a measurement tool, a wireless surface electromyography (EMG) was used to measure surface electromyography (Telemyo-DTS, NORAXON, USA) that derives a synthetic unit of muscle using a surface electrode. For statistical processing of data, the analysis is performed using the SPSS/PC Version 25.0 statistical program for Windows, and the statistical significance level is a=.05 Results : First, the duration was somewhat shorter in order to more accurately compare the muscle activity of the core muscles. Therefore, future research needs to be research that can be exercises with precise biofeedback and taping applied over a longer period of time. Secondly, it is believed that there is no significant difference, since the subjects were studied in healthy young adult men and women, not patients. Thirdly, they could not control the daily life of the subjects. Through future research, it is necessary to analyze the correlation between muscle activity and abdominal muscle thickness by adding ultrasound in addition to muscle activity in various age groups. Conclusion : During draw-in bridge exercise according to feedback, the muscle activity of the back muscle increased, and there was no significant difference in the muscle activity of the back muscle according to each feedback. Therefore, both the feedback applied during the draw-in pier exercise and the control group are effective in changing the thickness of the abdominal muscles.

Multiple accelerated degradation test and failure analysis for $Ni-BaTiO_3$ MLCCs ($Ni-BaTiO_3$ MLCCs에 대한 복합 가속 열화 시험 및 고장 분석)

  • Kim, Jung-Woo;Kim, Jin-Seong;Lee, Hee-Soo;Kang, Do-Won;Kim, Jeong-Wook
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.19 no.2
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    • pp.102-105
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    • 2009
  • The accelerated life time test of the MLCCs with different $BaTiO_3$ particle sizes were conducted at $150^{\circ}C$, 75 V condition and the effect of $BaTiO_3$ particle size on the breakdown voltage and degradation characteristics of MLCCs was investigated. The MLCCs were prepared by using the $BaTiO_3$ particles having the size of $0.525{\mu}m$, $0.555{\mu}m$, $0.580{\mu}m$ and Ni-electrode, respectively. The MLCCs which have the particle size of $0.525{\mu}m$, $0.555{\mu}m$, and $0.580{\mu}m$, respectively were confirmed to meet the standard requirements of X5R(change capacitance within ${\pm}15%$ at $-55{\sim}85^{\circ}C$) by TCC(Temperature Coefficient of Capacitance). The effect of the $BaTiO_3$ particle size on the insulation resistance behavior of MLCCs was confirmed by BDV(Breakdown Voltage) measurements and the cause and degree of degradation of MLCCs were characterized by XPS analysis after the accelerated life test. The MLCCs with $0.525{\mu}m-BaTiO_3$ showed better insulation resistance and BDV characteristics compare to other MLCCs and XPS analysis revealed that the MLCCs degradation is caused by the NiO peak and $BaTiO_3$ peak decrease.

Evaluations of Life Cycle Assessment on Indium-Tin-Oxide Electrochemical Recycling Process (디스플레이 투명전극용 인듐-주석-산화물의 전기화학적 재활용 공정에 관한 전과정 평가)

  • Kim, Raymund K.I.;Lee, Na-Ri;Lee, Soo-Sun;Lee, Young-Sang;Hong, Sung-Jei;Son, Young-Keun;Hong, Tae-Whan
    • Clean Technology
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    • v.19 no.4
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    • pp.388-392
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    • 2013
  • Iindium-tin-oxide (ITO) material was had to use in display application as transparent electrode. However it would be problems comes up, the depletion of indium, tin and energy consumption of production process. Therefore recently trend was demanded alternative ITO material and recycling/reused ITO. In this conditions, the environmental impact have to express correct value about recycling/reused ITO process. The life cycle assessment was valuable method in this process. Thus first step was carried out separating in/out put (material) sources and then, exactive data base (DB) was applied. The result of environment impact was calculated by affect categories and recycling rate was set to 34% (This value was measured in previous project). The rate (g) of ITO material was calculated by chemical equivalent. In result, environmental impact were revealed acidification potential and abiotic depletion and if do not recycle/reuse ITO, $ 476 per 1 ton waste in land.

Effects of Curing & Formation Conditions on the Capacity of Positive Plate for Automotive Vehicles VRLA Batteries (양극판의 숙성과 화성조건이 자동차용 VRLA 배터리 성능에 미치는 영향)

  • Jeong, Soon-Wook;Ku, Bon-Keun
    • Journal of the Korean Applied Science and Technology
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    • v.33 no.1
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    • pp.83-91
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    • 2016
  • We studied the effect of battery deep cycle according to the way of active materials formation and the creation condition of electrode material, 3BS ($3PbO{\cdot}PbSO_4{\cdot}H_2O$) and 4BS ($4PbO{\cdot}PbSO_4$), in order to develop the batteries for Idle Stop & Go system. During the curing with active materials of anode and cathode, we found that the final creased active material was deformed by temperature control and it effects the durability of batteries. AGM battery and Flooded battery with 3BS active materials have excellent initial performance. And AGM battery with 4BS active materials shows the lower performance relatively. To compare and analyze of the formation efficiency of active materials, we tested the formation chagging steps with 3 steps and 9 steps differently. The results are that AGM battery with 4BS active materials is better on initial performance than AGM battery with 3BS. After the comparison of durability by DOD 17.5% life test, AGM battery is more suitable than flooded battery for the ISG system which needs the frequent deep cycle. In conclusion, AGM battery is the most suitable for ISG system and the life performance shows 80% difference according to the way of formation and curing of AGM batteries.

Electrode characteristics of $AB_2$ type hydrogen storage alloy modified by Cr, La addition and fluorination ($AB_2$계 수소저장합금의 전극특성에 미치는 Cr, La 첨가 효과 및 표면 불화처리 효과)

  • Chang I.;Lee B. H.;Cho W. I.;Jang H.;Cho B. W.;Yun K. S.
    • Journal of the Korean Electrochemical Society
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    • v.1 no.1
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    • pp.45-51
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    • 1998
  • [ $AB_2-type$ ] alloy, one kind of hydrogen storage alloys used as an anode of Ni-MH batteries, has large discharge capacity but has remaining problems regarding initial activation, cycle life and self-discharge. This study investigates the effects of Cr-addition and fluorination after La-addition on $Zr_{0.7}Ti_{0.3}V_{0.4}Mn_{0.4}Ni_{1.2}$, composition $AB_2-type$ alloy. EPMA and SEM surface analysis techniques were used and the crystal structure was characterized by XRD analysis. In addition, electrodes were fabricated out of the alloys and characterized by constant current cycling test, electrochemical impedance spectroscopy and potentiodynamic polarization. Cr-addition was found to be effective to cycle life and self-discharge but ineffective to initial activation due to formation of stable oxide film on surface. Fluorination after La-addition to the alloys improved initial activation remarkably due to formation of highly reactive particles on surface.