• Title/Summary/Keyword: Electrode life

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Improvement of Cycle Performance of Graphite-Silicon Monoxide Mixture Negative Electrode in Lithium-ion Batteries (흑연과 실리콘 일산화물의 혼합물로 구성된 리튬이온 이차전지용 음극의 사이클 성능개선 연구)

  • Kim, Haebeen;Kim, Tae Hun;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.155-163
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    • 2019
  • Mixture electrodes of a graphite having a good cycle performance and a silicon monoxide (SiO) having a high capacity are fabricated and their cycle performances are evaluated as negative electrodes for lithium-ion batteries. The electrode prepared by mixing the natural graphite and carbon-coated SiO in a mass ratio of 9:1 shows a reversible capacity of $480mAh\;g^{-1}$, 33% higher than that of graphite. However, the capacity deteriorates continuously upon cycling due to the volume change of silicon monoxide. In this study, the factors that can improve the cycle performance have been discussed through the change in the configurations of the electrode and the electrolyte. The electrode using the carboxymethyl cellulose (CMC) binder shows the best cycle performance compared to the conventional binders. The electrode sing the CMC and styrene-butadiene rubber (SBR) binder not only has almost the similar cycle characteristics with the electrode using the CMC binder but also has the better rate capability. When the fluoroethylene carbonate (FEC) is used as an electrolyte additive, the cycle life is improved. However, the electrolyte with 5 wt% of FEC is appropriate because the rate capability decreases when the content of FEC is increased to 10 wt%. In addition, when the mass loading of the electrode is lowered, the cycle performance is greatly improved. Also, enhanced cycle performance is achieved using the roughened Cu current collector polished by abrasive paper.

Biosensor Electrode Manufacturing Technology Using Nano-carbon Materials (나노 탄소물질을 이용한 바이오센서 전극제조 기술)

  • Kim, Ji-Hyun;Bae, Tae-Sung;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.113-120
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    • 2013
  • Due to human life expectancy of the recent development of medical technology recently, it leads to increase the desire for improving the quality of human life, and grow health concerns and needs. Therefore, in order to prevent the occurrence of disease and to check up a disease quickly, research on the development of a biosensor has been actively processed. One of them, the nano-carbon materials, are very suitable for manufacturing biosensor due to their excellent electrical/mechanical properties. In this review, we introduced the recent studies about preparation methods of carbon electrodes using the carbon nano-materials for biosensors as well as its technological applications.

The electrochemical properties of Zr-Ti-V-Ni-Mn hydrogen storage alloys with various compositions for an electrode of Ni-MH secondary battery (Ni-MH 2차 전기 전극용 Zr-Ti-V-Ni-Mn계 수소저장합금의 조성에 따른 전기화학적 특성)

  • Choi, Seung-Jun;Jung, So-Yi;Park, Choong-Nyeon
    • Transactions of the Korean hydrogen and new energy society
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    • v.10 no.4
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    • pp.219-224
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    • 1999
  • Effects of alloy modification for the $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.4}$ alloy as an electrode materials have been investigated. When Ti in the alloy was partially substituted by Zr, the hydrogen storage capacity and subsequently the discharge capacity increased significantly, however, the activation characteristic and rate capability decreased. By substituting Mn with other elements (Cr, Co and Fe) in the alloy, discharge capacity decreased but the cycle life and rate capability were improved. Considering both the discharge capacity, the high rate discharge property and cycle life, the $Zr_{0.7}Ti_{0.3}V_{0.4}Ni_{1.2}Mn_{0.3}Cr_{0.1}$ alloy among the alloys subjected to the test was found to be a prominent alloy for a practical usage.

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Comparison of Optical Characteristics between CCFL and EEFL in Direct-type Backlight Unit

  • Han, Jeong-Min;Han, Jin-Woo;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.6
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    • pp.268-273
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    • 2007
  • In this study, It was studied about the luminance characteristics of 17 inch direct-type back light using EEFL(external electrode fluorescent lamp) and CCFL(cold cathode fluorescent lamp). The EEFL has a long life time because the electrode is installed outside of lamp. And it is produced in lower price than conventional CCFL. Moreover, it does not need process of installing internal electrode. However, the EEFL technology has several problems such as difficulty of designing driving inverter and preventing this phenomenon along the skin of lamps. We suggested two types of backlight unit for LCD TV application using the EEFL and the CCFL. We found optimized optical design parameters. We set the optical variation parameters such as lamp height, lamp distance, total thickness, and angles of inner walls. We achieved 7580 nits of center luminance, 82% of luminance uniformity by using 20 lamps of the EEFL and 7297 nits of center luminance, 78% of luminance uniformity by using 16 lamps of the CCFL.

Comparis on of Optical Characteristics between CCFL and EEFL in Direct-Type Backlight Unit (직하형 백라이트에서의 CCFL과 EEFL의 광학특성 비교)

  • Kim, Byoung-Yong;Kim, Jong-Yeon;Kim, Young-Hwan;Lee, Sang-Keuk;Kim, Jong-Hwan;Han, Jeong-Min;Ok, Chul-Ho;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.428-428
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    • 2007
  • In this study, It was studied about the luminance characteristics of 17inch direct-type back light using EEFL(External Electrode Fluorescent Lamp). EEFI has a long life time because the electrode is installed outside of lamp. And it is produced low price than conventional CCFL. It does not need process of installing internal electrode. But EEFL technology has several problems such as difficulty of design driving inverter, and prevents leckage current along the skin of lamps. Therefore, by the optimizing of inverter properties, 7525 nit center luminance was acquired in almost same power consumption condition. It was almost same luminance in CCFL backlight unit. And it was operated stably in low operating temperature such as the value of $40^{\circ}C$, so that it was adopted in conventional LCD-TV application.

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Performance of BDD Electrodes Prepared on Various Substrates for Wastewater Treatment (다양한 기판에 형성된 BDD 전극의 폐수처리 특성)

  • Kwon, Jong-Ik;You, Mi-Young;Kim, Seo-Han;Song, Pung-Keun
    • Journal of the Korean institute of surface engineering
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    • v.52 no.2
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    • pp.53-57
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    • 2019
  • Stability and activity of boron doped diamond (BDD) electrode are key factors for water treatment. In this study, BDD electrodes were prepared on various substrates such as Nb, Si, Ti, and $TiN_x/Ti$ by hot filament chemical vapor deposition (HFCVD) method. BDD/Ti film showed the delamination between BDD and Ti substrate due to the formation of TiC layer caused by diffusion of carbon. On the other hand, $BDD/TiN_x/Ti$ showed remarkably improved stability, compared to BDD/Ti. It was confirmed that $TiN_x$ intermediate layer act as barrier layer for diffusion of carbon. High potential window of 2.8 eV was maintained on the $BDD/TiN_x/Ti$ electrode and, better wastewater treatment capability and longer electrode working life than BDD/Nb, BDD/Si and BDD/Ti were obtained.

Portable Soil pH Sensor Using ISFET Electrode

  • Hong, Youngsin;Chung, Sun-Ok;Park, Jongwon;Hong, Youngki
    • Journal of information and communication convergence engineering
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    • v.20 no.1
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    • pp.49-57
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    • 2022
  • Fertilizers have long been used to increase crop yields; however, farmers are still having difficulties in managing fertilizers for growing crops as well as economic problems. The conventional method of soil sampling and laboratory analysis to determine soil pH is time consuming and costly; therefore, a portable pH sensor is developed to characterize spatial or temporal variability within fields via rapid and dense data acquisition. The portable pH sensor comprises an electrode unit, a portable console, and a USB connector. The soil water content (SWC) and electrical conductivity (EC) affect the electrical resistance of soil. An artificial test soil is performed to evaluate the effect of SWC and EC on soil pH. The test results show that stable pH measurements are achieved at SWCs greater than 20 mL (16.3%). Regardless of the SWC, the electric potential difference (EPD) remains at 2.5 g of NaCl. As the EC increases in the soil samples, the EPD increases.

Effect of Module Design for a Garment-Type Heart Activity Monitoring Wearable System Based on Non-Contact Type Sensing (비접촉식 심장활동 모니터링 기능 의복형 웨어러블 시스템의 모듈 효과 탐색)

  • Koo, Hye Ran;Lee, Young-Jae;Gi, Sunok;Lee, Seung Pyo;Kim, Kyeng Nam;Kang, Seung Jin;Lee, Jeong-Whan;Lee, Joo Hyeon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.39 no.3
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    • pp.369-378
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    • 2015
  • Various forms of wearable bio-signal monitoring systems have been developed recently. Acquisition of stable bio-signal data for health care purposes needs to be unconscious and continuous without hindrance to the users' daily activities. The garment type is a suitable form of a wearable bio-signal monitoring system; however, motion artifacts caused by body movement degrade the signal quality during the measurement of bio-signals. It is crucial to stabilize the electrode position to reduce motion artifacts generated when in motion. The problems with motion artifacts remain unresolved despite their significant effect on bio-signal monitoring. This research creates a foundation for the design of garment-type wearable systems for everyday use by finding a method to reduce motion artifacts through modular design. Two distinct garment-type wearable systems (tee-shirt with a motion artifact-reducing module (MARM) and tee-shirt without a MARM) were designed to compare the effects of modular design on the measurement of heart activity in terms of electrode position displacement, signal quality index value, and morphological quality. The tee-shirt with MARM showed superior properties and yielded higher quality signals than the tee-shirt without MARM. In addition, the tee-shirt with MARM showed a better repeatability of the heart activity signals. Therefore, a garment design with MARM is an efficient way to acquire stable bio-signals while in motion.

On-site Water Nitrate Monitoring System based on Automatic Sampling and Direct Measurement with Ion-Selective Electrodes

  • Kim, Dong-Wook;Jung, Dae-Hyun;Cho, Woo-Jae;Sim, Kwang-Cheol;Kim, Hak-Jin
    • Journal of Biosystems Engineering
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    • v.42 no.4
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    • pp.350-357
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    • 2017
  • Purpose: In-situ monitoring of water quality is fundamental to most environmental applications. The high cost and long delays of conventional laboratory methods used to determine water quality, including on-site sampling and chemical analysis, have limited their use in efficiently managing water sources while preventing environmental pollution. The objective of this study was to develop an on-site water monitoring system consisting mainly of an Arduino board and a sensor array of multiple ion selective electrodes (ISEs) to measure the concentration of $NO_3$ ions. Methods: The developed system includes a combination of three ISEs, double-junction reference electrode, solution container, sampling system consisting of three pumps and solenoid valves, signal processing circuit, and an Arduino board for data acquisition and system control. Prior to each sample measurement, a two-point normalization method was applied for a sensitivity adjustment followed by an offset adjustment to minimize the potential drift that could occur during continuous measurement and standardize the response of multiple electrodes. To investigate its utility in on-site nitrate monitoring, the prototype was tested in a facility where drinking water was collected from a water supply source. Results: Differences in the electric potentials of the $NO_3$ ISEs between 10 and $100mg{\cdot}L^{-1}$ $NO_3$ concentration levels were nearly constant with negative sensitivities of 58 to 62 mV during the period of sample measurement, which is representative of a stable electrode response. The $NO_3$ concentrations determined by the ISEs were almost comparable to those obtained with standard instruments within 15% relative errors. Conclusions: The use of the developed on-site nitrate monitoring system based on automatic sampling and two-point normalization was feasible for detecting abrupt changes in nitrate concentration at various water supply sites, showing a maximum difference of $4.2mg{\cdot}L^{-1}$ from an actual concentration of $14mg{\cdot}L^{-1}$.

Comparison of Electrical Tree Initiation According to Flow Pattern in EHV Power Cable Insulation (초고압 전력 케이블 절연층의 Flow Pattern 방향각에 따른 전기 트리 개시 특성 비교)

  • Lee, Seung-Yoo;Kim, Young-Ho;Cho, Dae-Hee;Lee, In-Ho;Park, Wan-Ki
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1532-1534
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    • 1999
  • Electrical treeing phenomenon, regarded as pre-breakdown which accelerates aging process leading an insulation to the complete breakdown, is with no doubt extremely fatal to the performance of the insulation. Investigated in this paper is electrical treeing representing local dielectric failure according to flow pattern, the flow history of liquid polyethylene formed during the extrusion process. Experiments of electrical tree initiation by means of ramp tests were conducted using newly developed electrode system with point-to-point structure. Constant voltage tests were also carried out with the electrode system to estimate the life time of the insulation. Results were analyzed using statistical method such as Weibull distribution.

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