• Title/Summary/Keyword: Electrode interface

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Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode

  • Kim, Kyungmin;Jung, Yongju;Kim, Seok
    • Carbon letters
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    • v.15 no.3
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    • pp.187-191
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    • 2014
  • This study reports on the influence of N-butyl-N-methylpyrrolidinium tetrafluoroborate ($PYR_{14}BF_4$) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammonium tetrafluoroborate ($TEABF_4$) as a common salt. Using the $PYR_{14}BF$ ionic liquid as additive produced higher ionic conductivity in the electrolyte and lower interface resistance between carbon and electrolyte, resulting in improved capacitance. The chemical and electrochemical stability of the electrolyte was measured by ionic conductivity meter and linear sweep voltammetry. The electrochemical analysis between electrolyte and carbon electrode was examined by cyclic voltammetry and electrochemical impedance spectroscopy.

A study on the weld nugget formation in resistance spot welding of aluminum alloy (알루미늄 합금의 저항 점 용접시 용접너깃의 형성에 대한 연구)

  • 나석주;오세진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.10 no.5
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    • pp.661-669
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    • 1986
  • In this study, the resistance spot welding process of an aluminum alloy was analyzed through the numerical simulation including the electric contact resistance and the heat generation in the electrode. The finite element model was used to solve the electro-thermal responses in weld cycles. The resistance of the contact area was represented as the contact element modeling, but the thermal resistance between the contact surfaces was neglected. Welding tests of Alclad 2024-T3 aluminum alloy were made not only to get the input data for the numerical simulation, but also to compare the numerical results. The contact resistance was determined initially by the contact resistance tests and assumed to decay exponentially up to the solidus temperature. The temperature distributions and dynamic resistance obtained numerically were in good agreement with the experimental results. Numerical results revealed that nugget growth depends mainly on the heat generated in the workpiece and its contact area. The heat generated in the electrode has, however, only a little effect on the nugget growth, and the heat generation in the electrode-workpiece interface is initially high but decrease repidly.

Supercapacitor of Auxiliary Electric Power Source in Industrial Safety for High Output (고출력용 산업안전 보조전원의 Supercapacitor)

  • 허진우;강안수
    • Proceedings of the Safety Management and Science Conference
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    • 2003.11a
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    • pp.335-343
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    • 2003
  • In the electrode fabrication of unit cell, it was ascertained that electrochemical characteristics were greatly increased with 90 wt.% of BP-20, 5 wt.% of Super P and 5 wt.% of mixed binder [P(VdF-co-HFP) : PVP =7 : 3] The self-discharge of unit cell showed that diffusion process was controlled by the ion concentration difference of initial electrolyte due to the characteristics of Electric Double Layer Capacitor (EDLC) charged by ion adsorption in the beginning, but this by current leakage through the double-layer at the electrode/electrolyte interface had a minor effect and voltages of curves were remained constant regardless of electrode material. The electrochemical characteristics of 2.3 V/3,000 F grade EDLC were as follows: 0.35 m of DC-ESR (100 A discharge), 0.14 mof AC-ESR (AC amplitude 100 mV), 2.80 Wh/kg (3.73 Wh/L) of energy density and 4.64 kW /kg (6.19 kW/L) of power density. Power output was compatible with electric vehicle applications, uninterrupted power supply and engine starter, in due consideration of Ragone relations.

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Effects of electrode tips on the weldability of galvannealed steel (Galvannealed steel의 점 용접성에 미치는 전극 팁의 영향)

  • 유병길;강춘식
    • Journal of Welding and Joining
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    • v.5 no.3
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    • pp.11-18
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    • 1987
  • Effects of electrode tips shapes of spot welding on the galvannealed steel have been studied, and the results obtained from this studies are as follows. 1) Expulsion had no effect on the shear strength of the specimen but been observed on the tensile strength of the specimen. 2) Effect of holding time after welding was neglegible when the spot welding supplies enough heat input. 3) Depending on the sopt welding tip shape it has different weldbility. It has better weldability in the order of pointed shape, truncated shape and dome shape. But the effect of coolind was just the opposite of the above order.

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Ionic Conductivity by A Complex Admittance Method

  • Chy Hyung Kim;Eung Dong Kim
    • Bulletin of the Korean Chemical Society
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    • v.10 no.6
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    • pp.495-500
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    • 1989
  • The ionic conductivity of polycrystalline, glass, and glass-ceramic silicates was measured using two-terminal AC method with blocking electrode over a frequency range of 100 Hz to 100 KHz in the temperature range of $200^{\circ}C$ to $320^{\circ}C$. Analysing the capacitance (C), susceptance (B), impedance (Z), and conductance (G) under the given conditions, an equivalent circuit containing temperature and frequency dependent component is proposed. Higher capacitance could be observed in the low frequency region and on the improved ionic migration conditions i.e., at higher temperature in a better ionic conductor. Also the electrode polarization built up at the electrode-specimen interface could be sorted out above 10 KHz. However, grain boundary contribution couldn't be extracted from the bulk resistance over the frequency range measured here.

Flexible biosensors based on field-effect transistors and multi-electrode arrays: a review

  • Kim, Ju-Hwan;Park, Je-Won;Han, Dong-Jun;Park, Dong-Wook
    • Journal of Semiconductor Engineering
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    • v.1 no.3
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    • pp.88-98
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    • 2020
  • As biosensors are widely used in the medical field, flexible devices compatible with live animals have aroused great interest. Especially, significant research has been carried out to develop implantable or skin-attachable devices for real-time bio-signal sensing. From the device point of view, various biosensor types such as field-effect transistors (FETs) and multi-electrode arrays (MEAs) have been reported as diverse sensing strategies. In particular, the flexible FETs and MEAs allow semiconductor engineering to expand its application, which had been impossible with stiff devices and materials. This review summarizes the state-of-the-art research on flexible FET and MEA biosensors focusing on their materials, structures, sensing targets, and methods.

A Study on the AC Interfacial Breakdown Properties of the Interface between Epoxy/EPDM with Variation of the Spread Oil (도포된 오일의 변화에 따른 Epoxy/EPDM 계면의 교류 절연파괴 특성에 관한 연구)

  • Bae, Deok-Gwon;Jeong, Il-Hyeong;O, Jae-Han;Park, U-Hyeon;Lee, Gi-Sik;Kim, Chung-Hyeok;Lee, Jun-Ung
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.8
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    • pp.445-450
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    • 2000
  • Many successful developments and microscopic studies have been made on the high quality insulating materials. However, a little attention have given to the macroscopic interface in HV(High Voltage) insulating systems. In this study, AC interfacial breakdown strength and V-t characteristic of the interface between Epoxy/EPDM(ethylene propylene diene terpolymer) are investigated. Electrode system is designed to reduce the charges from electrodes and to have the tangential potentials along the interface between Epoxy/EPDM by FEM(finite elements method). The AC breakdown strength is observed when HV is given to the interface. It is shown that AC interfacial breakdown strength is improved by increasing interfacial pressure and oiling. In particular, it was saturated at certain interfacial pressure level. V-t characteristic is able to extend to the life time of the interface between Epoxy/EPDM. Oiling also plays a good roll in prolongation of the life time.

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Control of Grain Size of PZT Thin Film through Seed Layers (Seed Layer를 통한 PZT 박막의 결정립 크기 조절)

  • Kim, Tae-Ho;Kim, Ji-Young;Lee, In-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.05b
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    • pp.273-278
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    • 2000
  • In order to study effects of interface layers between PZT films and electrodes for MFM(Metal-Ferroelectric-Metal) structure capacitors, we have fabricated the capacitors with the Pt/PZT/interface-layer/Pt/$TiO_2/SiO_2/Si$ structure. $PT(PbTiO_3)$ interface layers were formed by sol-gel deposition and PbO, $ZrO_2$ and $TiO_2$ thin layers were deposited by reactive sputtering. $TiO_2$ interface layers result in the finest grains of PZT films compared to $PbO_2$ and $ZrO_2$ layers. On the other hand, PT interface layers result in improved morphology of PZT films and do not significantly change ferroelectric properties. It is also observed that seed layers at the middle and top of PZT films do not give significant effects on grain size but the PT seed layer at the interface between the bottom electrode and the PZT films results in the small grain size.

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A Experiment Study of Torch Distance on Automated Tandem GMA Welding System (탄뎀 가스메탈아크 용접의 토치 극간거리에 관한 실험적 연구)

  • Lee, Ji-Hye;Kim, Ill-Soo;Jung, Seong-Myeong;Lee, Jong-Pyo;Kim, Young-Su;Park, Min-Ho
    • Journal of Welding and Joining
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    • v.30 no.6
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    • pp.49-55
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    • 2012
  • The tandem welding process is one of the most efficient welding processes widely used in material joining technique such as manufacturing of strong and durable structures. It facilitates high rate of joint filling with little increase in the overall rate of heat input due to the simultaneous deposition from two electrode wires. The two electrodes in tandem welding process helps in high-efficiency and high productive of welding process. In this study a automated tandem welding system is developed to determine the correlation between cathode and anode and compared with current ratio of the two electrode torch. Three different inter-electrode distances were chosen, 25mm, 35mm and 45mm to perform the experiment with three different current ratio. From the experiment results, the current ratio between two torch has a large impact on width, height and depth of penetration. In addition, a stable bead geometry is obtained when inter-electrode distance is 35mm.