• Title/Summary/Keyword: Electrode Porosity

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Application of Advanced Manufacturing Technologies to Polymer Lithium Ion (PLI) Bi Cell Production Electrode Preparation / Assembly / Lamination

  • Singleton Robert W.;Nelson Craig R.
    • 한국전기화학회:학술대회논문집
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    • 1999.11a
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    • pp.83-91
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    • 1999
  • Technical advances in manufacturing techniques and applied technologies have been made for bi cell manufacture, and are currently being implemented in the areas of discrete electrode / bi cell assembly, and electrode / separator lamination. Not only have improvements been noted in the reliability of the mechanical assembly and the increase in yields and decrease in costs, battery electrical performance has also been enhanced thru these assembly techniques. Evidence has been shown that the lamination techniques can influence porosity and electrolyte dispersion, and therefore electrical performance and long term reliability of the cells.

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Treatment of Heavy Metal Wastewater Bed Electrode Reactor by a Fluidized 1. Distribution of Local Mass Transfer Coefficients on the Current Feeder (유동층 전극반응기를 이용한 중금속폐수의 처리에 관한 연구 1. 전류공급원에서의 국부물질전달계수의 분포)

  • 황영기;정은혁
    • Journal of Environmental Science International
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    • v.6 no.1
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    • pp.1-8
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    • 1997
  • Varing the flow velocity of solution and particle diameter, the mass transfer coefficient of the local electrode on current feeder has been measured in an empty flow reactor, an inert fluidized bed electrode reactor, and an active fluidized bed electrode reactor. It had its maximium value when the bed porosity was 0.6 to 0.65 and decreased with in- creasing the height of local electrode. The mass transfer coefficient was found to be high especially when higher particle was fluidized. Electrochemical deposition of copper dissolved in the synthesized wastewater has been performed in the active fluidized bed electrode reactor. The deduction rate was higher than 90% and the residual concentration of copper decreased to less than 5ppm.

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Formation of Porous Si by Indirect Electrode Anodization (간접전극 양극산화에 의한 다공성 실리콘의 형성)

  • Kim, Soon-Kyu;Chang, Joon-Yeon
    • Journal of the Korean Vacuum Society
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    • v.15 no.3
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    • pp.273-279
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    • 2006
  • This study explored the possibility of porous Si (PS) formed by indirect electrode anodization used for effective isolation material for radio frequency integrated circuits (RFIC). We investigated the effect of current density and reaction time on the porosity size and depth, and X-ray diffraction of bulk Si and porous Si to evaluate the change in lattice parameter. Porosity size and depth usually increases with an increase in the current density and reaction time. PS increases the lattice parameter of Si compared to the bulk Si which causes the compressive stress of around 8 MPa. PS formed by the method is believed to be suitable for isolation material for RFIC because it is simple process as well as good compatibility to Si VLSI process.

A study of DSC using Ultrasonic and Thermal treatment on Photo-Electrode (염료감응형 태양전지 광전극 초음파 열처리에 관한 연구)

  • Hong, Ji-Tae;Kim, Mi-Jeong;Sim, Ji-Yong;Seo, Hyun-Woong;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1291-1292
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    • 2007
  • Recently, there were many researches for efficiency improvement of DSC. Among of these works, research of surface treatment is still a prerequisite for electron diffusion, light-harvesting and surface state of DSC.[1] Using of the surface treatment, it can be raise up porosity of $TiO_2$ nano-crystalline structure on photo-electrode. There are chemical, physical, electrical and optical methods which raise up its porosity. In this paper, we have designed and manufactured MOPA-type ultrasonic circuit (100W, frequency and duty variable). Manufactured ultrasonic circuit to use to force cavity density and power into $TiO_2$ paste. Then, we have optimized forcing time, frequency and duty of ultrasonic irradiation for surface treatment of photo-electrode of DSC. In I-V characteristic test of DSC, ultrasonic and thermal treated DSC shows 19% improved its efficiency against monolithic DSC. And it shows stability of light-harvesting from drastically change of light irradiation test.

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Recent Advances in Preparation and Supercapacitor Applications of Lignin-Derived Porous Carbon: A Review

  • Hae Woong Park;Hyo-Jun Ahn;Kwang Chul Roh
    • Journal of Electrochemical Science and Technology
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    • v.15 no.1
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    • pp.111-131
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    • 2024
  • Lignin-derived porous carbon has been identified as a versatile electrode material for supercapacitors (SCs) in energy storage systems (ESSs) owing to their intrinsic advantages including good electrical conductivity, low cost, high thermal and chemical stability, and high porosity, which stem from high surface, appropriate pore distribution, tailored morphologies, heterostructures, and diverse derivates. In this review, to provide a fundamental understanding of the properties of lignin, we first summarize the origin, historical development, and basic physicochemical properties. Next, we describe essential strategies for the preparation of lignin-derived porous carbon electrode materials and then highlight the latest advances in the utilization of lignin-derived porous carbon materials as advanced electrode materials. Finally, we provide some of our own insights into the major challenges and prospective research directions of lignin-derived porous carbon materials for supercapacitors. We believe that this review will provide general guidance for the design of next-generation electrode materials for supercapacitors.

Preparation of Thin Nickel Foam for Nickel-Metal Hydride Battery (Ni-MH 전지용 thin nickel foam의 제조)

  • 신준호;김기원
    • Journal of the Korean institute of surface engineering
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    • v.28 no.2
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    • pp.83-91
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    • 1995
  • A new method for preparation of thin nickel foam for Ni-MH battery was investigated. In this method, fine graphite powders of $1\mu\textrm{m}$$2\mu\textrm{m}$ diameter were pasted into pores of thin polyurethane foam film in order to supply electric conducting seeds for nickel deposition by electroless plating reaction. After electroless plating, remaining polyurethane foam was removed chemically by organic solvent treatment and graphite particles also removed by ultrasonic cleaning. Porosity of formed nickel foam was about 85% During electroplating, porosity of the nickel foam decreased less than 5% up to $30\mu\textrm{m}$ coating thickness. And then it was electroplated and heat-treated to improve mechanical strength and ductility. Finally, thin nickel foam for Ni electrode of Ni-MH battery with 80% porosity and $350\mu\textrm{m}$~X$400\mu\textrm{m}$ thickness was obtained.

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Numerical Study of Electrolyte Wetting Phenomena in the Electrode of Lithium Ion Battery Using Lattice Boltzmann Method (격자 볼츠만법을 이용한 리튬이온전지의 전극내 전해액 함침현상에 관한 수치적 연구)

  • Lee, Sang Gun;Jeon, Dong Hyup
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.4
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    • pp.357-363
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    • 2014
  • The electrolyte wetting phenomena in the electrode of lithium ion battery is studied numerically using a multiphase lattice Boltzmann method (LBM). When a porous electrode is compressed during roll-pressing process, the porosity and thickness of the compressed electrode are changed, which can affect its wettability. In this study, the change in electrolyte distribution and degree of saturation as a result of varying the compression ratio are investigated with two-dimensional LBM approach. We found that changes in the electrolyte transport path are caused by a reduction in through-plane pore size and result in a decrease in the wettability of the compressed electrode.

Estimation of Representative Mechanical Property of Porous Electrode for Secondary Batteries with Homogenization Method (균질화 기법을 이용하여 기공이 있는 이차전지 극판의 대표 기계 물성 도출을 위한 연구)

  • Pyo, Changmin;Kim, Jaewoong
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.21 no.9
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    • pp.85-91
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    • 2022
  • The demand for electric vehicles has increased because of environmental regulations. The lithium-ion battery, the most widely used type of battery in electric vehicles, is composed of a cathode, an anode, and an electrolyte. It is manufactured according to the pole plate, assembly, and formation processes. To improve battery performance and increase manufacturing efficiency, the manufacturing process must be optimized. To do so, simulation can be used to reduce wasted resources and time, and a finite-element method can be utilized. For high simulation quality, it is essential to reflect the material properties of the electrode by considering the pores. However, the material properties of electrodes are difficult to derive through measurement. In this study, the representative volume element method, which is a homogenization method, was applied to estimate the representative material properties of the electrode considering the pores. The representative volume element method assumes that the strain energy before and after the conversion into a representative volume is conserved. The method can be converted into one representative property, even when nonhomogeneous materials are mixed in a unit volume. In this study, the material properties of the electrode considering the pores were derived. The results should be helpful in optimizing the electrode manufacturing process and related element technologies.

Thick Positive Electrode using Polytetrafluorethylene (PTFE) Binder for High-Energy-Density Lithium-ion Batteries (높은 에너지 밀도의 리튬이온 이차전지를 위한 PTFE 바인더를 적용한 고로딩 양극)

  • Kang, Jeong Min;Kim, Hyoung Woo;Jang, Young Seok;Kim, Haebeen;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.24 no.2
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    • pp.28-33
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    • 2021
  • Many researchers have increased the loading level of electrodes to improve the energy density of secondary batteries. In this study, high-loading NCM523 (LiNi0.5Co0.2Mn0.3O2) positive electrode is manufactured using a polytetrafluoroethylene (PTFE) binder, not the conventional polyvinylidene fluoride (PVdF) binder, which has been commonly used in lithium-ion batteries. Through the kneading process using PTFE suspension, not the conventional slurry process using PVdF solution in N-methyl-2-pyrrolidinone (NMP), thick electrodes with high loading are easily manufactured. When the PTFE and PVdF-based electrodes are prepared at a loading level of 5.0 mAh/cm2, respectively, the PTFE-based electrode shows better cycle performance and rate capability than those of PVdF-based electrodes. The electrode manufactured by the kneading process using a PTFE binder has high electrode porosity due to insufficient roll-press, but the porosity can be lowered by high temperature roll-press over 120℃. However, there is no significant difference in cycle performance according to the roll press temperature. In addition, the cycle performance of the high loading electrode is slightly improved by increasing the content of the conductive material. Overall, the PTFE binder can improve the performance of the high loading electrode, but additional solutions will be needed.