• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2003년도 춘계총회 및 학술발표회
• /
• pp.65-65
• /
• 2003

• 한국수소및신에너지학회논문집
• /
• 제25권6호
• /
• pp.620-628
• /
• 2014

Direct Carbon Fuel Cell(DCFC) is one of new power generation that the chemical energy of solid carbon can be converted into electrical energy directly. At the high temperature, the electrochemical reaction of the carbon takes place and the carbon reacts with oxygen to produce carbon dioxide as followed overall reaction ($C+O_2{\rightarrow}CO_2$). However, in case of using the raw coals as a fuel of DCFC, the volatile matter containing carbon, hydrogen, and oxygen produces at operating temperature. In this study, the electrochemical reaction of Adaro coal was compared with Graphite. This work focused on the electrochemical reaction of two kinds of solid carbon by Electrochemical Impedance Spectroscopy(EIS). The EIS results were estimated by equivalent circuit analysis. The constant phase element(CPE) was applied in Randle circuit to explain an electrode and fuel interface. The correlation between the fuel characteristic and electrochemical results was discussed by elements of equivalent circuit of each fuel.

• Korean Chemical Engineering Research
• /
• 제59권2호
• /
• pp.159-164
• /
• 2021

부착형(attachable) 타입의 웨어러블 디바이스 적용을 위한 패브릭(fabric)이나 텍스처(textiles) 타입의 고성능 전극 소재 개발에 대한 필요성이 부각되고 있다. 본 연구에서는 유연 전극 소재로 탄소나노튜브 섬유(CNT fibers)를 응용하고자, CNT fibers의 전기화학적 특성과 이를 적용한 비효소적 글루코스 센싱 성능을 확인하였다. CNT fibers의 표면 구조는 주사전자 현미경(SEM)을 이용하여 분석하였으며, 전기화학적 특성 및 센싱 성능 분석은 시간대전류법와 순환전압 전류법, 전기화학 임피던스 분석법을 이용하여 수행되었다. CNT fibers 전극은 낮은 capacitive current와 산화-환원 화학종과 전극 계면 간의 효율적인 direct electron transfer에 의한 우수한 electrochemical activity 등 향상된 전기화학적 특성으로 인해 높은 감도와 넓은 선형 농도 범위, 그리고 낮은 검출 한계 등 우수한 센싱 특성을 보였다. 따라서, 본 연구는 CNT fibers 기반의 고성능 유연 전극 소재 개발을 위한 기초 연구로 활용될 수 있을 것으로 기대된다.

• 한국정밀공학회:학술대회논문집
• /
• 한국정밀공학회 2002년도 춘계학술대회 논문집
• /
• pp.918-921
• /
• 2002

Some investigators who have tried to achieve the highly smooth surface finish using electrochemical processes have reported that high current density produced lustrous surfaces while the opposite conditions produced a passive layer and had a tendency to produce a black surface. However, processing at a low current density may produce a non-lustrous surface but the improvement of dimensional accuracy of the surface is significant. The surface with pulse process was a bit more lustrous than with continuous current but the black passive layer still could be found at grooved surface. There are two ways to achieve highly smooth surface finish. One is brushing it with a brush the other is electrochemical machining (ECM) with high current. The former method is the most common polishing practice, but not only may the surface obtained differ from operator to operator, but precision smooth surface on micro grooves are difficult to obtain. The latter one recently has been used to produce a highly smooth surface after EDM process. However, the material removal rate in ECM with high current is relatively high. Hence the original shape of the micro grooves, which was formed by electrochemical micro-machining (EMM) process, may be destroyed. In this study, an electrochemical polishing process using pulse current is adopted as a possible alternative process when micro grooves formed by EMM process should be polished. Mirror-like micro grooves with lustrous and smooth surface can be produced electrochemically with pulse current because the voltage and current used can be lower than the case of continuous current. This study will discuss the accurate control of physical and electrical conditions so as to achieve mirror-like micro grooves with lustrous and smooth surface without destroying the original shape of micro grooves.

• 대한기계학회논문집A
• /
• 제21권3호
• /
• pp.430-438
• /
• 1997

Deburring and edge finishing technology as the final process of machining operation is required for manufacturing of advanced precise conponents. But, deburring is considered as a difficult problem on going to the high efficient production and automation in the FMS. Removal of burr couldn't have a standard of its definition because of its various shapes, dimensions and properties and mostly depends on manual treatment. Especially, deburring for cross hole inside is very difficult owing to its shape passing through out perpendicular to a main hole. The electrochemical method is suggested as its solution in practical aspect. Therefore, electrochemical deburring technology needs to be developed for the high efficiency and automation of internal deburring in the cross hole. In this study, the new process in the eliminating burr inside cross hole, electrochemical deburring by the wheel electroplated with Cubic-Boron-Nitrade abrasives, is suggested. Its deburring mechanism is described and machining performances is investigated. Also, CBN electroplated wheel is designed and manufactured and then characteristics of electrochemical deburring are investigated through experiments. Overall electrochemical deburring performance against burr inside cross hole is examined in the various power sources such as peak current and direct current.

• Journal of Electrochemical Science and Technology
• /
• 제11권4호
• /
• pp.392-398
• /
• 2020

Producing solar grade silicon using an inexpensive method is a key factor in lowering silicon solar cell costs; the direct electrochemical reduction of SiO₂ in molten salt is one of the more promising candidates for manufacturing this silicon. In this study, SiO₂ granules were electrochemically reduced in molten CaCl₂ (850℃) using Ag-Si eutectic droplets that catalyze electrochemical reduction and purify the Si product. When Ag is used as the working electrode, the Ag-Si eutectic mixture is formed naturally during SiO₂ reduction. However, since the Ag-Si eutectic droplets are liquid at 850℃, they are easily lost during the reduction process. To minimize the loss of liquid Ag-Si eutectic droplets, a cylindrical graphite container working electrode was introduced and Ag was added separately to the working electrode along with the SiO₂ granules. The graphite container working electrode successfully prevented the loss of the Ag-Si eutectic droplets during reduction. As a result, the Ag-Si eutectic droplets acted as stable catalysts for the electrochemical reduction of SiO₂, thereby producing one-dimensional Si rods through a mechanism similar to that of vapor-liquid-solid growth.

• Journal of Electrochemical Science and Technology
• /
• 제2권1호
• /
• pp.32-38
• /
• 2011

The composite barium strontium cobalt ferrite (BSCF) cathodes were investigated in the intermediate temperature range of solid oxide fuel cells (SOFCs). The characteristics and electrochemical performances of composited BSCF/samarium doped ceria (SDC); BSCF/gadolinium doped ceria (GDC); and BSCF/SDC/GDC were compared to single BSCF cathode. The BSCF used in this study were synthesized using glycine nitrate process and mechanically mixing was used to fabricate a composite cathode. Using a composite form, the thermal expansion coefficient (TEC) could be reduced and BSCF/SDC/GDC exhibited the lowest TEC value at $18.95{\times}10^{-6}K^{-1}$. The electrochemical performance from half cells and single cells exhibited nearly the same trend. All the composite cathodes gave higher electrochemical performance than the single BSCF cathode (0.22 $Wcm^{-2}$); however, when two kinds of electrolyte were used (BSCF/SDC/GDC, 0.36$Wcm^{-2}$), the electrochemical performance was lower than when the BSCF/SDC (0.45 $Wcm^{-2}$) or BSCF/GDC (0.45 $Wcm^{-2}$) was applied as cathode ($650^{\circ}C$, 97%$H_2$/3%$H_2O$ to the anode and ambient air to the cathode).

• Bulletin of the Korean Chemical Society
• /
• 제34권5호
• /
• pp.1462-1466
• /
• 2013

We demonstrate that ruthenium oxide ($RuO_2$) nanotubes with controlled dimensions can be synthesized using facile electrochemical means and anodic aluminum oxide (AAO) templates. $RuO_2$ nanotubes were formed using a cyclic voltammetric deposition technique and an aqueous plating solution composed of $RuCl_3$. Linear sweep voltammetry (LSV) was used to determine the effective electrochemical oxidation potential of $Ru^{3+}$ to $RuO_2$. The length and wall thickness of $RuO_2$ nanotubes can be adjusted by varying the range and cycles of the electrochemical cyclic voltammetric potentials. Thick-walled $RuO_2$ nanotubes were obtained using a wide electrochemical potential range (-0.2~1 V). In contrast, an electrochemical deposition potential range from 0.8 to 1 V produced thin-walled and longer $RuO_2$ nanotubes in an identical number of cycles. The dependence of wall thickness and length of $RuO_2$ nanotubes on the range of cyclic voltammetric electrochemical potentials was attributed to the distinct ionic diffusion times. This significantly improves the ratio of surface area to mass of materials synthesized using AAO templates. Furthermore, this study is directive to the controlled synthesis of other metal oxide nanotubes using a similar strategy.

• Journal of Electrochemical Science and Technology
• /
• 제10권3호
• /
• pp.276-283
• /
• 2019

Nitinol is an alloy of nickel and titanium. Nitinol is one of the shape memory alloys(SMA) that are restored to a remembered form, changing the crystal structure at a given temperature. Because of these unique features, it is used in medical devices, high precision sensors, and aerospace industries. However, the conventional method of mechanical machining for nitinol has problems of thermal and residual stress after processing. Therefore, the electrochemical machining(ECM), which does not produce residual stress and thermal deformation, has emerged as an alternative processing technique. In addition, to replace the existing experimental planning methods, this study used deep neural network(DNN), which is the basis for AI. This method was shown to be more useful than conventional method of design of experiments(RSM, Taguchi, Regression) by applying deep neural network(DNN) to electrochemical machining(ECM) and comparing root mean square errors(RMSE). Comparison with actual experimental values has shown that DNN is a more useful method than conventional method. (DOE - RSM, Taguchi, Regression). The result of the machining was accurately and efficiently predicted by applying electrochemical machining(ECM) and deep neural network(DNN) to the shape memory alloy(SMA), which is a hard-mechinability material.

• Journal of Electrochemical Science and Technology
• /
• 제14권2호
• /
• pp.131-138
• /
• 2023

The carbon felt is usually hired as electrodes for vanadium redox flow battery (VRFB). In the study, surface modification of carbon felt under CO₂ atmosphere with variables of operating various temperature ranges between 700℃ and 900℃. The qualitative and quantitative analysis were carried out such as scanning electron microscope (SEM) and X-ray photoelectron spectroscopy (XPS) to observe degree of surface modification. Result of XPS analysis confirmed increase of carbon and oxidation functional group on the surface with increase of temperature. SEM image was discovered similar phenomena. Electrochemical characteristics such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) revealed the improved electrode performance with increase of temperature. However, the electrochemical performance under treatments temperature of 900℃ was less than that of under treatment temperature of 850℃ due to weight loss at the treatment temperature of 900℃. From the CV and EIS results, the best electrochemical characteristics was at the temperature of 850℃. That of at the temperature of 900℃ was decreased due to weight loss. The energy efficiencies (EE) obtained from full cell test were 69.37, 80.76, 82.45, and 75.47%, at the temperature of 700, 800, 850, and 900℃, respectively.