• 제목/요약/키워드: Electrochemical parameters

검색결과 339건 처리시간 0.024초

Application of Neural Networks in Aluminum Corrosion

  • Powers, John;Ali, M. Masoom
    • Journal of the Korean Data and Information Science Society
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    • 제11권2호
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    • pp.157-172
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    • 2000
  • Metal containers represent a situation where a specific metal is exposed to a wide variety of electrolytes of varying degrees of corrosivity. For example, hundreds, if not thousands of different products are packaged in an aluminum beverage can. These products vary in pH, chloride concentration and other natural or artificial ingredients which can effect the type and severity of potential corrosion. Both localized (perforation) and uniform corrosion (metal dissolution without the onset of pitting) may occur in the can. A quick test or series of tests which could predict the propensity towards both types of corrosion would be useful to the manufacturer. Electrochemical noise data is used to detect the onset and continuation of pitting corrosion. Specific noise parameters such as the noise resistance (the potential noise divided by the current noise) have been used to both detect pitting corrosion and also to estimate the pitting severity. The utility of noise resistance and other electrochemical parameters has been explored through the application of artificial neural networks. The versatility of artificial neural networks is further demonstrated by combing electrochemical data with electrolyte properties such as pH and chloride concentration to predict both the severity of both localized and uniform corrosion.

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Electrochemical Biosensors for Biomedical and Clinical Applications: A Review

  • Rahman Md. Aminur;Park Deog-Su;Shim Yoon-Bo
    • 대한의용생체공학회:의공학회지
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    • 제26권5호
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    • pp.271-282
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    • 2005
  • There are strong demands for accurate, fast, and inexpensive devices in the medical diagnostic laboratories, such as biosensors and chemical sensors. Biosensors can provide the reliable and accurate informations on the desired biochemical parameters, which is an essential prerequisite for a patient before going for a treatment. They can be used for continuous measurements of metabolites, blood cations, gases, etc. Of these, electrochemical biosensors play an important role in the improvement of public health, because rapid detection, high sensitivity, small size, and specificity are achievable for clinical diagnostics. In this paper, the clinical applications with electrochemical biosensors are reviewed. An attempt is also made to highlight some of the trends that govern the research and developments of the important biosensors that are associated to clinical diagnosis.

Electrochemical behaviors of Indium

  • Chung, Yong-Hwa;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • 제3권1호
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    • pp.1-13
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    • 2012
  • Many researchers focus on indium contained semiconductors and alloy compounds for their various applications. Electrochemists want to obtain indium contained compounds simply via one-step electrodeposition. First of all, electrochemistry of constituent elements must be understood in order to develop the best condition for the electrodeposition of indium contained compounds. We will review the electrochemistry of indium. Equilibria between indium metal and indium ions and the standard electrode potentials of the equilibria will be reviewed. The electrochemical reactions of indium species are affected by surrounding conditions. Thus dependences of electrochemical behaviors of indium metal and indium ions on various parameters will be reviewed.

Electrochemical Impedance Spectroscopy (EIS) Performance Analysis and Challenges in Fuel Cell Applications

  • Padha, Bhavya;Verma, Sonali;Mahajan, Prerna;Arya, Sandeep
    • Journal of Electrochemical Science and Technology
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    • 제13권2호
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    • pp.167-176
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    • 2022
  • Electrochemical impedance spectroscopy (EIS) is a unique non-destructive technique employed to analyze various devices in different energy storage applications. It characterizes materials and interfaces for their properties in heterogeneous systems employing equivalent circuits as models. So far, it has been used to analyze the performance of various photovoltaic cells, fuel cells, batteries, and other energy storage devices, through equivalent circuit designing. This review highlights the diverse applications of EIS in fuel cells and specific parameters affecting its performance. A particular emphasis has been laid on the challenges faced by this technique and their possible solutions.

초박형 태양전지 제작에 Porous Silicon Layer Transfer기술 적용을 위한 전기화학적 실리콘 에칭 조건 최적화에 관한 연구 (Optimization of Electrochemical Etching Parameters in Porous Silicon Layer Transfer Process for Thin Film Solar Cell)

  • 이주영;구연수;이재호
    • 마이크로전자및패키징학회지
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    • 제18권1호
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    • pp.23-27
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    • 2011
  • 전기화학적 에칭을 이용한 다공성 실리콘 이중층 형성은 초박형 태양전지 제작에서 PS layer transfer 기술을 적용하기 위한 선행 공정이다. 다공성 실리콘 층의 다공도는 전류밀도와 에칭용액 내 불산의 농도를 조절하여 제어할 수 있다. 전기화학적 에칭을 이용한 다공성 실리콘 형성을 위하여 비저항 $0.01-0.02\;{\Omega}{\cdot}cm$의 p-type (100)의 실리콘 웨이퍼를 사용하였으며, 에칭용액의 조성은 HF (40%) : $C_2H_5OH$(99 %) : $H_2O$ = 1 : 1 : 2 (volume)으로 고정하였다. PS layer transfer 기술에 사용되는 다공성 실리콘 이중층을 형성하기 위해서 에칭 도중 전류밀도를 낮은 전류밀도 조건에서 높은 전류밀도 조건으로 변환하여 low porosity layer 하부에 high porosity layer를 형성할 수 있다.

가공 인자에 다른 미세 전해 가공 속도 변화 연구 (Study on Machining Speed according to Parameters in Micro ECM)

  • 권민호;박민수;신홍식;주종남
    • 한국정밀공학회지
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    • 제28권3호
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    • pp.308-314
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    • 2011
  • In micro electrochemical machining (micro ECM), machining conditions have been determined to maintain a small side gap and to machine a workpiece stably However, machining speed is slow. To improve machining speed while maintaining the form accuracy, the paper investigates machining parameters such as pulse amplitude, duty ratio, pulse on-time, and the electrolyte's temperature and concentration. The experiment in this study shows that the electrolyte's concentration is the key factor that can reduce machining time while maintaining the form accuracy Micro square columns were fabricated to confirm the machining parameters' effects.

1,2-Dichloroethane 내 백금 전극에서의 dicarboximide 레이저 염료에 대한 convolutive 순환 전압-전류법 연구 (Convolutive Cyclic Voltammetry Investigation of Dicarboximide Laser Dye at a Platinum Electrode in 1,2-Dichloroethane)

  • Al-Bishri, Hassan M.;El-Mossalamy, E.H.;El-Hallag, Ibrahim;El-Daly, Samy
    • 대한화학회지
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    • 제55권2호
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    • pp.169-176
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    • 2011
  • N,N-bis(2,5-di-tert-butylphenyl) - 3,4,9,10 perylenebis(dicarboximide) 레이저 염료에 대한 전기화학적 연구가 0.1 M tetrabutyl ammonium perchlorate(TBAP)/1,2 dichloroethane($CH_2Cl-CH_2Cl$) 용액내에서 백금 전극을 이용하여 순환 전압-전류법 및 디지털 시뮬레이션 기술과 결합된 convolution-deconvolution 전압-전류법으로 수행되었다. 연구에 사용된 염료는 두개의 전자를 순차적으로 소모하며 radiacal anion과 dianion으로(EE 메커니즘) 환원되었다. 전위를 positive scan으로 전환하면, 이 화합물은 두 개의 전자를 잃고 산화된 뒤 빠른 응집 과정($EC_1EC_2$ 메커니즘)을 거치게 된다. 이 화합물의 전극 반응 경로, 화학 및 전기화학적 파라미터는 순환 전압-전류법과 convolutive 전압-전류법을 이용하여 측정되었다. 이렇게 구한 전기화학적 파라미터는 디지털 시뮬레이션 방법을 통하여 검증되었다.