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http://dx.doi.org/10.5012/jkcs.2011.55.2.169

Convolutive Cyclic Voltammetry Investigation of Dicarboximide Laser Dye at a Platinum Electrode in 1,2-Dichloroethane  

Al-Bishri, Hassan M. (Chemistry Department, Faculty of Science, King Abdul-Aziz University)
El-Mossalamy, E.H. (Chemistry Department, Faculty of Science, King Abdul-Aziz University)
El-Hallag, Ibrahim (Chemistry Department, Faculty of Science, Tanta University)
El-Daly, Samy (Chemistry Department, Faculty of Science, Tanta University)
Publication Information
Journal of the Korean Chemical Society / v.55, no.2, 2011 , pp. 169-176 More about this Journal
Abstract
The electrochemical investigation of N,N-bis (2,5-di-tert-butylphenyl)-3,4,9,10 perylenebis (dicarboximide) laser dye have been carried out using cyclic voltammetry and convolution - deconvolution voltammetry combined with digital simulation technique at a platinum electrode in 0.1 mol/L tetrabutyl ammonium perchlorate (TBAP) in solvent 1,2 dichloroethane ($CH_2Cl-CH_2Cl$). The investigated dye was reduced via consumption of two sequential electrons to form radical anion and dianion (EE mechanism). In switching the potential to positive scan, the compound was oxidized by loss of two electrons, which were followed by a fast aggregation process ($EC_1EC_2$ mechanism). The electrode reaction pathway and the chemical and electrochemical parameters of the investigated compound were determined using cyclic voltammetry and convolutive voltammetry. The extracted electrochemical parameters were verified and confirmed via digital simulation method.
Keywords
Solar cells; cyclic voltammetry; convolutive voltammetry; digital simulation; electrochemical parameters;
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