• Title/Summary/Keyword: Electrochemical modeling

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State of Health estimation based on Secondary Li-ion battery Electrochemical Modeling and Electrical experiment (리튬 이차 전지의 전기화학 모델링과 전기적 실험 기반 상태 추정)

  • Kim, Su-An;Park, Seong-Yun;Kim, Jong-hoon
    • Journal of IKEEE
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    • v.24 no.4
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    • pp.1098-1103
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    • 2020
  • This paper deals with a method for estimating the battery state-of-health(SOH) through electrical experiments and electrochemical modeling of lithium-ion secondary battery. In order to confirm the actual battery SOH through the battery electrical aging experiment, the current integration method was used. The SOH is estimated using the internal resistance value derived from the electrical experiment. Also, in electrochemical modeling, the SOH is estimated through the change of the SEI layer with the increase of the number of cycles. The new SOH is derived by applying weighting factor to the three methods of estimating SOH, including the actual battery SOH.

A Review on Electrochemical Model for Predicting the Performance of Lithium Secondary Battery (리튬이차전지 성능 모사를 위한 전기화학적 모델링)

  • Yang, Seungwon;Kim, Nayeon;Kim, Eunsae;Lim, Minhong;Park, Joonam;Song, Jihun;Park, Sunho;Appiah, Williams Agyei;Ryou, Myung-Hyun;Lee, Yong Min
    • Journal of the Korean Electrochemical Society
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    • v.22 no.1
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    • pp.43-52
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    • 2019
  • As the application area of lithium secondary batteries becomes wider, performance characterization becomes difficult as well as diverse. To address this issue, battery manufacturers have to evaluate many batteries for a longer period, recruit many researchers and continuously introduce expensive equipment. Simulation techniques based on battery modeling are being introduced to solve such difficulties. Various lithium secondary battery modeling techniques have been reported so far and optimal techniques have been selected and utilized according to their purpose. In this review, the electrochemical modeling based on the Newman model is described in detail. Particularly, we will explain the physical meaning of each equation included in the model; the Butler-Volmer equation, which represents the rate of electrode reaction, the material and charge balance equations for each phase (solid and liquid), and the energy balance. Moreover, simple modeling processes and results based on COMSOL Multiphysics 5.3a will be provided and discussed.

A study on the analysis of bipolar packed-bed electrode reactor for complex reactions (복잡반응에 대한 복극성 고정층 전극반응기 해석)

  • Kim Hark-Joon
    • Journal of the Korean Electrochemical Society
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    • v.2 no.1
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    • pp.13-16
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    • 1999
  • A mathematical analysis of bipolar electrode reactor model for complex electrochemical reactions could estimate total current from time-concentration data, which coincided well with experimental total current data. Thus behaviour of bipolar electrode reactor could be described by a proposed simulation model. This paper demonstrates how such a model can be used a useful tool in the design for pilot plant experimentation.

Modeling and Applications of Electrochemical Impedance Spectroscopy (EIS) for Lithium-ion Batteries

  • Choi, Woosung;Shin, Heon-Cheol;Kim, Ji Man;Choi, Jae-Young;Yoon, Won-Sub
    • Journal of Electrochemical Science and Technology
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    • v.11 no.1
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    • pp.1-13
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    • 2020
  • As research on secondary batteries becomes important, interest in analytical methods to examine the condition of secondary batteries is also increasing. Among these methods, the electrochemical impedance spectroscopy (EIS) method is one of the most attractive diagnostic techniques due to its convenience, quickness, accuracy, and low cost. However, since the obtained spectra are complicated signals representing several impedance elements, it is necessary to understand the whole electrochemical environment for a meaningful analysis. Based on the understanding of the whole system, the circuit elements constituting the cell can be obtained through construction of a physically sound circuit model. Therefore, this mini-review will explain how to construct a physically sound circuit model according to the characteristics of the battery cell system and then introduce the relationship between the obtained resistances of the bulk (Rb), charge transfer reaction (Rct), interface layer (RSEI), diffusion process (W) and battery characteristics, such as the state of charge (SOC), temperature, and state of health (SOH).