• Journal of Industrial Convergence
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• v.21 no.9
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• pp.33-39
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• 2023

Nano-sized materials can be coated on various substrates, and since this material is transparent and conductive, it can be used as a transparent electrode for electronic devices or an electrode for power supply. In this study, CNT and Ag nanowires were repeatedly coated using the silk screen technique, and samples formed up to 5 times were fabricated, and their optical and electrical properties were measured and analyzed. It was confirmed that marks were formed on the surface of the silkscreen-coated sample according to the coating direction, and the trend of transmittance and surface resistance according to the number of times of coating was investigated. As the number of coatings increased, transmittance and surface resistance tended to decrease. In particular, in the case of transmittance, the range of change was large in the samples coated 2 and 5 times. These changes were confirmed by the Ag nanowire coating. In addition, starting from 700 nm, the previous wavelength region increased according to the wavelength, while the above showed a tendency to decrease. The surface resistance was lowered from 9Ω/cm² when coating once to 0.856Ω/cm² when coating five times. It was found that the resistance value was affected by Ag similarly to the permeability. In the future, it is necessary to realize a desired transparent electrode through Ag concentration and coating of Ag nanowires with other methods and fusion with highly transparent CNT to apply to electronic devices.

• Journal of Adhesion and Interface
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• v.25 no.1
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• pp.169-274
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• 2024

Recent attention has been drawn to materials that undergo reversible expansion and contraction in response to external stimuli, leading to morphological changes. These materials hold potential applications in various fields including soft robotics, sensors, and artificial muscles. In this study, a novel material capable of responding to high temperatures for protection or encapsulation is proposed. To achieve this, liquid crystal elastomer (LCE) with nematic-isotropic transition properties and polyimide (PI) with high mechanical strength and thermal stability were utilized. To utilize a solution process, a dope solution was synthesized and introduced into micro-printing techniques to develop a two-dimensional pattern of LCE/PI bilayer structures with sub-millimeter widths. The honeycomb-patterned LCE/PI bilayer mesh combined the mechanical strength of PI with the high-temperature contraction behavior of LCE, and selective printing of LCE facilitated deformation in desired directions at high temperatures. Consequently, the functionality of selectively and reversibly encapsulating specific high-temperature materials was achieved. This study suggests potential applications in various actuator fields where functionalities can be implemented across different temperature ranges without the need for electrical energy input, contingent upon molecular changes in LCE.

• Journal of the Korean Geotechnical Society
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• v.40 no.3
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• pp.85-91
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• 2024

To realize stable use of ground treated with cementitious materials, the curing process must be evaluated. In this study, a time domain reflectometry (TDR) measurement system was employed to evaluate the curing process of cementitious grout based on the electromagnetic property. A coated probe was manufactured to prevent electrical connection between the electrodes by the electrically conductive cementitious grout, and a calibration process was performed to estimate the actual relative permittivity using the coated probe. To assess the curing process of cementitious grout using the TDR measurement system, cementitious grout with added retarder was prepared with a water-to-cement ratio of 45%. A preliminary measurement was conducted immediately after pouring the cementitious grout into the mold to test the applicability of the coated probe, and TDR signals and relative permittivity were measured at 3~288 hours of curing time. The experimental results demonstrate that the relative permittivity of the cementitious grout immediately after pouring was greater than 100, decreased rapidly over time, and converged to approximately 13.8 at 144 hours, which is considered the fully cured time. This findings of this study demonstrate that the TDR measurement system with a coated probe is applicable to electrically conductive materials. In addition, the TDR measurement system can be used effectively to monitor the curing process of cementitious grout based on electromagnetic properties.

• The Journal of Engineering Geology
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• v.34 no.1
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• pp.1-12
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• 2024

South Korea's mining industry was actively developed until 1980, but subsequent declining profitability forced many mines to close. Most of the abandoned mines are susceptible to persistent subsidence because of the length of time since mining ceased. Accurate prediction of the locations and times of subsidence is difficult; therefore, this study aims to apply continuum analysis to past cases of subsidence to establish a method of predicting the location and magnitude of future subsidence. The study area is an area of ○○ mining located between the Yangsan fault zone and the Moryang fault zone, in which three subsidence events occurred between 2005 and 2009. Drilling surveys and electrical resistivity surveys were performed at subsidence sites determined the distribution of strata, and through laboratory tests obtained the physico-mechanical properties of the rock. Numerical analysis of the results found that the plastic status area includes the areas of actual subsidence and that continuum analysis can also be used to predict the location and magnitude of subsidence caused by mine goaf.

• Korean Chemical Engineering Research
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• v.62 no.3
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• pp.238-245
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• 2024

The lactate electrode can be utilized either as an electrode for lactate sensor to monitor the patient's health status, stress level, and athlete's fatigue in real time or lactate fuel cell. In this study, we fabricated a high-performance electrode composed of lactate oxidase, catalase, and mitochondria, and investigated the surface analysis and electrochemical properties of this electrode. Carbon paper modified with single-walled carbon nanotubes (CP-SWCNT) had significantly improved electrical conductivity compared to before modification. The electrode to which lactate oxidase, catalase, and mitochondria were attached (CP-SWCNT-LOx-Cat-Mito) produced a higher current than the electrode to which lactate oxidase and catalase were attached. The amount of reduction current produced by the bilirubin oxidase (BOD)-attached electrode (CP-SWCNT-BOD) was greatly affected by the presence or absence of oxygen in the electrolyte. The fuel cell composed of CP-SWCNT-LOx-Cat-Mito (anode) and CP-SWCNT-BOD (cathode) produced maximum power (29 ㎼/cm²) at a discharge current density of 133 ㎂/cm². From this study, we had proved that mitochondria is essential for improving lactate sensor and fuel cell performance.

• Applied Chemistry for Engineering
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• v.35 no.4
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• pp.321-328
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• 2024

The performance of carbon fluoride-based lithium primary batteries (Li/CF_X) is limited due to poor rate capability resulting from the low conductivity of carbon fluoride, which is used as the active material. Therefore, in this study, we applied a carbon coating using pyrolysis fuel oil on carbon fluoride to overcome this limitation and considered its electrochemical performance. An amorphous carbon layer was formed on the surface of the carbon fluoride through carbon coating, and the surface physicochemical properties of the carbon fluoride were meticulously considered based on the heat treatment temperature. The advanced research chemical 1000 heat treated at 450 ℃ (ARC@C450) sample, which was commercial carbon fluoride heat-treated at 450 ℃, showed the largest increase in the concentration of sp² carbon bonds (62%) and the highest formation of semi-ionic C-F bonds. Also, the primary battery using the ARC@C450 sample as a cathode active material exhibited stable discharge capability at the highest rate of 5 C (392 mAh/g), and the R_ct value was reduced by 53% compared to the untreated sample. Therefore, we proposed pyrolysis fuel oil-based carbon coating as a method to overcome the low conductivity of carbon fluoride, and the carbon-coated carbon fluoride showed excellent rate performance, suggesting its potential application in high-power primary batteries.

• Journal of Wetlands Research
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• v.26 no.3
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• pp.298-310
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• 2024

In this study, we analyzed the results of previous studies on different types of agricultural ecosystems to understand how environmental factors in soils, which serve as significant carbon reservoirs within agricultural ecosystems, a type of terrestrial ecosystem, affect soil carbon storage and soil respiration. As a result, most previous studies have been conducted on paddy field and facility cultivation area. And, the carbon storage in the soil and the soil's chemical properties, such as soil pH, electrical conductivity, soil organic matter content, and total nitrogen content, were higher in paddy field and orchard compared to field, facility cultivation area, and other cultivation area. The soil respiration in paddy field was also higher than in other types of agricultural ecosystems. Furthermore, soil carbon storage showed a significant correlation with soil organic matter (R²=0.7237, p=0.0000), total nitrogen (R²=0.8419, p=0.0000), and available phosphorus (R²=0.3123, p=0.0024), while soil respiration had a significant relationship with soil organic matter (R²=0.5644, p=0.0000). In this study, agricultural ecosystems were found to act as carbon sinks, with soil carbon storage measured at 49.1±8.9 tons C ha^-1 in orchard, 31.8±6.9 tons C ha^-1 in paddy field, and 25.3±28.0 tons C ha^-1 in facility cultivation area. Therefore, agricultural ecosystems need to manage soil carbon storage and carbon emissions through proper soil nutrient management.

• Korean Journal of Agricultural Science
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• v.51 no.3
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• pp.271-281
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• 2024

The application of biochar to soil for sustainable agriculture has been considered to have a positive impact on soil fertility and crop productivity. In this study, biochar derived from rice husk and chicken manure was applied to the soil at rates of 1% and 3% by weight, respectively, for lettuce cultivation experiments. The results indicated that both rice husk biochar and chicken manure biochar were effective in improving soil fertility through soil pH correction and increased nutrient content. The nitrogen content and pH of the biochar increased the available nitrogen and phosphate in the soil, creating a soil environment conducive to the growth enhancement of lettuce. In particular, after the application of 3% chicken manure biochar, the soil exhibited the highest levels of available nitrogen and phosphate at 87.42 mg·kg^-1 and 69.07 mg·kg^-1, respectively. Plant fresh weight increased with rising biochar amount, with the 3% chicken manure biochar treatment (228.25 g·plant^-1 fresh weight [FW]) exhibiting superior fresh weight compared to 3% rice husk biochar treatment (120.88 g·plant^-1 FW). The nutrient content in lettuce, except for K₂O, was higher in the chicken manure biochar treatment compared to the same dosage of rice husk biochar. Therefore, for enhancing lettuce productivity and soil fertility, chicken manure biochar appears to be more effective than rice husk biochar, and increasing the application rate up to 3% showed improvement effects without adverse impacts. However, excessive application of chicken manure biochar may lead to an increase in soil pH and electrical conductivity (EC) beyond the optimal range, requiring further assessment of application rates.

• Journal of Sensor Science and Technology
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• v.33 no.5
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• pp.310-317
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• 2024

Formaldehyde (HCHO) is a major primary indoor air pollutant with various adverse effects on the human body, includingsuch as sick building syndrome, lung cancer, and nasal cancer. Therefore, gas sensors for effective HCHO detection detecting HCHO are crucial for maintaining a healthy indoor environments, and research is being conducted to develop high-performance sensors for this purpose. AnOne of the effective methods for enhancing the to enhance sensing properties is involves modifying the p-n heterojunction structure, which improves sensing through via electronic sensitization based on the expanded depletion region and chemical sensitization that dissociates specific gases. In this studyHerein, weWe fabricated NiO-decorated In₂O₃ NRs using an e-beam evaporator based on the glancing angle deposition technique by optimizing the NiO thickness (0, 1, 2, and 3 nm). When exposed to 50 ppm HCHO, NiO-decorated In₂O₃ NRs showed a 3.91%-fold enhancement in the gas response (Ra/Rg-1= 23.9) and a 41.47% faster response time (40.7 s) than-compared to bare In₂O₃ NRs with an extremely low theoretical detection limit of ≈approximately 9.3 ppb.

• Journal of Sensor Science and Technology
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• v.33 no.5
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• pp.318-325
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• 2024

In this study, we fabricated TiO₂-decorated SnO₂ nanorods (TSNRs) via glancing-angle deposition to achieve highly sensitive and selective CH₃COCH₃ detection. The gas-sensing properties of the TSNRs were systematically investigated, and the optimal sensing performance was achieved at 350℃ by 2-nm-thick TSNRs. When the sensors were exposed to 50 ppm of various gases (CH₃COCH₃, C₂H₅OH, C₅H₈, CH₄, and CO), the 2-nm-thick TSNRs demonstrated a 4.6-fold increase in response (R_a/R_g-1=134) to CH₃COCH₃ compared with bare SnO₂ nanorods (R_a/R_g-1=29.5) and exhibited excellent selectivity. In a high-humid environment (relative humidity = 80%), the 2-nm-thick TSNRs indicated a low theoretical detection limit of ≈5.31 ppb for CH₃COCH₃. These results suggest the significant potential of the proposed sensor for use in Internet-of-Things applications, particularly under extreme environmental conditions.