• Title/Summary/Keyword: Electric Dipole

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Effectiveness of the Electrode Arrays for Delineating 2-D Subsurface Structure (2차원 지하구조 규명을 위한 전극배열의 효율성)

  • Yoon, Jong-Ryeol;Lee, Kiehwa
    • Economic and Environmental Geology
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    • v.29 no.3
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    • pp.345-355
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    • 1996
  • The effectiveness of various electrode configurations in horizontal mappings and 1-D inversions of vertical sounding data for delineating 2-D structures was studied. Apparent resistivity values of three point, dipole-dipole, Wenner, and Schlumberger mappings were simulated for such structures as vertical dyke, tabular prism, buried vertical fault, ramp and complex structure by finite difference method (FDM) and they were compared with each other. Also 2-D cross sections for three structures obtained by interpolation of 1-D inverted sounding data in terms of three layers were compared for Schlumberger and Wenner arrays. On these cross sections, horizontal and vertical resistivity interfaces of the 2-D structures are revealed relatively clearly. Apparent resistivity curves of Schlumberger mapping show vertical resistivity discontinuities very well. On the whole, Schlumberger array is superior to the other arrays in electric sounding as well as mapping. This study clearly indicates that interpretations of 2-D structures based on 1-D inversion are possible.

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Acetylcholinesterase(AChE)-Catalyzed Hydrolysis of Long-Chain Thiocholine Esters: Shift to a New Chemical Mechanism

  • Jung, Dai-Il;Shin, Young-Ju;Lee, Eun-Seok;Moon, Tae-sung;Yoon, Chang-No;Lee, Bong-Ho
    • Bulletin of the Korean Chemical Society
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    • v.24 no.1
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    • pp.65-69
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    • 2003
  • The kinetic and chemical mechanisms of AChE-catalyzed hydrolysis of short-chain thiocholine esters are relatively well documented. Up to propanoylthiocholine (PrTCh) the chemical mechanism is general acid-base catalysis by the active site catalytic triad. The chemical mechanism for the enzyme-catalyzed butyrylthiocholine(BuTCh) hydrolysis shifts to a parallel mechanism in which general base catalysis by E199 of direct water attack to the carbonyl carbon of the substrate. [Selwood, T., et al. J. Am. Chem. Soc. 1993, 115, 10477- 10482] The long chain thiocholine esters such as hexanoylthiocholine (HexTCh), heptanoylthiocholine (HepTCh), and octanoylthiocholine (OcTCh) are hydrolyzed by electric eel acetylcholinesterase (AChE). The kinetic parameters are determined to show that these compounds have a lower Michaelis constant than BuTCh and the pH-rate profile showed that the mechanism is similar to that of BuTCh hydrolysis. The solvent isotope effect and proton inventory of AChE-catalyzed hydrolysis of HexTCh showed that one proton transfer is involved in the transition state of the acylation stage. The relationship between the dipole moment and the Michaelis constant of the long chain thiocholine esters showed that the dipole moment is the most important factor for the binding of a substrate to the enzyme active site.

Effects of Eu3+ Concentration on the Photoluminescence Properties of Red-orange Phosphor Gd1-xPO4:Eux3+ (Eu3+ 농도가 적주황색 형광체 Gd1-xPO4:Eux3+의 발광 특성에 미치는 영향)

  • Cho, Seon-Woog
    • Korean Journal of Materials Research
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    • v.21 no.11
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    • pp.611-616
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    • 2011
  • Red-orange phosphors $Gd_{1-x}PO_4:{Eu_x}^{3+}$ (x = 0, 0.05, 0.10, 0.15, 0.20) were synthesized with changing the concentration of $Eu^{3+}$ ions using a solid-state reaction method. The crystal structures, surface morphology, and optical properties of the ceramic phosphors were investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), and photoluminescence (PL) spectrophotometry. The XRD results were in accordance with JCPDS (32-0386), and the crystal structures of all the red-orange phosphors were found to be a monoclinic system. The SEM results showed that the size of grains increases and then decreases as the concentration of $Eu^{3+}$ ionincreases. As for the PL properties, all of the ceramic phosphors, irrespective of $Eu^{3+}$ ion concentration, had orange and red emissions peaks at 594 nm and 613 nm, respectively. The maximum excitation and emission spectra were observed at 0.10 mol of $Eu^{3+}$ ion concentration, just like the grain size. An orange color stronger than the red means that $^5D_0{\rightarrow}^7F_1$ (magnetic dipole transition) is dominant over the $^5D_0{\rightarrow}^7F_2$ (electric dipole transition), and $Eu^{3+}$ is located at the center of the inversion symmetry. These properties contrasted with those of a red phosphor $Y_{1-x}PO_4:{Eu_x}^{3+}$, which has a tetragonal system. Therefore, we confirm that the crystal structure of the host material has a major effect on the resulting color.

Estimation of the Depth of Embedded Sheet Piles Using Two Types of Geophysical Loggings (다종 물리검층을 통한 시트파일 근입 심도 추정 연구)

  • Hwang, Sungpil;Kim, Wooseok;Jeoung, Jaehyeung;Kim, Kiju;Park, Byungsuk;Lee, Chulhee
    • The Journal of Engineering Geology
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    • v.32 no.4
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    • pp.525-534
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    • 2022
  • This investigation used two different geophysical logging techniques to confirm the depth to which a sheet pile was driven. Depth was estimated through analysis of the movement speed and three-component movement directions of a P-wave transmitted through the ground. It was also estimated by pole-pole and pole-dipole methods using electrical data logging to measure apparent resistivity. The two methods' respective results were 9.0 m (±1.5 m) and 7.5 m. As field ground conditions will include mixtures of various materials, electrical data logging is judged to be suitable for assessing depth due to its low signal-to-noise ratio.

Stark Effect in Molecular Exciton States (分子 Exciton 狀態에서의 Stark 效果)

  • Jo W. Lee
    • Journal of the Korean Chemical Society
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    • v.19 no.5
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    • pp.304-316
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    • 1975
  • A formal theory to explain the Stark effect in molecular exciton states is developed using the second-quantization formalism. In this theory not only the Stark effect but also the Davydov effect are explicitly taken into consideration since the observed spectral splitting in the UV spectra for molecular crystals with two or more molecules per unit cell may be the result of combination of the above two effects. Especially for molecular crystals containing two molecules in a unit cell the splitting is shown to be hyperbolically dependent upon the strength of an externally applied, uniform electric field, from which informations regarding the excited state dipole moments of a single molecule may be obtained.

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Modelling and Simulation Resolution of Ground-Penetrating Radar Antennas

  • Alsharahi, G.;Mostapha, A. Mint Mohamed;Faize, A.;Driouach, A.
    • Journal of electromagnetic engineering and science
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    • v.16 no.3
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    • pp.182-190
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    • 2016
  • The problem of resolution in antenna ground-penetrating radar (GPR) is very important for the investigation and detection of buried targets. We should solve this problem with software or a numeric method. The purposes of this paper are the modelling and simulation resolution of antenna radar GPR using three antennas, arrays (as in the software REFLEXW), the antenna dipole (as in GprMax2D), and a bow-tie antenna (as in the experimental results). The numeric code has been developed for study resolution antennas by scattered electric fields in mode B-scan. Three frequency antennas (500, 800, and 1,000 MHz) have been used in this work. The simulation results were compared with experimental results obtained by Rial and colleagues under the same conditions.

$\pi$-A properties of phospholipid monolayers by Maxwell-displacement-current-measuring technique (변위전류법에 의한 지질 단분자막의 $\pi$-A특성)

  • 이경섭;전동규;권영수;국상훈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.120-123
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    • 1995
  • Maxwell-Displacement-Currnt-Measuring Technique(MDCM) is a simple system for displacement current measuring which consist with two electrodes to the electrometer, With this method, the displacement current flow only when the electric flux density change by the displacement of molecules or charge particles of membrance on the water surface. Thus, It is Possible to detect dynamic behavior of molecules of membrane without any electrical contact with molecule membrane. In this paper, We measure surface pressure, displacement current and dipole moment of phospholipid monolayers on the wafer surface with applied pressure by MDCM and We measured DTA(differential thermal analysis).

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A study of coupling mechanism between two dipoles integrated within a conductor-backed thin dieelectric layer above earth using asymptotic evaluation (점근적 근사를 사용한 지표면 위에 놓여 있는 한쪽 면이 도체로 된 얇은 유전체 층 내부의 두 다이폴 사이의 상호 결합 원리에 관한 연구)

  • 박동국;라정웅
    • Journal of the Korean Institute of Telematics and Electronics D
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    • v.34D no.1
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    • pp.8-13
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    • 1997
  • An electric field due to point dipole within conductor-backed thin dielectric layer above the earth is calculated by using saddle point method When the dielectric layer is thin enough to support a cutoff mdoe, we show that the field may be approximated by sum of contributions of branch points of TE mode and poles of tM mode and that the branch points and poles contributions are interpreted as an evanescent lateral waves and leaky waves, respectively.

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A new red phosphor $BaZr(BO_{3})_{2}$ doped with $Eu^{3+}$ for PDP applications

  • Tian, Lian-Hua;Yu, Byung-Yong;Pyun, Chong-Hong;Mho, Sun-Il
    • 한국정보디스플레이학회:학술대회논문집
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    • 2003.07a
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    • pp.1042-1044
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    • 2003
  • The photoluminescence (PL) properties are studied for a new phosphor $BaZr(BO_{3})_{2}$ doped with $Eu^{3+}$ activator ion. The excitation spectrum shows strong absorption in the vacuum ultraviolet (VUV) region with an absorption band edge at 200 nm. The PL spectrum shows the strongest emission at 615 nm corresponding to the electric dipole $^{5}D_{0}\;{\rightarrow}\;^{7}F_{2}$ transition of $Eu^{3+}$, which results in a good color purity.

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Effect of local field on atomic systems II : Derivation of macroscopic quantum Langevin equations in two-level systems (국소장이 원자계에 미치는 영향에 대한 이론 II: 이준위 원자계에서의 거시 양자 Langevin 방정식의 유도)

  • 안성혁
    • Korean Journal of Optics and Photonics
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    • v.14 no.1
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    • pp.103-106
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    • 2003
  • The microscopic quantum Langevin equations for two-level atom electric dipole systems are derived. starting from the microscopic interaction Hamiltonian of the systems. By averaging those microscopic equations over a macroscopic region, the macroscopic quantum Langevin equations are derived and the effect of local-field corrections on the two-level systems is investigated.