• Title/Summary/Keyword: Effective size

Search Result 4,755, Processing Time 0.037 seconds

Synthesis of Hyper Crosslinked Polymer Particle Having Hydroxyl Group (하이드록시기를 갖는 Hyper Crosslinked 고분자 입자의 합성)

  • Jeon, Hyo-Jin;Kim, Dong-Ok;Park, Jea-Sung;Kim, Jong-Sik;Kim, Dong-Wook;Jung, Mi-Sun;Shin, Seong-Whan;Lee, Sang-Wook
    • Polymer(Korea)
    • /
    • v.35 no.1
    • /
    • pp.66-71
    • /
    • 2011
  • With the synthesis of hyper crosslinked polymer particle (HCPP), having microporous structure with hydroxyl functional group, synthesized via polymerization reaction consists of three stepssuspension polymerization, hyper crosslinking by Friedel-Craft catalysis and hydrolysis reaction, the effects of the ratio of each monomer, hyper crosslinking conditions and $CO_2$ supercritical drying on the variations of surface morphology, pore size & distribution and BET surface area of HCPP have been investigated. It was observed that the formation of surface crack or fracture of HCPP was intimately related with the degree of hyper crosslinking reaction between microphase separated domains. And the value of BET surface area of HCPP increased with the increase of reaction temperature, time and the amounts of solvent used in hyper crosslinking step. Moreover, $CO_2$ supercritical drying was proven to be a very effective method for removing stabilizer, unreacted monomers and oligomers from HCPP but needed to add methanol as a co-solvent for efficient removing of residual catalyst.

Spray-dried powder preparation of pumpkin sweet potato hydrolysates and its physicochemical properties (호박고구마 효소 분해물의 분무건조 분말 제조 및 물리화학적 품질특성)

  • Lee, Dae-Hoon;Jang, Jong-Hyun;Hong, Joo-Heon
    • Food Science and Preservation
    • /
    • v.24 no.2
    • /
    • pp.246-253
    • /
    • 2017
  • This study was conducted prepare spray-dried powder using pumpkin sweet potato hydrolysates and examine the physicochemical properties of the powder. The insoluble dietary fiber and soluble dietary fiber of the pumpkin sweet potato treated by enzyme were 4.17% and 2.07%, respectively. The spray-dried pumpkin sweet potato hydrolysates was manufactured via spray-drying with different forming agents: i.e., pectin 0.1%, 0.5%, 1%, and 2.0%. The moisture contents and total starches of the spray-dried powders were approximately 1.68-2.46 and 45.32-46.51%, respectively. The color of the L and a value decreased, and that of the b and ${\Delta}E$ value increased. The particle size and outer topology of the spray-dried powders were $37.17-42.32{\mu}m$, and its shape was generally globular. The water absorption index of the spray-dried powder (1.74-1.91) was lower than that of the freeze-dried powder (2.15). The water solubility index of the spray-dried powder, 80.75-87.61%, was higher than that of the freeze-dried powder (70.47%). The adhesion values of spray-dried powder to epithelial HT-29 cells were 2.66-6.18% of the initial cell counts, whereas freeze-dried powder showed lower adhesive ability (1.79%). The in vitro human digestibility in the spray-dried powder was 70.09% which is very effective in digestion.

The Mediating Effect of Job Satisfaction between Organizational Members' Turnover Intention and the Leadership Type of Middle Managers in Agricultural Cooperatives (농협 조직구성원의 이직 의도와 중간관리자의 리더십 유형 관계에서 직무만족도의 매개효과)

  • Jeon, Young-Gil
    • Journal of Digital Convergence
    • /
    • v.13 no.3
    • /
    • pp.85-93
    • /
    • 2015
  • There are the leadership is the main factor for managing effective organization as the size of organization becomes large and its functions are a complex and rapidly changing environment. Therefore it needs to suggest the desirable direction for managing organization by the effect of middle manager's leadership on organization's effectiveness. The aim of the present study is to investigate the proper leadership type of middle manager through the mediating effect of job satisfaction between turnover intention and leadership type recognized of organizational members. It suggested the guidelines for the proper leaderships type and the efficient management for employees through the findings. To test hypotheses, the leadership types are classified and the data of this study has collected to evaluate middle managers from the actual employees of agricultural cooperatives in Nonghyup. Through the findings of this study, it is expected the organizational convergence and provides guidelines in managing the agriculture organization to suggest implications and future research directions.

The Treatment of Heavy Metal Hydroxides by Crossflow-Microfiltration (정밀여과에 의한 중금속수산화물의 처리)

  • Yoo, Kun-Woo;Seo, Hyung-Joon
    • Clean Technology
    • /
    • v.8 no.3
    • /
    • pp.151-165
    • /
    • 2002
  • In the treatment of the wastewater containing metals($Cu^{2+}$, $Zn^{2+}$, $Ni^{2+}$, $Cr^{3+}$) by using batch precipitation and flocculation followed by membrane filtration, permeate flux and removal efficiency were investigated according to by the effect of pH and coagulants, and the type of membranes used and pore size. It was found that it is most effective to use $0.45{\mu}m$-polysulfone membrane and coagulant(PAC) at the conditions of the pH of 10.0~10.5 for the case of copper containing wastewater, $0.1{\mu}m$-PVDF membrane and coagulant(PAC) at the conditions of the pH of 10.0~10.5 for the case of zinc containing wastewater, $0.1{\mu}m$-PVDF membrane and coagulant at the conditions of the pH of 11.0~11.5 for the case of nickel containing wastewater, $0.2{\mu}m$ membrane and coagulant at the conditions of the pH of 8.0~8.5 for the case of chromic containing wastewater, and $0.2{\mu}m{\sim}0.45{\mu}m$ membrane and coagulant at the conditions of the pH of 11.0~11.5 for the case mixture wastewater. The permeate flux could higher as to be used coagulants except for the case of copper containing wastewater.

  • PDF

Detection of Water Cloud Microphysical Properties Using Multi-scattering Polarization Lidar

  • Xie, Jiaming;Huang, Xingyou;Bu, Lingbing;Zhang, Hengheng;Mustafa, Farhan;Chu, Chenxi
    • Current Optics and Photonics
    • /
    • v.4 no.3
    • /
    • pp.174-185
    • /
    • 2020
  • Multiscattering occurs when a laser transmits into dense atmosphere targets (e.g. fogs, smoke or clouds), which can cause depolarization effects even though the scattering particles are spherical. In addition, multiscattering effects have additional information about microphysical properties of scatterers. Thus, multiscattering can be utilized to study the microphysical properties of the liquid water cloud. In this paper, a Monte Carlo method was used to simulate multi-scattering transmission properties of Lidar signals in the cloud. The results showed the slope of the degree of linear polarization (SLDLP) can be used to invert the extinction coefficient, and then the cloud effective size (CES) and the liquid water content (LWC) may be easily obtained by using the extinction coefficient and saturation of the degree of linear polarization (SADLP). Based on calculation results, a microphysical properties inversion method for a liquid cloud was presented. An innovative multiscattering polarization Lidar (MSPL) system was constructed to measure the LWC and CES of the liquid cloud, and a new method based on the polarization splitting ratio of the Polarization Beam Splitter (PBS) was developed to calibrate the polarization channels of MSPL. By analyzing the typical observation data of MSPL observation in the northern suburbs of Nanjing, China, the LWC and CES of the liquid water cloud were obtained. Comparisons between the results from the MSPL, MODIS and the Microwave radar data showed that, the microphysical properties of liquid cloud could be retrieved by combining our MSPL and the inversion method.

Phase Behavior of Simvastatin Drug in Mixtures of Dichloromethane and Supercritical Carbon Dioxide and Microparticle Formation of Simvastatin Drug Usins Supercritical Anti-Solvent Process (디클로로메탄과 초임계 이산화탄소의 혼합용매에서 Simvastatin 약물의 상거동과 초임계 역용매 공정을 이용한 Simvastatin 약물 미세입자의 제조)

  • Oh, Dong-Joon;Lee, Byung-Chul
    • Clean Technology
    • /
    • v.13 no.1 s.36
    • /
    • pp.34-45
    • /
    • 2007
  • Phase behavior of the ternary systems of water-insoluble simvastatin drug, which is well known to be effective drugs for hypercholesterolemia therapy, in solvent mixtures of dichloromethane and supercritical carbon dioxide was investigated to present a guideline of establishing operating conditions in the particle formation of the drugs by a supercritical anti-solvent recrystallization process utilizing dichloromethane as a solvent and carbon dioxide as an anti-solvent. The solubilities of simvastatin in the mixtures of dichloromethane and carbon dioxide were determined as functions of temperature, pressure and solvent composition by measuring the cloud points of the ternary mixtures at various conditions using a high-pressure phase equilibrium apparatus equipped with a variable-volume view cell. The solubility of the drug increased as the dichloromethane composition in solution and the system pressure increases at a fixed temperature. A lower solubility of the drug was obtained at a higher temperature. The second half of this work is focused on the particle formation of the simvastatin drug by a supercritical anti-solvent recrystallization process in a cylindrical high-pressure vessel equipped with an impeller. Microparticles of the simvastatin drug were prepared as functions of pressure (8 MPa to 12 MPa), temperature (303.15 K, 313,15 K), feed flow rate of carbon dioxide, and stirring speed (up to 3000 rpm), in order to observe the effect of those process parameters on the size and shape of the drug microparticles recrystallized.

  • PDF

Full-scale EFC Study on Oil Recovery and Reuse from Discharge Gas of Tenter Facility in Textile Industry (Full-scale EFC (Electric Fume Collector)를 활용한 텐타공정 배출가스 정화 및 오일 회수)

  • Hwang, Yeal-Soon;Park, Hee-Jae;Chung, Gu-Hoi;Kim, Duk-Hyun;Na, Byung-Ki
    • Clean Technology
    • /
    • v.17 no.3
    • /
    • pp.259-265
    • /
    • 2011
  • The textile industry is suffered from air pollution problems which must be resolved. In particular, white smoke and odor after the tenter process require abatement. The major air pollution problem in the textile industry occurs during the finishing stages, where various chemicals are used for coating the fabrics. Lubricating oils, plasticizers, and water repellent chemicals are the fabric treatment chemicals. The coated fabrics are cured by heating in tenter facility. In this process, most of air pollutants emitted into the air. White smoke is basically made up of tiny solid or liquid particles of VOCs less than one micron in size. The oil mist can be carried over long distance from their point of origin. The most effective method of removing odor from tenter process is to get rid of tiny oil mist at the emitted gas. For this reason, the full-scale EFC (Electric Fume Collector) of 700 CMM was tested for removing odorous substances emitted from tenter facility. As a result of this study, odor and white smoke can be eliminated effectively and quite large amounts of oil can be recovered.

Capability of CO2 on Metal-Organic Frameworks-Based Porous Adsorbents and Their Challenges to Pressure Swing Adsorption Applications (금속-유기 골격계 다공성 흡착제의 이산화탄소 흡착성능과 압력순환흡착 공정 적용의 문제점)

  • Kim, Moon Hyeon;Choi, Sang Ok;Choo, Soo Tae
    • Clean Technology
    • /
    • v.19 no.4
    • /
    • pp.370-378
    • /
    • 2013
  • This review has shown the capability of MOFs and ZIFs materials to adsorb $CO_2$ under typical PSA temperatures and pressures. The usual operating conditions are adsorption temperatures of $15{\sim}40^{\circ}C$ and adsorption pressures of 4~6 bar based on numerous PSA processes which are widely employed in gases industry for adsorptive separation of $CO_2$. The extent of $CO_2$ adsorption on the microporous materials depends on the metal species and organic linkers existing in the frameworks. The pore size and the surface area, and the process variables are the key parameters to be associated with the efficiency of the adsorbents, particularly adsorption pressures if other variables are comparable each other. The MOFs and ZIFs materials require high pressures greater than 15 bar to yield significant $CO_2$ uptakes. They possess a $CO_2$ adsorption capacity which is very similar to or less than that of conventional benchmark adsorbents such as zeolites and activated carbons. Consequently, those materials have been much less cost-effective for adsorptive $CO_2$ separation to date because of very high production price and the absence of commercially-proven PSA processes using such new adsorbents.

Design of In-Wheel Motor for Automobiles Using Parameter Map (파라미터 맵을 이용한 차량용 인휠 전동기의 설계)

  • Kim, Hae-Joong;Lee, Choong-Sung;Hong, Jung-Pyo
    • Journal of the Korean Magnetics Society
    • /
    • v.25 no.3
    • /
    • pp.92-100
    • /
    • 2015
  • Electric Vehicle (EV) can be categorized by the driving method into in-wheel and in-line types. In-wheel type EV does not have transmission shaft, differential gear and other parts that are used in conventional cars, which simplifies and lightens the structure resulting in higher efficiency. In this paper, design method for in-wheel motor for automobiles using Parameter Map is proposed, and motor with continuous power of 5 kW is designed, built and its performance is verified. To decide the capacity of the in-wheel motor that meets the automobile's requirement, Vehicle Dynamic Simulation considering the total mass of vehicle, gear efficiency, effective radius of tire, slope ratio and others is performed. Through this step, the motor's capacity is decided and initial design to determine the motor shape and size is performed. Next, the motor parameters that meet the requirement is determined using parametric design that uses parametric map. After the motor parameters are decided using parametric map, optimal design to improve THD of back EMF, cogging torque, torque ripple and other factors is performed. The final design was built, and performance analysis and verification of the proposed method is conducted by performing load test.

Is higher dose always the right answer in stereotactic body radiation therapy for small hepatocellular carcinoma?

  • Lee, Kyung Hwa;Yu, Jeong Il;Park, Hee Chul;Park, Su Yeon;Shin, Jung Suk;Shin, Eun Hyuk;Cho, Sungkoo;Jung, Sang Hoon;Han, Young Yih;Lim, Do Hoon
    • Radiation Oncology Journal
    • /
    • v.36 no.2
    • /
    • pp.129-138
    • /
    • 2018
  • Purpose: This study was conducted to compare clinical outcomes and treatment-related toxicities after stereotactic body radiation therapy (SBRT) with two different dose regimens for small hepatocellular carcinomas (HCC) ${\leq}3cm$ in size. Materials and Methods: We retrospectively reviewed 44 patients with liver-confined HCC treated between 2009 and 2014 with SBRT. Total doses of 45 Gy (n = 10) or 60 Gy (n = 34) in 3 fractions were prescribed to the 95% isodose line covering 95% of the planning target volume. Rates of local control (LC), intrahepatic failure-free survival (IHFFS), distant metastasis-free survival (DMFS), and overall survival (OS) were calculated using the Kaplan-Meier method. Results: Median follow-up was 29 months (range, 8 to 64 months). Rates at 1 and 3 years were 97.7% and 95.0% for LC, 97.7% and 80.7% for OS, 76% and 40.5% for IHFFS, and 87.3% and 79.5% for DMFS. Five patients (11.4%) experienced degradation of albumin-bilirubin grade, 2 (4.5%) degradation of Child-Pugh score, and 4 (9.1%) grade 3 or greater laboratory abnormalities within 3 months after SBRT. No significant difference was seen in any oncological outcomes or treatment-related toxicities between the two dose regimens. Conclusions: SBRT was highly effective for local control without severe toxicities in patients with HCC smaller than 3 cm. The regimen of a total dose of 45 Gy in 3 fractions was comparable to 60 Gy in efficacy and safety of SBRT for small HCC.