• Title/Summary/Keyword: EVAPORATION

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Measurement of Evaporation Rates for Lanthanum and Neodymium Chlorides

  • Kwon, S.W.;Lee, Y.S.;Jung, J.H.;Chang, J.H.;Kim, S.H.;Lee, S.J.
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2017.10a
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    • pp.74-74
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    • 2017
  • Electrorefining is a key step in pyroprocessing. The electrorefining process is generally composed of two recovery steps - the deposit of uranium onto a solid cathode and the recovery of the remaining uranium and TRU elements simultaneously by a liquid cadmium cathode. Uranium deposit recovered from the solid cathode is a dendritic powder. It is necessary to separate the adhered salt from the deposits prior to the consolidation of uranium deposit. The adhered salt is composed of lithium, potassium, uranium, and rare earth chlorides. Distillation process was employed for the cathode processing. One of the operation methods is distillation of the salt at low temperature ($900^{\circ}C$), and then melting of the deposit at high temperature to avoid a backward reaction. For the development of the salt distiller, the distillation behavior of the low vapor pressure chlorides should be studied. Rare earth chlorides in the adhered salt of uranium deposits have relatively low vapor pressures compared to the process salt (LiCl-KCl). In this study, the evaporation rates of the lanthanum and neodymium chlorides were measured for the salt separation from electrorefiner uranium deposits in the temperature range of $825{\sim}910^{\circ}C$. The evaporation rate of both chlorides increased with an increasing templerature. The evaporation rate of lanthanum chloride varied from 0.12 to $1.68g/cm^2/h$. Neodymium chloride was more volatile than lanthanum chloride. The evaporation rate of neodymium chloride varied from 0.20 to $4.55g/cm^2/h$. The evaporation rate of both chlorides are more than $1g/cm^2/h$ at $900^{\circ}C$. Even though the evaporation rates of both chlorides were less than that of the process salt, the contents of the lanthanide chlorides were small in the adhered salt. Therefore it can be concluded that $900^{\circ}C$ is suitable for the operation temperature of the salt distiller.

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A Study on the Acquisition Technique of Water Retention Characteristics Based on the Evaporation Method and the Chilled Mirror Method for Unsaturated Soils (증발법과 냉각거울법에 의한 불포화토의 함수특성 획득기법 연구)

  • Oh, Seboong;Yoo, Younggeun;Park, Gyusoon;Kim, Seongjin
    • Journal of the Korean GEO-environmental Society
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    • v.23 no.4
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    • pp.11-20
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    • 2022
  • In order to acquire hydraulic characteristics for unsaturated layers, water retention tests were performed and compared by using the evaporation method, volumetric pressure plate extractor (VPPE) and chilled-mirror dew point method. The evaporation and chilled-mirror method are currently developed experimental technology and measure the water retention curve of unsaturated soils quickly and accurately. In the evaporation and VPPE method, the water retention has been measured and compared until 100kPa matric suction and consequently the result of the evaporation method could be verified. In the chilled-mirror method, the water retention has been measured until high level of matric suction and the overall shape of water retention curves could be obtained. As a result of water retention tests, the representative water retention curves were obtained and the applicability of each test method was discussed. Using both the evaporation and chilled-mirror methods, the soil water retention curve can be acquired reasonably for the whole range of matric suction.

Survey of High School Student and Chemistry Teacher Perceptions and Analysis of Textbook Contents Related to the Effect of Water Vapor in the Air on Evaporation and Boiling (대기 중의 수증기량이 증발과 끓음에 미치는 영향에 대한 고등학생과 화학 전공 교사들의 인식 조사 및 관련 교과서 내용 분석)

  • Paik, Seoung-Hey;Cho, Mi-Jeong
    • Journal of The Korean Association For Science Education
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    • v.25 no.7
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    • pp.773-786
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    • 2005
  • This study investigated high school student and chemistry teacher perceptions on the effect of water vapor in the air on evaporation and boiling of water by a questionnaire. In science textbooks evaporation and the boiling of water are related to the vaporization concept, boiling is related to vapor pressure and air pressure, and vapor pressure is related to the vapor concept in the air. High school student and chemistry teacher perceptions on these linkages were compared. Science textbooks were also analyzed for reasons behind these diverse perceptions. Results revealed that a majority of students conceptualized that vapor in the air was related to evaporation and boiling, but were unable to distinguish the evaporation phenomena at the macroscopic level and the evaporation of water molecules at the microscopic level. They also thought that vapor in the air affected vapor pressure and boiling. Although the percentage of teacher scientific conception was higher, a great number of teachers had diverse perceptions on evaporation and boiling just as students had. Common explanations of evaporation and boiling phenomena in science textbooks were at the macroscopic level. Moreover, there were few connections of concepts even if the explanations were at the microscopic level.

Effects of Evaporation Processes and a Reduction Annealing on Thermoelectric Properties of the Sb-Te Thin Films (증착공정 및 환원분위기 열처리가 Sb-Te 박막의 열전특성에 미치는 영향)

  • Bae, Jae-Man;Kim, Min-Young;Oh, Tae-Sung
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.4
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    • pp.77-82
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    • 2010
  • Effects of evaporation processes and a reduction annealing on thermoelectric properties of the Sb-Te thin films prepared by thermal evaporation have been investigated. The thin film evaporated by using the powders formed by crushing a $Sb_2Te_3$ ingot as an evaporation source exhibited a power factor of $2.71{\times}10^{-4}W/m-K^2$. The thin film processed by evaporation of the mixed powders of Sb and Te as an evaporation source showed a power factor of $0.12{\times}10^{-4}W/m-K^2$. The thin film fabricated by coevaporation of Sb and Te dual evaporation sources possessed a power factor of $0.73{\times}10^{-4}W/m-K^2$. With a reduction annealing at $300^{\circ}C$ for 2 hrs, the power factors of the films evaporated by using the $Sb_2Te_3$ ingot-crushed powders and coevaporated with Sb and Te dual evaporation sources were remarkably improved to $24.1{\times}10^{-4}W/m-K^2$ and $40.2{\times}10^{-4}W/m-K^2$, respectively.

Experimental study on characteristics of evaporation heat transfer of $CO_2$ in horizontal micro-channel tube (수평 다채널관 내 이산화탄소의 증발 열전달 특성에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.2200-2205
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    • 2007
  • In order to investigate the variation on a heat transfer coefficient during evaporation of $CO_2$, basic experiment on the evaporation heat transfer characteristics in a horizontal micro-channel tube was performed. Hydraulic diameters of micro-channels were 0.68 and 1.46 mm. The experiment apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiments were conducted for various mass fluxes of 300 to 800 kg/$m^2s$, heat fluxes of 10 to 40 kW/$m^2$ and saturation temperatures of -5 to 5$^{\circ}C$. With the increase heat flux, the evaporation heat transfer coefficient increased. And the significantly change of the heat transfer coefficient was observed at any heat flux and mass flux. As the saturation temperature increased and the hydraulic diameter decreased, the heat transfer coefficient increased.

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Evaporation Heat Transfer Characteristics of Carbon Dioxide in the Inner Diameter Tube of 4.57 mm (4.57 mm 세관 열교환기 내 이산화탄소의 증발열전달 특성)

  • Ku, Hak-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.31 no.2
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    • pp.145-151
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    • 2007
  • The evaporation heat transfer coefficient of $CO_2$(R-744) in a horizontal tube was investigated experimentally. The main components or the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator(test section). The test section consists of a smooth, horizontal stainless steel tube of inner diameter of 4.57 mm. The experiments were conducted at mass flux of 200 to $500\;kg/m^2s$, saturation temperature of -5 to $5^{\circ}C$, and heat flux of 10 to $40\;kW/m^2$. The test results showed the heat transfer of $CO_2$ has a greater effect on nucleate boiling more than convective boiling. Mass flux of $CO_2$ does not effect nucleate boiling too much. In comparison with test results and existing correlations, the best fit of the present experimental data is obtained with the correlation of Jung et al. But existing correlations failed to predict the evaporation heat transfer coefficient of $CO_2$, therefore, it is necessary to develope reliable and accurate predictions determining the evaporation heat transfer coefficient of $CO_2$ in a horizontal tube.

The Effect of Geometrical Structure on the Moisture Transport Properties of Nonwoven Batting Materials (부직포 충전재의 구조적 특성이 수분전달 특성에 미치는 영향-단층구조와 이층구조 부직포의 비교-)

  • 김희숙;나미희
    • Journal of the Korean Society of Clothing and Textiles
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    • v.24 no.6
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    • pp.810-818
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    • 2000
  • The purpose of this study was to analyze the effect of geometrical structure on the moisture transport properties of nonwoven batting materials. Two types of nonwovens were used such as single and double layered nonwovens. Steady and dynamic state water vapor transport properties were measured by absorption, evaporation and cobaltous chloride method respectively. The results of this study were as follows: 1) Geometrical structure affected water vapor evaporation, but there were no differences between single and double layered nonwovens in moisture absorption. Thickness and air permeability were influencing factor on water vapor transport rate. 2) Directionality of double layered nonwoven was observed both in steady and dynamic state moisture transport. There were differences between upper and lower layer of double layered nonwoven both in moisture absorption rate and color change by cobaltous chloride method. 3) In dynamic state of water vapor transport rate, single layered nonwoven reached more rapidly at the established relative humidity. It was confirmed that geometrical structure affected water vapor evaporation and hydrophilicity of fiber affected moisture absorption because there were much more water vapor transport rate by evaporation than absorption within the same period of time.

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Study on the evaporation of high melting temperature metal by using the manufactured electron hem gun system (전자총 시스템 제작과 이를 이용한 고융점 금속 증발에 관한 연구)

  • 정의창;노시표;김철중
    • Journal of the Korean Vacuum Society
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    • v.12 no.1
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    • pp.1-6
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    • 2003
  • An axial electron beam gun system, which emits the electron beam power of 50 kW, has been manufactured. The electron beam gun consists of two parts. One is the electron beam generation part. including the filament, cathode, and anode. The maximum beam current is 2 A and the acceleration voltage is 25 kV. The other part includes the focusing-, deflection-, and scanning coils. The beam diameter and ham trajectory can be controlled by these coils. The characteristic of each part is measured ior the optimum condition of evaporation process. Moreover, Helmholtz coil is installed inside the vacuum chamber to adjust the incident angel of the beam to the melting surface for the maximum evaporation. We report on the evaporation rates for zirconium(Zr) and gadolinium(Gd) metals which have the high melting temperatures.

Design and Evaluation of Multiple Effect Evaporator Systems According to the Steam Ejector Position (증기 이젝터 위치에 따른 다중효용증발시스템의 설계 및 성능분석)

  • Kim, Deukwon;Choi, Sangmin
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.28 no.11
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    • pp.434-443
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    • 2016
  • The evaporation of water from an aqueous solution is widely used in the food, desalination, pulp, and chemical industries. Usually, a large amount of energy is consumed in the evaporation process to boil off water due to atmospheric pressure. As a way of improving the energy efficiency of the evaporation process, the combination of multiple effect evaporation and thermal vapor recompression has been proposed and has become a successful technique. In this study, 4 multiple-effect falling film type evaporators for sugar solution are designed and the energy efficiency of the system is analyzed in response to the selection of the steam ejector position. Energy efficiency is increased and vapor is more compressed in the steam ejector as the Thermal Vapor Recompression (TVR) is arranged in the rear part of the evaporator system. A simplified 0-dimensional evaporator model is developed using non-linear equations derived from mass balances, energy balances, and heat transfer equations. Steam economy is calculated to compare the evaporation performance of the 4 proposed evaporators. The entrainment ratio, compression ratio, and expansion ratio are computed to check the ejector performance.

Analysis of Concepts Related to Explanations of Evaporation and Boiling in Secondary School Science Textbooks (중등 과학교과서에서 증발, 끓음의 설명에 제시된 개념간의 관련 정도 분석)

  • Paik, Seong-Hey;Jeong, Ae-Kyung;Ko, Young-Hwan
    • Journal of The Korean Association For Science Education
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    • v.24 no.3
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    • pp.429-441
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    • 2004
  • This study was to examine the concepts using to explain evaporation and boiling in secondary school science textbooks developed in 6th and 7th science curriculum. The types of explanations were compared with maps represented the concepts relationships divided into middle and high schools, 6th and 7th curriculum, and subjects and chapters to find explanation diversity. The difference of explanations related to evaporation and boiling concepts was found in the school levels and subjects. There were few relationships between the main concepts of evaporation phenomena and those of boiling phenomena.