• Title/Summary/Keyword: EDTA

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STUDIES ON THE SHELLFISH PROCESSING 2. Effect of Dehydration Method, EDTA or BHA Treatment on the Pigment Retention and the Water Absorbing Capacity of the Dehydrated Meat of the Surf Clam Mactra Sulcataria REEVE (패류 가공에 관한 연구 2. 건조 방법 및 EDTA, BHA처리가 개량조개 Mactra Sulcataria REEVE의 색소 잔존율 및 흡수율에 미치는 영향에 대하여)

  • LEE Eung-Ho;HUR Jong-Wha
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.3 no.1
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    • pp.33-37
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    • 1970
  • The effect of the dehydration method and EDTA or BHA treatment upon the pigment degradation and water re-absorption of the dehydrated meat of the surf clam Mactra Sulcataria REEVE was studied. Sun drying Produced a realer decrease in pigment content as compared to that produced by hot-air dehydration. The hot-air dehydrated product which was treated with BHA showed little pigment loss in comparison with the pigment of the fresh surf clam meat. The BHA treatment upon the dehydrated surf clam products had an outstanding effect on the pigment retention and the EDTA treated one had a weak effect on it. The hot-air dehydrated products more rapidly re-absorbed water than the sun dried one. It could be seen that there was tittle difference among the rate of rehydration of the BHA or EDTA treated product and untreated one.

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Treatment of Wastewater Containing Cu(II)-EDTA Using Ferrate in Sequencing Batch Scale System (연속회분식 반응 장치에서 Ferrate를 이용한 Cu(II)-EDTA 함유 폐수 처리 연구)

  • Kim, Hyoung-Uk;Kim, Byeong-Kwon;Lee, Seung-Mok;Yang, Jae-Kyu;Kim, Hyun-Ook;Kwan, Jung-An;Im, Hang-Sik
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.7
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    • pp.729-734
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    • 2008
  • The higher valence state of iron i.e., Fe(VI) was employed for the treatment of Cu(II)-EDTA in the aqueous/waste waters. The ferrate(VI) was prepared through wet oxidation of Fe(III) by sodium hypochlorite. The purity of prepared Fe(VI) was above 93%. The stability of Fe(VI) solution decreased as solution pH decreased through self decomposition. The reduction of Fe(VI) was obtained by using the UV-Visible measurements. The dissociation of Cu(II)-EDTA complex through oxidation of EDTA using Fe(VI) and subsequent treatment of organic matter and metal ions by Fe(III) reduced from Fe(VI) in bench-scale of continuous flow reactor were studied. The removal efficiencies of copper were 69% and 79% in pH control basin and reactor, respectively, at 120 minutes as retention time. In addition, Cu(II)-EDTA in the reactor was decomplexated more than 80% after 120 minutes as retention time. From this work, a continuous treatment process for the wastewater containing metal and EDTA by employing Fe(VI) as muluti-functional agent was developed.

A Study of Heavy Metal-Contaminated Soil Remediation with a EDTA and Boric acid Composite(II): Cd and Cr (EDTA와 붕산 혼합용출제를 이용한 중금속으로 오염된 토양의 처리에 관한 연구(II): 카드뮴 및 크롬)

  • Lee Jong-Yeol;Kim Yong-Soo;Kwon Young-Ho;Kong Sung-Ho;Park Shin-Young;Lee Chang-Hwan;Sung Hae-Ryun
    • Journal of Soil and Groundwater Environment
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    • v.9 no.4
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    • pp.8-14
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    • 2004
  • To investigate the optimal operation factors in appling Soil Flushing Process, which use EDTA and boric acid composite as a flushing reagent, to the Cd(cadmium) and Cr(chromium) contaminated sites, Cd and Cr emediation rate was investigated at various experimental conditions; as EDTA concentration was increased from 0.001M to 0.1M, Cd remediation rate was increased from $73.2\%\;to\;98.5\%$; as boric acid concentration was increased from 0.001M to 0.1M, Cr remediation rate was increased from $59.2\%\;to\;99.0\%$. In the experiments using 0.005M of EDTA and 0.005M of boric acid composite as a flushing reagent at different pH regimes, Cd remediation rate was decreased from $92.4\%\;to;80.9\%$ as the pH was increased from 3 to 7. But Cr remediation rate was more effective ($70.4\%$) at pH 5 compared to the other pHs. Furthermore, at pH 5, Cd and Cr remediation rate was investigated at different molecular ratio of [EDTA]/[Boric aicd]; the optimized [EDTA]/[Boric acid] ratio was 0.01M/0.1M for Cd contaminated site and, as the concentration of boric acid was increased over 0.1M, Cr remediation rate was also increased. So the similar results were shown in the experiments using real contaminated soils which were sampled from a mining and a industrial area.

Combination Effects of EDTA-Tris and Antibiotics on Bovine Mastitis Pathogens in Bovine Milk (우유즙중에서 유방염 세균에 대한 EDTA- Tris와 항생제병용의 항균효과)

  • Choi Jun-Pyo;Han Hong-Ryul
    • Journal of Veterinary Clinics
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    • v.5 no.2
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    • pp.73-81
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    • 1988
  • Combinations of EDTA-Tris and gentamicin, oxytetracycline in normal bovine milk were examined for synergistic activities aganist Staphylococcus aureus, Streptococcus agalactiae, Corynebacterium Pyogenes, Escherichia coli, Salmonella dublin, Pseudomonas aeruginosa, and proteus spp. isolated from the milk of acute clinical bovine mastitis. The results were summarized as follows: 1. The minimal inhibitory concentrations of EDTA-Tris and gentamicin, oxytetracycline on Escherichia coli, Salmonella dublin, proteus spp., Pseudomonas aeruginosa, Staphylococcus aureus, and Streptococcus agalactiae were markedly reduced. 2. The significant synergistic effects observed when the microorganisms were reacted with EDTA-Tris and gentamicin, oxytetracycline. These findings were respectively verified by kinetic studies of microbial death, using one-fourth minimal inhibitory concentrations of EDTA-Tris, gentamicin, and oxytetracycline.

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A Simple EDTA Titration Method for the Determination of Lead in Monazite (모나자이트 중의 납 정량을 위한 신속한 EDTA 적정법)

  • Chul Lee;Won Ji Cho
    • Journal of the Korean Chemical Society
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    • v.13 no.4
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    • pp.313-316
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    • 1969
  • In this paper a simple and rapid method is described for the determination of lead in monazite. A monazite sample was dissolved with hot concentrated sulfuric acid and diluted to 200 ml with distilled water. Lead is quatitatively separated by coprecipitating with strontium. Lead-strontium sulfate is dissolved in 3N NaOH soluion. An excess Zn-EDTA is added. The remaining zinc ion is titrated with standard 0.01 M EDTA solution using xylenol orange as indicator at pH 5 in the presence of KCN and acetyl acetone as masking agents.

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Effects of HCl and EDTA on Soil Washing to Remediate Lead-contaminated Soil in a Firing Range (사격장 납 오염토양 복원을 위한 토양세척시 HCl과 EDTA의 영향 연구)

  • Kim, Hyo-Sik;Choi, Sang-Il
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.60-66
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    • 2008
  • Laboratory soil washing experiments with HCl or EDTA were conducted to remediate lead-contaminated soil in a firing range. After lead bullets were removed by standard sieve #18 (1.0 mM), Pb concentrations were measured by EPA Method 3050B (9,443 mg/kg) and Korea Standard Test (4,803.5 mg/kg). The results of the batch test showed that the removal efficiency curve was logarithmic and approximately 90% of lead in soil was removed, when HCl was used. In case of EDTA, the removal efficiency increased proportionally to the concentration of EDTA, up to 98% lead removal with 0.1M EDTA. High mixing strength resulted in increase of removal efficiency and kinetics showed that the most lead was extracted in 10 min.

EDTA Surface Capped Water-Dispersible ZnSe and ZnS:Mn Nanocrystals

  • Lee, Jae-Woog;Lee, Sang-Min;Huh, Young-Duk;Hwang, Cheong-Soo
    • Bulletin of the Korean Chemical Society
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    • v.31 no.7
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    • pp.1997-2002
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    • 2010
  • ZnSe and ZnS:Mn nanocrystals were synthesized via the thermal decomposition of their corresponding organometallic precursors in a hot coordinating solvent (TOP/TOPO) mixture. The organic surface capping agents were substituted with EDTA molecules to impart hydrophilic surface properties to the resulting nanocrystals. The optical properties of the water-dispersible nanocrystals were analyzed by UV-visible and room temperature solution photoluminescence (PL) spectroscopy. The powders were characterized by X-ray diffraction (XRD), high resolution transmission electron microscopy (HR-TEM), and confocal laser scanning microscopy (CLSM). The solution PL spectra revealed emission peaks at 390 (ZnSe-EDTA) and 597 (ZnS:Mn-EDTA) nm with PL efficiencies of 4.0 (former) and 2.4% (latter), respectively. Two-photon spectra were obtained by fixing the excitation light source wavelengths at 616 nm (ZnSe-EDTA) and 560 nm (ZnS:Mn-EDTA). The emission peaks appeared at the same positions to that of the PL spectra but with lower peak intensity. In addition, the morphology and sizes of the nanocrystals were estimated from the corresponding HR-TEM images. The measured average particle sizes were 5.4 nm (ZnSe-EDTA) with a standard deviation of 1.2 nm, and 4.7 nm (ZnS:Mn-EDTA) with a standard deviation of 0.8 nm, respectively.

Effect of Iron Ion on Cell Division and Microcallus Growth in Mesophyll Protoplast Cultures of Arabidopsis thaliana (철이온이 Arabidopsis thaliana 초기 원형질체배양의 세포분열 및 미세 캘러스 생장에 미치는 효과)

  • 박현용
    • Korean Journal of Plant Tissue Culture
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    • v.22 no.6
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    • pp.339-343
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    • 1995
  • This study was performed to investigate the effect of iron ion on the mesophyll protoplast culture of Arabidopsis thaliana. Mesophyll protoplasts were isolated and cultured in a modified IMH medium supplemented with various concentrations of Fe-EDTA. Relatively low concentration of Fe-EDTA (<0.02 mM) induced the low level (4.8%) of cell division. In addition the cell division and microcallus growth were dose-dependently stimulated by 0 to 1 mM of Fe-EDTA. In 0.5 to 1 mM concentration range of Fe-EDTA, microcolonies were readily formed and the plating deficiency (8.5%) also showed maximal rate. However more than 1 mM of Fe-EDTA inhibited the initial growth of protoplase. The overall results suggest that Fe2+ion concentration plays an important role at the early developmental stage of protoplast regeneration.

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Influence of pH on Chelation of BaCl2 and EDTA Using Isothermal Titration Calorimetry (등온적정열량계를 이용한 BaCl2와 EDTA 킬레이션 결합 반응의 pH 영향)

  • Ga Eun Yuk;Ji Woong Chang
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.279-284
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    • 2023
  • Isothermal titration calorimetry (ITC) is a useful technique to obtain thermodynamic binding properties such as enthalpy, Gibbs free energy, entropy, and stoichiometry of the chelation reaction. A single independent binding site model was used to evaluate the thermodynamic binding properties in BaCl2 and ethylenediaminetetraacetic acid (EDTA) in Trince and HEPES buffers. ITC enables us to elucidate the binding mechanism and find an optimal chelation condition for BaCl2 and EDTA in the pH range of 7~11. Chelation of BaCl2 and EDTA is a spontaneous endothermic reaction. As pH increased, entropic contributions dominated. The optimal pH range is narrow around pH 9.0, where 1:1 binding between BaCl2 and EDTA occurs.

Effects of EDTA on morphology of hydroxyapatite prepared by hydrothermal method (수열합성법에 의해 합성된 수산화아파타이트 결정의 입자 형상에 관한 EDTA의 영향)

  • Choi, Bong-Seok;Kim, Dong-Hyun;Kim, Tae-Wan;Park, Hong-Chae;Yoon, Seog-Young
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.21 no.2
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    • pp.75-81
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    • 2011
  • Hydroxyapatite (HAP) crystals with hexagonal structure have been successfully synthesized by using EDTA(ethylene diamine tetraacetic acid) as chelate under hydrothermal condition. The as-prepared HAp powders were characterized by XRD and SEM. The XRD result indicated that the products were preferentially oriented along c-axis. The SEM photographs showed that the morphology of the HAp crystals was well controlled by the reaction parameters such as temperature, pH value, and the molar ratio of EDTA/Ca.