• Title/Summary/Keyword: ED Process

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Ultra-pure water production by integrated electrodialysis-ion exchange/electrodeionization

  • Turek, Marian;Mitko, Krzysztof;Bandura-Zalska, Barbara;Ciecierska, Kamila;Dydo, Piotr
    • Membrane and Water Treatment
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    • v.4 no.4
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    • pp.237-249
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    • 2013
  • Ultra-pure water (UPW), a highly treated water free of colloidal material and of a conductivity less than 0.06 ${\mu}S$, is an essential component required by modern industry. One of the methods for UPW production is the electrodialysis-ion exchange (ED/IE) system, in which the electrodialysis (ED) process is used as a preliminary demineralization step. The IE step can be replaced with electrodeionization (EDI) to decrease the volume of post-regeneration lyes. In this paper, the electrodialysis process carried out to relatively low diluate conductivity was investigated and the costs of UPW production were calculated. The optimal value of desalination degree by ED in the ED/IE and ED/EDI systems was estimated. UPW unit costs for integrated ED/IE and ED/EDI systems were compared to simple ion exchange and other methods for UPW production (RO-IE, RO-EDI). The minimal UPW unit costs in ED/EDI integrated system were estimated as $0.37/$m^3$ for feed TDS 600 mg/L and $0.36/$m^3$ for feed TDS 400 mg/L at 64 $m^3/h$ capacity, which was lower than in the comparable ED/IE integrated system ($0.42-0.44/$m^3$). The presented results suggest that an ED/EDI integrated system may be economically viable.

Separation of Cd(II) from Aqueous Solutions by A New Consecutive Process Consisting of Supported Liquid Membrane and Electrodialysis

  • Altin, Sureyya;Altin, Ahmet
    • Journal of Electrochemical Science and Technology
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    • v.10 no.1
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    • pp.14-21
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    • 2019
  • Supported liquid membrane process usually is used for recovering or enrichment of valuable metals in the industrial wastewater. But, even if the metals in the wastewater was separated with high chemical selectivity, it cannot be enough concentrated since separation performance of supported liquid membrane (SLM) process is limited by concentration gradient between feed solution and stripping solution. If metal concentration in the stripping solution to be enough low, transport of metal through membrane can be accomplishment constantly. Therefore, Electrodialysis (ED) has been placed after SLM process and the stripping solution of SLM was used as the feed solution for the ED process. Transport of ions in the solutions is successfully performed by ED process. Thus, the metal concentration in the stripping solution does not rise as to stop ion transport. Besides, valuable metals easily are concentrated by ED process for re-use. In this study, effects of operation parameters like initial Cd(II) concentration, HCl concentration in the feed solution of SLM and applied voltage are investigated on separation efficiency, flux and permeability of the both processes. As the feed solution concentration increased, all performance values has increased. When initial concentration of 100 mg/L is used, separation performances (SP) are 55% and 70%, for SLM and consecutive process, respectively. The best HCl concentration in the feed solution of SLM has determined as 2 M, in this conditions SP are 64% and 72%, for SLM and consecutive process, respectively. With increased of applied voltage on ED process, SP of the consecutive process has been raised from 72% to 83%. According to the obtained experimental data, consecutive process has better separation performance than SLM. When the separation performances of both processes were compared for the same operating conditions, it was determined higher the separation efficiency, permeability and flux values of the consecutive process, 8%, 9% and %10.6, respectively. Consequently, the use of the consecutive process increases the performance efficiency of both processes. The consecutive process studied has quite a good chemical separation efficiency, and enrichment capability. Moreover, this process requires few water and energy.

Removal of organic acid salts from 1,3-propanediol fermentation broth by electrodialysis

  • Wang, Xiao-Lin;Gong, Yan;Yu, Li-Xin;Tang, Yu;Liu, De-Hua
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05a
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    • pp.19-24
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    • 2004
  • ED method is employed to effectively remove the organic acid salts in actual PDO fermentation broth. The lower electrical potential is selected to avoid the serious membrane fouling so as to ensure a stable and durative desalination process. Under the selected operation conditions, about 90% of organic acids salts are removed from PDO fermentation broth successfully by ED process. To reduce the loss of PDO product due to the diffusion, the operation time should be considered carefully. And based on mass balance equation and irreversible thermodynamics approach, a mathematical model is developed to describe the desalination process of an aqueous solution containing neutral solute by ED method. While the influence of concentration polarization is reflected by decreasing the conductivity of membrane, the model is verified well to describe the ED processes under varied operation conditions. Through the model, ED process of actual PDO fermentation broth is simulated to get a suitable scope of initial concentration in concentrated compartment.

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Alkali Recovery by Electrodialysis Process: A Review (전기투석 공정에 의한 알칼리 회수: 총설)

  • Sarsenbek Assel;Rajkumar Patel
    • Membrane Journal
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    • v.33 no.3
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    • pp.87-93
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    • 2023
  • Electrodialysis (ED) is essential in separating ions through an ion exchange membrane. The disposal of brine generated from seawater desalination is a primary environmental concern, and its recycling through membrane separation technology is highly efficient. Alkali is produced by several chemical industries such as leather, electroplating, dyeing, and smelting, etc. A high concentration of alkali in the waste needs treatment before releasing into the environment as it is highly corrosive and has a chemical oxygen demand (COD) value. The concentration of calcium and magnesium is almost double in brine and is the perfect candidate for carbon dioxide adsorption, a major environmental pollutant. Sodium hydroxide is essential for the metal carbonation process which, is easily produced by the bipolar membrane electrodialysis process. Various strategies are available for its recovery, like reverse osmosis (RO), nanofiltration (NF), ultrafiltration (UF), and ED. This review discusses the ED process by ion exchange membrane for alkali recovery are discussed.

Differences in performance and importance of handover items between 119 paramedics and emergency department staff (119구급대원과 응급실 의료진의 인수인계 항목 수행도 및 중요도의 차이)

  • Na, Yoon-Jeong;Lee, Kyoung-Youl
    • The Korean Journal of Emergency Medical Services
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    • v.25 no.1
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    • pp.105-124
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    • 2021
  • Purpose: This study aims to identify the present handover status and the difference in performance and importance of handover between 119 paramedics and emergency department (ED) staff to improve the quality of handover. Methods: The study involved a questionnaire survey of 171 paramedics and 108 ED staff in four regions from August 28 to September 23, 2020. Subsequently, 279 questionnaires were collected and 277 copies were used for this study. Data were analyzed by SPSS 26.0 version. Results: The results showed that most of the paramedics and the ED staff rely on memory and verbally handover, without formal education about the handover process. And there were significant differences in performance in important information of prehospital. Some of the handover items were a difference in performance and importance between the paramedics and the ED staff. Conclusion: The unified education based on required and optional items is necessary to reduce the loss of information between the paramedics and ED staff, and standardized tools need to be developed in the handover process.

Yttrium-Stabilized Zirconia Particles Prepared Using Electro-dialysis of (Zr,Y)OCl2 Aqueous Solution

  • Chang, Myung Chul
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.466-471
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    • 2014
  • Hydrous zirconia particles were prepared from $ZrOCl_2$ aqueous solution using an electro-dialysis [ED] process. For the preparation of $(Zr,Y)(OH)_4$ precipitates, 3 mol% $YCl_3$ was added into $ZrOCl_2$ aqueous solution. During the hydrolysis of 0.5 mol/L $(Zr,Y)OCl_2$ solution at $90^{\circ}C$ a slurry solution was obtained. The ED process was used for the removal of chlorine from the slurry solution. Two kinds of slurry solution were sampled at the beginning and end of the ED process. The morphology of hydrous zirconia particles in the solution was observed using an inverted optical microscope and an FE-SEM. The hydrous zirconia particles were nano-crystalline, and easily coagulated with drying. Yttrium stabilized zirconia [YSZ] powder could be obtained by the calcination of $(Zr,Y)(OH)_4$ precipitates prepared from a $(Zr,Y)OCl_2$ solution by the ED process. The coagulated dry powders were shaped and sintered at $1500^{\circ}C$ for 2 h. The sintered body showed a dense microstructure with uniform grain morphology.

Improvement of the ED-Drilling Machinability using Multi-hole Electrodes (Multi-hole 전극에 의한 Ed-Drilling 가공성 향상)

  • Kim, Chang-Ho
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.5
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    • pp.88-93
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    • 2012
  • This paper describes the machinability of the sintered carbide and tool-die steel(STD-11) by electric discharge drilling with various tubular electrodes which have multi-holes. Various types of electrode which have different diameters and materials are used with the application of continuous direct current and axial electrode feed. Inner part of electrodes are inserted with smaller tubes or Y-channel or bar. In ED-Drilling, the dielectric flushed down the interior of the rotating tube electrode, in order to remove machining debris from the hole. As result of experiments, the bigger the diameter of the electrode is, the lower the material removal rate is. Machinability of copper electrode is higher than that of brass. In machining of sintered carbide, to use oil is better than distilled water as dielectric.

RECENT DEVELOPMENTS OF MEMBRANE TECHNOLOGY IN JAPAN

  • Kimura, Shoji
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.10-12
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    • 1991
  • The first membrane technology applied in the Japanese industry was a. electro-dialysis(ED) process using ion-exchange meabranes. These membranes were first developed in early 50ties and the Japanese government decided to use this method for concentration of sea water to produce salt, which was then produced by solar evaporation. This development program started from 1960 by the Japan monopoly Coop. (at that time). To apply ED process for sea-water concentrat ion it was necessary to develop ion-exchange membranes having very low electric resistance to avoid energy loss due to Joule heat, and those having selectivity to permeate single valent ions only to avoid scale formation in the ED stacks. These Japanese companies, Asahi Glass, Asahi Chemical and Tokuyama Soda, have succeeded to develop such membranes, and until 1971 all of the seven salt manufacturing companies had adopted ED for production of food salt.

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A Review Based on Ion Separation by Ion Exchange Membrane (이온교환막을 통한 이온분리에 대한 총설)

  • Assel, Sarsenbek;Patel, Rajkumar
    • Membrane Journal
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    • v.32 no.4
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    • pp.209-217
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    • 2022
  • Ion exchange membrane (IEM) is an important class of membrane applied in batteries, fuel cells, chloride-alkali processes, etc to separate various mono and multivalent ions. The membrane process is based on the electrically driven force, green separation method, which is an emerging area in desalination of seawater and water treatment. Electrodialysis (ED) is a technique in which cations and anions move selectively along the IEM. Anion exchange membrane (AEM) is one of the important components of the ED process which is critical to enhancing the process efficiency. The introduction of cross-linking in the IEM improves the ion-selective separation performance due to the reduction of free volume. During the desalination of seawater by reverse osmosis (RO) process, there is a lot of dissolved salt present in the concentrate of RO. So, the ED process consisting of a monovalent cation-selective membrane reduces fouling and improves membrane flux. This review is divided into three sections such as electrodialysis (ED), anion exchange membrane (AEM), and cation exchange membrane (CEM).

Swelling Properties and Releasing Characteristics of Chitosan Beads Containing Bisamino-PEG (Bisamino-PEG가 함유된 키토산 비드의 팽윤성 및 방출 특성)

  • Ha, Byung-Jo;Lee, Ok-Sub;Lee, Yoon-Sik
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.59-66
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    • 1996
  • Novel chitosan beads containing a series of bisamino-terminated polyethylene glycol (Bisamino-PEG, $Jeffamine^{(R)}ED$ series) have been prepared via capillary extrusion method using an alkaline solution. The results of swelling kinetics of chitosan beads showed that as the chain length of PEG in chitosan beads increased, the swelling process of the beads proceeded slowly. In order to study the releasing kinetics quantitatively, fluorescamine was coupled to the pendant amino groups and the releasing processes were followed by UV spectra. The results revealed that the releasing process was retarded in the order of $Jeffamine^{(R)}ED$-600 < $Jeffamine^{(R)}ED$-900 < $Jeffamine^{(R)}ED$-2001 as the chain length of PEG was increased. The slow release of PEG from the beads is considered to be governed by the chain length of PEG and interpolymeric hydrogen bonding between PEG and the chitosan molecule.

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