• Title/Summary/Keyword: ECA (electrically conductive adhesives)

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Characteristics of electrically conductive adhesives filled with silver-coated copper

  • Nishikawa, Hiroshi;Terad, Nobuto;Miyake, Koich;Aoki, Akira;Takemoto, Tadashi
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.217-220
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    • 2009
  • Conductive adhesives have been investigated for use in microelectronics packaging as a lead-free solder substitute due to their advantages, such as low bonding temperature. However, high resistivity and poor mechanical behavior may be the limiting factors for the development of conductive adhesives. The metal fillers and the polymer resins provide electrical and mechanical interconnections between surface mount device components and a substrate. As metal fillers used in conductive adhesives, silver is the most commonly used due to its high conductivity and the stability. However the cost of conductive adhesives with silver fillers is much higher than usual lead-free solders and silver has poor electro-migration performance. So, copper can be a promising candidate for conductive filler metal due to its low resistivity and low cost, but oxidation causes this metal to lose its conductivity. In this study, electrically conductive adhesives (ECAs) using surface modified copper fillers were developed. Especially, in order to overcome the problem associated with the oxidation of copper, copper particles were coated with silver, and the silver-coated copper was tested as a filler metal. Especially the effect of silver coating on the electrical resistance just after curing and after aging was investigated. As a result, it was found that the electrical resistance of ECA with silver-coated copper filler was clearly lower and more stable than that of ECA with pure copper filler after curing process. And, during high temperature storage test, the degradation rate of electrical resistance for ECA with silver coated copper filler was quite slower than that for ECA with pure copper filler.

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A Study on Correlation Peel Strength and the Efficiency of Shingled Modules According to Curing Condition of Electrically Conductive Adhesives (슁글드 모듈에서 경화조건에 따른 ECA 접합강도와 효율의 상관관계에 관한 연구)

  • Jun, Dayeong;Son, Hyoungin;Moon, Jiyeon;Cho, Seonghyeon;Kim, Sung hyun
    • Current Photovoltaic Research
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    • v.9 no.2
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    • pp.31-35
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    • 2021
  • Shingled module shows high ratio active area per total area due to more efficient packing without inactive space between cells. The module is fabricated by connecting the pre-cut cells into the string using electrically conductive adhesives (ECA). ECAs are used for electric and structural connections to fabricate the shingled modules. In this work, we investigated a correlation between ECA peel strength and the efficiency of pre-cut 5 cells module which are fabricated according to ECA interconnection conditions. The curing conditions are varied to determine whether ECA interconnection properties can affect module properties. As a result of the peel test, the highest peel strength was 1.27 N/mm in the condition of 170℃, the lowest peel strength was 0.89 N/mm in the condition of 130℃. The efficiency was almost constant regardless of the curing conditions at an average of 20%. However, the standard deviation of the fill factor increased as the adhesive strength decreased.

Characterization of Electrically Conductive Adhesives for Shingled Array Photovoltaic Cells (전도성 접착제 물성에 따른 슁글드 어레이 태양전지 특성 평가)

  • Jee, Hongsub;Choi, Wongyong;Lee, Jaehyeong;Jeong, Chaehwan
    • Current Photovoltaic Research
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    • v.5 no.3
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    • pp.95-99
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    • 2017
  • The interconnecting shingled solar cells method shows extremely high ratio active area per total area and has the excellent potential for high power PV (photovoltaic). Compared to the conventional module, it can have much more active area due to busbar-free structure. The properties of ECA (electrically conductive adhesives) are significant to fabricate the shingled array PV since it should be used in terms of electric and structural connection. Various ECA were tried and characterized to optimize the soldiering conditions. The open circuit voltage of shingled array cells showed a three-fold increase and efficiency was also increased by 1.63%. The shingled array cells used in CE3103WLV showed the highest power and in CA3556HF the lowest curing temperature and very fast curing time.

Electrical Characteristics of c-Si Shingled Photovoltaic Module Using Conductive Paste based on SnBiAg (SnBiAg 전도성 페이스트를 이용한 Shingled 결정질 태양광 모듈의 전기적 특성 분석)

  • Yoon, Hee-Sang;Song, Hyung-Jun;Kang, Min Gu;Cho, Hyeon Soo;Go, Seok-Whan;Ju, Young-Chul;Chang, Hyo Sik;Kang, Gi-Hwan
    • Korean Journal of Materials Research
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    • v.28 no.9
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    • pp.528-533
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    • 2018
  • In recent years, solar cells based on crystalline silicon(c-Si) have accounted for much of the photovoltaic industry. The recent studies have focused on fabricating c-Si solar modules with low cost and improved efficiency. Among many suggested methods, a photovoltaic module with a shingled structure that is connected to a small cut cell in series is a recent strong candidate for low-cost, high efficiency energy harvesting systems. The shingled structure increases the efficiency compared to the module with 6 inch full cells by minimizing optical and electrical losses. In this study, we propoese a new Conductive Paste (CP) to interconnect cells in a shingled module and compare it with the Electrical Conductive Adhesives (ECA) in the conventional module. Since the CP consists of a compound of tin and bismuth, the module is more economical than the module with ECA, which contains silver. Moreover, the melting point of CP is below $150^{\circ}C$, so the cells can be integrated with decreased thermal-mechanical stress. The output of the shingled PV module connected by CP is the same as that of the module with ECA. In addition, electroluminescence (EL) analysis indicates that the introduction of CP does not provoke additional cracks. Furthermore, the CP soldering connects cells without increasing ohmic losses. Thus, this study confirms that interconnection with CP can integrate cells with reduced cost in shingled c-Si PV modules.

Simulation of Shingled String Characteristics Depending on Cell Strips Type for High Power Photovoltaic Modules (고출력 태양광 모듈을 위한 분할 셀 종류에 따른 슁글드 스트링 특성 시뮬레이션)

  • Park, Ji Su;Oh, Won Je;Lee, Jae Hyeong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.1
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    • pp.10-15
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    • 2020
  • Recently, with the increase in the use of urban solar power, solar modules are required to produce high power in limited areas. In this report, we proposed the fabrication of a high-power photovoltaic module using shingles technology, and developed accurate string characteristic simulations based on circuit modeling. By comparing the resistance components between the interconnected cells and the cell strips, the ECA resistance was determined to be 0.003 Ω. Based on the equivalent circuit of the modeled shingled string, string simulation was performed according to the type of cell strip. As a result, it was determined that the cell efficiency of the 4-cell strip was the highest at 19.66%, but the efficiency of the string simulated with the 6-cell strip was the highest at 20.48% in the string unit.

Shingled String for the High Performance Photovoltaic Module (고효율 태양광 모듈 제작을 위한 스트링 공정 최적화)

  • Jee, Hongsub;Moon, Daehan;Song, Jinho;Jeong, Chaehwan
    • Current Photovoltaic Research
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    • v.6 no.4
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    • pp.119-123
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    • 2018
  • The High Performance Module With The Shingled String Has Several Advantages Such As The Larger Active Area, Higher Open-Circuit Voltage And Smaller Cell To Module (Ctm) Loss. To Obtain Increase Of Power In Pv Shingled Module, The Detailed Condition Of Various Parameters Related To Cutting And Bonding Process Were Investigated In This Study. We Searched The Optimized Cutting Conditions Of Laser Scan Speed, The Number Of Laser-Scribing And Also Bonding Conditions Of Electrically Conductive Adhesives (Eca) By Varying Amount Of Eca, Curing Time And Curing Temperature. The Shingled Pv Module Showed 25.4W of Maxmimum Power At 60 Rpm Of Dipensing Motor Speed, 30 Seconds Of Curing Time And $140^{\circ}C$ Of Curing Temperature, Respectively.

Improvement in Power of Shingled Strings by Re-work Process (Re-work 공정을 통한 슁글드 스트링의 출력 개선)

  • Song, Jinho;Jee, Hongsub;Moon, Daehan;Kim, Do-Heyong;Yang, O-Bong;Jeong, Chaehwan
    • Current Photovoltaic Research
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    • v.7 no.2
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    • pp.51-54
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    • 2019
  • The high density module (HDM) has advantages for its larger active area and smaller current density. This new way of making a photovoltaic (PV) module method has benefit for increasing module power with the same installed area. Because HDM consisted with serially connected PV strings, loss of strings during the fabrication process can increase the overall production cost.1-2 This study investigates the rework conditions of the shingled strings with electrically conductive adhesives (ECA). By heating the electrically connected area of a fabricated string, cured area become soft and a string can be detached for the rework process. After rework process, a refabricated string showed 5~10% increased output power compared to before rework process and reached to the 90~95% output power compare to the undamaged strings.