• Title/Summary/Keyword: Dynamic physical properties

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Influence of Silane Coupling Agent Treatments on Physical Properties of Rubbery Materials (실란 커플링제 처리방법이 고무 물성에 미치는 영향)

  • Woon, Jin-Bok
    • Elastomers and Composites
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    • v.36 no.4
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    • pp.237-245
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    • 2001
  • A study was made on the chemical treatment of silica and silane coupling agents, bistriethox ysilylpropyltetrasulfide(Si 69) and ${\gamma}$-mercaptopropyltrimethoxy silane (MPS) for reinforcement of silica formulation. The effects of chemical treatment method and the most popular two coupling agents were examined. The results clearly indicate that the wet method, coupling agent is combined chemically with the silica prior to mixing, has more dispersion, wetting ability, dynamic properties and stability than the dry method, coupling agent is premixed directly with the silica. The mixing was done using a bench-type kneader having two mixing cam and a two-roll mill, under approximately similar conditions. The physical properties of SBR vulcanizates give rise to marked improvements by addition of Si 69 and MPS in comparison with without silane coupling agents. The optimum amount of Si 69 and MPS was 2 w/w% by experiments in the dry method but was 4 w/w% by EA and TGA analysis in the wet method.

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Preparation of Silica-Filled SBR Compounds with Low Rolling Resistance by Wet Masterbatch

  • Yang, Jae-Kyoung;Park, Wonhyeong;Ryu, Changseok;Kim, Sun Jung;Kim, Doil;Seo, Gon
    • Elastomers and Composites
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    • v.55 no.1
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    • pp.26-39
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    • 2020
  • The physical properties of silica-filled SBR compounds (WSBR) prepared using silica-SBR wet masterbatches (WMB) were systematically investigated to understand the effect of the surface treatment of silica on the reinforcement performance of SBR. Treatment of silica with bis(triethoxysilylpropyl)tetrasulfide (TESPT) in the liquid phase, followed by mixing with an SBR solution and recovery by water stripping, easily produced silica-SBR WMB. However, insufficient surface treatment in terms of the amount and stability of the incorporated TESPT led to considerable silica loss and inevitable TESPT elution. Pretreatment of silica in the gas phase with TESPT and another organic material that enabled the formation of organic networks among the silica particles on the surface provided hydrophobated silica, which could be used to produce silica-SBR WMB, in high yields of above 99%. The amount and type of organic material incorporated into silica greatly influenced the cure characteristics, processability, and tensile and dynamic properties of the WSBR compounds. The TESPT and organic material stably incorporated into silica increased their viscosity, while the organic networks dispersed on the silica surface were highly beneficial for reducing their rolling resistance. Excessive dosing of TESTP induced low viscosity and a high modulus. The presence of connection bonds formed by the reaction of glycidyloxy groups with amine groups on the silica surface resulted in physical entanglement of the rubber chains with the bonds in the WSBR compounds, leading to low rolling resistance without sacrificing the mechanical properties. Mixing of the hydrophobated silica with a rubber solution in the liquid phase improved the silica dispersion of WSBR compounds, as confirmed by their low Payne effect, and preservation of the low modulus enhanced the degree of entanglement.

Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

Prediction of Material Properties of Carbon Fiber Prepreg in the Laminated Composite Using Reverse Analysis with Dynamic Characteristics (동적 특성이 고려된 역해석를 이용한 적층 복합재료 내부의 탄소섬유 프리프레그의 물성 예측)

  • Hwang, Mun-Young;Kang, Lae-Hyong
    • Composites Research
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    • v.32 no.4
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    • pp.177-184
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    • 2019
  • If what the mechanical properties according to a layer have was found out by analyzing the already fabricated composite, it could be possible to develop the composite of the better performance than the existing products. In this study, we tried to calculate the mechanical properties of the inner prepreg lamina by applying the reverse design technique to the composite structure made by laminating prepregs. When the physical quantities obtained by the simple tensile test are used alone and the physical quantities obtained by the tensile test and the mode analysis are used at the same time, the results of this study show that the accuracy of the latter is higher Finally, the maximum error of $E_1$ predicted was 0.09% and the maximum error of predicted $E_2$ was 7%.

Estimation of Shear-Wave Velocities of Layered Half-Space Using Full Waveform Inversion with Genetic Algorithm (유전 알고리즘을 활용한 완전파형역산 기법의 층상 반무한 지반 전단파 속도 추정)

  • Lee, Jin Ho;Lee, Se Hyeok
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.34 no.4
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    • pp.221-230
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    • 2021
  • This paper proposes full waveform inversion (FWI) for estimating the physical properties of a layered half-space. An FWI solution is obtained using a genetic algorithm (GA), which is a well-known global optimization approach. The dynamic responses of a layered half-space subjected to a harmonic vertical disk load are measured and compared with those calculated using the estimated physical properties. The responses are calculated using the thin-layer method, which is accurate and efficient for layered media. Subsequently, a numerical model is constructed for a layered half-space using mid-point integrated finite elements and perfectly matched discrete layers. An objective function of the global optimization problem is defined as the L2-norm of the difference between the observed and estimated responses. A GA is used to minimize the objective function and obtain a solution for the FWI. The accuracy of the proposed approach is applied to various problems involving layered half-spaces. The results verify that the proposed FWI based on a GA is suitable for estimating the material properties of a layered half-space, even when the measured responses include measurement noise.

Physical and Mechanical Properties of Blast Furnace Cement Concrete with Polypropylene Fiber (폴리프로필렌 섬유를 보강한 고로시멘트 콘크리트의 물리·역학적 특성)

  • Jun, Hyung Soon
    • Journal of The Korean Society of Agricultural Engineers
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    • v.54 no.6
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    • pp.151-158
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    • 2012
  • This study will not only prove experimental dynamic properties which are classified to slump, compressed strength, bending strength and toughness index blast-furnace cement concrete with polypropylene (PP) fiber that refer properties and volume of it, but also establish a basic data in order to use PP fiber reinforced blast-furnace cement concrete. The slump didn't changed by PP fiber volume $5kgf/m^3$ because of flexibility of fiber in despite of loose mixing. The reason why the slump decreased steadily by PP fiber volume $3kgf/m^3$ was rising contact surface of water. The compressed strength indicated a range of 19.49~26.32 MPa. The tensile strength indicated a range of 2.10~2.44 MPa. The bending strength was stronger about 3~16 % in case of mixing with PP fiber volume than normal concrete. The flexure strength indicated a range of 4.30~4.83 MPa. The toughness indicated a range of $0{\sim}19.88N{\cdot}mm$ and was stronger about 6.7 times in case of PP fiber volume $9kg/m^3$ than PP fiber volume $1kg/m^3$. The pavement with PP fiber volume over such a fixed quantity in the roads of a respectable amount load can have a effect to prevent not only resistance against clack but also rip off failures.

Dynamism of Lived Space in the Light of Intuitive Experiential Contents (직관적 체험내용으로 비추어 본 생활공간의 역동성)

  • Kim, Young-Chul
    • Journal of the Korean housing association
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    • v.16 no.5
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    • pp.75-81
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    • 2005
  • The purpose of this study is to shed light on the field dynamics of 'lived space' in the light of our intuitive experiential contents by way of investigating three properties of space. While finding inspirations in the field theory of modern physics, investigation of our intuitive responses to the physical and spatial environment leads us to a coherent view of matter and space. We find then that our lived world is more than a system of inert matter; it is a dynamic environment of life in which feeling and mood, spiritual meaning and value, are perpetually infused with matter. Any concept of space, if it is to be meaningful to lift has to somehow acknowledge this fact. Empty space and matter cannot be conceived as mutually exclusive and independent as in classical physics. Rather they should be seen as two different manifestations of an underlying dynamism which permeates the world. The 'properties' of space can only be understood in terms of the 'impact' of material presence. The object cannot be seen as an isolated entity, but the 'conditioning' of its surrounding space has to be understood as an integral part of its being. Lived space can thus be viewed as an emotionally charged field, or a field of emotional energy, whose properties may be described in terms of concentration, mobility and resonance.

Physical Properties of Organic Vegetable Cultivation Soils under Plastic Greenhouse (유기농 시설채소 재배지 토양의 물리적 특성변화)

  • Lee, Sang-Beom;Choi, Won-A;Hong, Seung-Gil;Park, Kwang-Lai;Lee, Cho-Rong;Kim, Seok-Cheol;An, Min-Sil
    • Korean Journal of Organic Agriculture
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    • v.23 no.4
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    • pp.963-974
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    • 2015
  • This study was conducted to determine the effects of organic vegetable cultivation on the soil physical properties in 33 farmlands under plastic greenhouse in Korea. We were investigated 5~8 farms per organic vegetable crops during the period from August to November 2014. The main cultivated vegetables were leafy lettuce (Lactuca sativa L.), Perilla leaves (Perilla frutescens var. Japonica Hara), cucumber (Cucumis sativus L.), strawberry (Fragaria ananassa L.) and tomato (Lycopersicon spp.). We have analyzed soil physical properties. The measured soil physical parameters were soil plough layer, soil hardness, penetration resistance, three soil phase, bulk density and Porosity. The measurement of the soil plough layer, soil hardness and penetration resistance were carried out direct in the fields, and the samples for other parameters were taken using the soil core method with approximately 20 mm diameter core collected from each organic vegetable field. Soil plough layer was average 36 cm and ranged between 30 and 50 cm, and slightly different depending on the sorts of vegetable cultivation. The soil hardness was $0.17{\pm}0.15{\sim}1.34{\pm}1.02$ in the topsoil, $0.55{\pm}0.34{\sim}1.15{\pm}0.62$ in the subsoil. It was not different between topsoil and subsoil, but showed a statistically significant difference between the leafy and fruit vegetables. Penetrometer resistance is one of the important soil physical properties that can determine both root elongation and yield. The increase in density under leafy vegetables resulted in a higher soil penetrometer resistance. Soil is a three-component system comprised of solid, liquid, and gas phases distributed in a complex geometry that creates large solidliquid, liquid-gas, and gas-solid interfacial areas. The three soil phases were dynamic and typically changed in organic vegetable soils under greenhouse. Porosity was characterized as range of $54.2{\pm}2.2{\sim}60.3{\pm}2.4%$. Most measured soils have bulk densities between 1.0 and $1.6gcm^{-3}$. To summarize the above results, Soil plough layer has been deepened in organic vegetable cultivation soils. Solid hardness (the hardness of the soil) and bulk density (suitable for the soil unit mass) have been lowered. Porosity (soil spatial content) was high such as a well known in organic farmlands. Important changes were observed in the physical properties according to the different vegetable cultivation. We have demonstrated that the physical properties of organic cultivated soils under plastic greenhouse were improved in the results of this study.

Study on the physical properties of nylon66/glass fiber composites as a function of extrusion number (나일론66/유리섬유 복합체의 압출횟수에 따른 특성 연구)

  • Lee, Bom Yi;Kim, Youn Cheol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.6
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    • pp.3990-3996
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    • 2014
  • Because the physical properties can be decreased when a Nylon 66/glass fiber composite is injected into a mold over $300^{\circ}C$, a systematic study of the thermal history in the case of re-use is needed. Nylon 66/glass fiber extrudates as a function of the extrusion number were prepared using a twin screw extruder at 305/290/273/268/265/$260^{\circ}C$. The chemical structure, thermal properties, melt index, crystal structure, Izod impact strength, and rheological properties were measured by Fourier transform infra-red (FT-IR), melt indexer, DSC, TGA, XRD, Izod impact tester, and dynamic rheometer. The FT-IR spectra indicated that the number of extrusions did not affect the chemical structure. The decrease in molecular weight with increasing extrusion number was confirmed by the melt index and the complex viscosity of extrudates. Based on the DSC and TGA results, the thermal history had no effect on the melting temperature, regardless of the number of extrusions, but the degradation temperature decreased up to $20^{\circ}C$ with increasing extrusion number. The Izod impact strengths of the extrudates were found to decrease with increasing extrusion number. No structural change after extrusion was also confirmed because there was no change in the slope and shape of the G'-G" plot.

Physical and Mechanical Properties of Polymer Concrete Using Recycled Aggregate (재생골재를 사용한 폴리머 콘크리트의 물리·역학적 특성)

  • Sung, Chan-Yong;Baek, Seung-Chul
    • Korean Journal of Agricultural Science
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    • v.32 no.1
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    • pp.19-27
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    • 2005
  • This study was performed to evaluate the physical and mechanical properties of polymer concrete using unsaturated polyester resin, initiator, heavy calcium carbonate, crushed gravel, recycled coarse aggregate, silica sand and recycled fine aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were decreased with increasing the content of recycled aggregate. The unit weight, compressive strength, flexural strength and dynamic modulus of elasticity were showed in $2,127{\sim}2,239kg/m^3$, 80.5~88.3MPa, 19.2~21.5MPa and $254{\times}10^2{\sim}288{\times}10^2MPa$ at the curing age 7 days, respectively. Therefore, these recycled aggregate can be used for polymer concrete.

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