• 제목/요약/키워드: Dye-Function

검색결과 113건 처리시간 0.022초

입상 활성탄에 의한 Rhodamin-B의 흡착 열역학, 동력학 및 등량 흡착열에 관한 연구 (Adsorption Thermodynamics, Kinetics and Isosteric Heat of Adsorption of Rhodamin-B onto Granular Activated Carbon)

  • 이종집
    • 공업화학
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    • 제27권2호
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    • pp.199-204
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    • 2016
  • 입상 활성탄을 사용하여 수용액으로부터 Rhodamine-B 염료의 흡착에 대해 조사하였다. 회분식 실험은 흡착제의 양, pH 초기농도와 접촉시간과 온도를 흡착변수로 사용하여 수행하였다. 흡착평형자료는 Langmuir 등온식에 잘 맞았다. 평가된 Langmuir 분리계수($R_L$ = 0.0164~0.0314)로부터 이 흡착공정이 적절한 처리방법이 될 수 있음을 알았다. 흡착속도실험결과는 유사 1차 반응속도식에 잘 맞는 것으로 나타났다. 음수값의 Gibbs 자유에너지(-4.51~-13.44 kJ/mol)와 양수값의 엔탈피(128.97 kJ/mol)는 흡착이 자발적이고 흡열공정으로 진행된다는 것을 나타냈다. 등량흡착열은 흡착된 염료분자들의 측면상호작용에 따라 표면부하량이 증가할수록 커졌다.

Effects of Elastic Taping and Non-elastic Taping on Static Balance Control Ability, Dynamic Balance Control Ability, and Navicular bone Drop in Young Adults

  • Lim, Jong-Gun;Lee, Hyun-Woo;Lee, Dongyeop;Hong, Ji-Heon;Yu, Jae-Ho;Kim, Jin-Seop;Kim, Seong-Gil
    • 대한물리의학회지
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    • 제17권2호
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    • pp.1-10
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    • 2022
  • PURPOSE: This study examined the effects of the low dye taping technique on the static and dynamic balancing ability and navicular bone drop when the low dye taping technique was divided into elastic and non-elastic taping. METHODS: The subjects of the study were 31 volunteers without musculoskeletal disorders. The length (L) and anterior (A), posteromedial, and posterolateral values of the arch in the NO (normal eyes open), NC (normal eyes closed), PO (pillow with eyes open), and PC (pillow with close eyes closed) states were evaluated when barefoot and when Kinesio tape and non-elastic tape were applied. The measurements were analyzed using repeated ANOVA and an independent t-test. Post hoc tests were performed using a Fisher's LSD. RESULTS: A significant difference was found in the arch L and A values using a foot scanner (p < .05). In addition, there was a significant difference in dynamic balance in the three directions (p < .05), and no difference was found in the case of static balance. As a result, non-elastic tape application helps improve the dynamic balance ability and arch of the foot. CONCLUSION: The non-elastic tape technique is helpful for the foot arch function, and there is no difference in the static balance ability between Kinesio tape and non-elastic tape. Nevertheless, non-elastic tape is more helpful for the dynamic balance ability than Kinesio taping.

Estimation of Electrical Parameters of OD Organic Semiconductor Diode from Measured I-V Characteristics

  • Moiz, Syed Abdul;Ahmed, Mansoor M.;Karimov, Kh. S.
    • ETRI Journal
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    • 제27권3호
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    • pp.319-325
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    • 2005
  • In this paper the effect of temperature on the electrical properties of organic semiconductor disperse orange dye 25 (OD) have been examined. Thin films of OD have been deposited on $In_{2}O_{3}$ substrates using a centrifugal machine. DC current-voltage (I-V) characteristics of the fabricated devices $(Al/OD/In_{2}O_{3)$ have been evaluated at varying temperatures ranging from 40 to $60^{\circ}C$. A rectification behavior in these devices has been observed such that the rectifying ratio increases as a function of temperature. I-V characteristics observed in $Al/OD/In_{2}O_{3)$ devices have been classified as low temperature $({\leq} 50^{\circ}C)$ and high temperature characteristics (approximately $60^{\circ}C$). Low temperature characteristics have been explained on the basis of the charge transport mechanism associated with free carriers available in OD, whereas high temperature characteristics have been explained on the basis of the trapped space-charge-limited current. Different electrical parameters such as traps factor, free carrier density, trapped carrier density, trap density of states, and effective mobility have been determined from the observed temperature dependent I-V characteristics. It has been shown that the traps factor, effective mobility, and free carrier density increase with increasing values of temperature, whilst no significant change has been observed in the trap density of states.

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소귀나무 수피(양매피) 추출물을 이용한 견직물의 염색성과 기능성 (Dyeability and Function of Silk Fabrics Using Myrica Rubra rind Extract)

  • 이정은
    • 한국의류산업학회지
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    • 제20권5호
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    • pp.608-615
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    • 2018
  • The purpose of this study is to investigate the dyeability and functional properties of dyed fabric with the extract of Myrica rubra rind. For this purpose, the ultraviolet and visible spectra of the bark extracts were investigated. The dyeing temperature, dyeing time, mordant type, mordanting order, mordant concentration and dyeability were investigated. The color fastness based on washing, dry-cleaning, rubbing and light were evaluated by the types of Myrica rubra rind extract used. In addition, the deodorization and antibacterial activity were measured, and the functionality of the silk fabric dyed with the extract of the Myrica rubra rind was evaluated. The result shows that the color strength of the dye was excellent when the Myrica rubra rind was dyed at $80^{\circ}C$ for 80 minutes. The mordant dye color strength was high in the order of Fe mordant> Cu mordant> Al mordant. The dyeability of Al and Cu mordant was high during pre-mordanting compared to Fe mordant, and the dyeability of Fe mordant was high during post-mordanting than Cu and Al mordant. The deodorant property of the dyed fabric stained with the Myrica rubra rind extract was 92.4% and that of antibacterial property was 99.9% for Staphylococcus aureus and Klebsiella pneumoniae bacteria respectively.

제주 송이를 이용한 천연염색 면직물의 기능성 연구 (A Study on Function of Natural Dyeing with Cotton Fabrics Using Jeju scoria)

  • 임은숙;이혜선
    • 한국염색가공학회지
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    • 제23권3호
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    • pp.179-186
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    • 2011
  • For the application of Jeju scoria scattered around the island as a natural dye, cotton fabrics were dyed with the dye and their properties were measured including dyeability, colorfastness, antibacterial activity, deodorization efficiency, ultraviolet protection, and far-infrared emission. The dyed cotton fabrics were in yellowish red and optimal dyeing conditions were obtained with a colorant concentration of 25%(o.w.b) at a temperature of $80^{\circ}C$ for the dyeing time of 120 minutes. The ratings of colorfastness to light, rubbing, perspiration, and washing were 8, 5, 5, and 4~5 respectively. After 15 wash cycles, colorfastness remained as much as 4~5 rating. The cotton fabric dyed with Jeju scoria demonstrated excellent antimicrobial activity and deodorization efficiency of 99.9% and 93.9% respectively. Ultraviolet protection factor was 50+. Far-infrared emission rate and far-infrared emission intensity were 90% and 362(W/$m^2{\cdot}{\mu}m$) respectively. The Jeju scoria can be introduced as a new colorant for the natural dyeing of cotton.

전기화학적 산화를 이용한 염료 처리에 중심합성설계와 반응표면분석법의 적용 (Application of the Central Composite Design and Response Surface Methodology to the Treatment of Dye Using Electrochemical Oxidation)

  • 김동석;박영식
    • 한국환경과학회지
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    • 제18권11호
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    • pp.1225-1234
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    • 2009
  • The aim of this research was to apply experimental design methodology in the optimization condition of electrochemical oxidation of Rhodamine B(RhB). The reactions of electrochemical oxidation were mathematically described as a function of parameters amounts of current, NaCl dosage, pH and time being modeled by the use of the central composite design, which was used for fitting quadratic response surface model. The application of response surface methodology using central composite design(CCD) technique yielded the following regression equation, which is an empirical relationship between the removal efficiency of RhB and test variable in actual variables: RhB removal (%) = 3.977 + 23.279$\cdot$Current + 49.124$\cdot$NaCI - 5.539$\cdot$pH - 8.863$\cdot$time - 22.710$\cdot$Current$\cdot$NaCl + 5.409$\cdot$Current$\cdot$time + 2.390$\cdot$NaCl$\cdot$time + 1.061$\cdot$pH$\cdot$time - $0.570{\cdot}time^2$. The model predicted also agree with the experimentally observed result($R^2$ = 91.9%).

인삼(Panax ginseng C.A. Meyer) 종자의 배발달에 따른 배유의 구조변화 및 조직화학적 연구 (Structural Changes and Histochemical Study of Endosperm on Panax ginseng C.A. Meyer during Embryo Development)

  • 유성철;김유갑
    • Journal of Ginseng Research
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    • 제16권1호
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    • pp.37-43
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    • 1992
  • Structural changes of the endosperm of Panax ginseng C.A. Meyer from fertilization to germination were investigated by light microscope. The endosperm of the ginseng seed is cellular type. Since endosperm cells adjacent embryo continuously breakdown and disappear with the elongation of embryo, the real of endosperm is gradually decreased. As the anatropous ovules of immature seed with green seed coat developes more and more, ovary cells adjacent ovary cavity become abundant by the periclinal division, their size is decreased, hypotrophy of cell wall discern, and they are gradually differentiated in seed coat. Though embryo responds strongly to basic dye at the stage of completion of endosperm formation, tissue of endosperm responds to acidic dye positively Cell wall of embryo and endosperm are composed of primary cell wall not lignified. Endosperm cells adjacent embryo begin to breakdown in the endosperm tissue of indehiscent seed before the beginning of the after-ripening. Dehiscent seed of which seed coat is opened through after-ripening represent the form as a seedling in the result of embryo developments with the formation of organs; radicle, cotyledon, plumule. Umbilifom layer represents strong positive response to the toluidine blue and the basic function. Umbiliform layer that endosperm cells breakdown and disappear is observed clearly at the periphery of the embryo cotylemon, while slightly at the periphery of the radicle.

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Photo Catalytic Activity of CNT-TiO2 Nano Composite in Degrading Anionic and Cationic Dyes

  • Kim, Sang-Jin;Im, Ji-Sun;Kang, Phil-Hyun;Kim, Tae-Jin;Lee, Young-Seak
    • Carbon letters
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    • 제9권4호
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    • pp.294-297
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    • 2008
  • A CNT-$TiO_2$ nano composite was prepared from titanium chloride ($TiCl_4$) via sol-gel process using multi walled carbon nano tube (MWCNT) followed by calcination at $450^{\circ}C$. Spectral analysis revealed that the formed $TiO_2$ resided on the carbon in anatase form. The effect of adsorption was investigated using aqueous solution of methylene blue and procion blue dye. The photochemical reaction of CNT-$TiO_2$ composite in aqueous suspensions was studied under UV illumination in batch process. The reaction was investigated by monitoring the discoloration of the dyes employing UV-Visible spectro-photometeric technique as a function of irradiation time. The catalyst composites were found to be efficient for the photodegradation of the dye.

해양에서의 염료 플럼의 사행에 대한 모델 (A Diagnostic Model for Dye Plume Meandering in Oceanic Waters)

  • Ro, Young-Jae
    • 한국해안해양공학회지
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    • 제2권4호
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    • pp.200-207
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    • 1990
  • 본 연구는 해양에서의 염료 플럼축의 사행에 관한 것이다. 농도 확산장에서의 이러한 과정은 산단 염료 확산장의 무게 중심의 분석에 대하여 속도장의 여러 주기 성분이 원점으로부터의 거리의 함수로서 차별적으로 기여하기 때문에 일어나는 것으로 이해된다. 제시된 진단 모델은 과동장을 보여줄 뿐만 아니라 플럼축이 증폭되어 사행하는 현상까지도 설명할 수 있다. 염표 플럼의 항공사진을 이용한 자료로부터 사행 과동의 파장을 추정한 바 연안 표층수에서 5.5에서 60.3 미터까지 분포하였다. 또한 수치 시뮬레이션을 통하여 사행 플럼 농도장을 예측하였다.

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Studies on the interaction of Azo dyes with cationic surfactant(1)

  • Cho, Yung-Mee;Lee, Wang-Kyu;Kim, Bak-Kwang
    • Archives of Pharmacal Research
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    • 제4권2호
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    • pp.75-84
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    • 1981
  • As the cetyltrimenthy ammonium bromide (CTAB) concentration increases to $2{\times}10^{-4}$/M the absorption maximum of ethyl orange (EO) makes a blue shift from 475 mm to 395 mm. At higher concentration of CTAB than $2{\times}10^{-4}$ / M the absorption maximum shifts to higher wavelength than 395 nm. A new peak at 395 nm is shown to result from the mixed micelle due to dye stacking interaction rather than from a change in dye geometry. Because Raman spectra of EO on interaction with varying amount of CTAB are similar to that of EO in water. EO retains trans azo type on interaction with CTAB. There is a change of c.m.c.s. of CTAB for the mixed micelle in the presence of salt. The effect of added salt on C. M. C. of CTAB for the mixed micelle is given that the logarithm of the c. m. c. is a linear function of the logarithm of the sum of the c. m. c. and the concentration of added salt.

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