• Textile Coloration and Finishing
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• v.32 no.3
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• pp.150-157
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• 2020

Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.

• Journal of the Korean Wood Science and Technology
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• v.31 no.3
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• pp.50-60
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• 2003

The main purpose of this study was to propose the development direction and application method of wood as a landscape material by analysis and investigation of the present condition and characteristics of wood, which is a quite interesting natural material for its beauty as an exterior material. This study is based on the relationships between the establishment of development direction and practical use of exterior wood as a landscape material. The research method used was fieldwork and data analysis. On the analysis of the present condition of wood utilization, it was investigated to need of complement of a design aspect, use method, the limit of use type, and use range. The direction of a durable design for the practical use of exterior wood as landscape materials was established. On the use of exterior wood, first, the characteristics of wood have to be understood. Then exterior wood can be used while preserving its safety and beauty over a long time by physical and chemical treatment. At the same time, an application plan for the practical and effective use of wood as an outdoor landscape material, we concluded that future research in design aspects is needed in consideration of physical, chemical, and structural properties of durable wood materials used in outdoor facilities.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.11a
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• pp.259-260
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• 2012

As RC structures in the marine environment rapidly increase, the interest and the importance of Chloride Penetration durable design have been growing. However, there is hardly any domestic Chloride Penetration durability of RC structures designed analysis programs. Currently, Chloride Penetration durable design method is studied and launched actively as a program in the United States, Europe, Japan and etc., but it is limited to Chloride Penetration durability of RC structures excluded from maintenance construction. Also, the level of dependence on the foreign technology is high; the foreign program is imported and used when needed. The main objective is to compare and to evaluate with the durability assessment program and several conditions when considering the design of Chloride Penetration durability through the programs developed abroad.

• Textile Coloration and Finishing
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• v.33 no.2
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• pp.64-71
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• 2021

Large amount of formaldehyde could be released inevitably during the flame-retardant (FR) treatments or from the finished fabrics using Provatex reagent and Proban polymers which have been used as durable FRs for cotton. A water-soluble cyclophosphazene derivative was synthesized as an ecofriendly phosphorus-based FR for cotton fibers. Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) was synthesized through the substiutution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] methacrylamide at a mole ratio of 1 : 4, which can be cured dually by both alkaline treatment and UV irradiation. More crosslinked networks were produced through the addition of Triacryloyl hexahydrotriazine and Acrylamide as a UV-curable crosslinker and a comonomer respectively. Both flame retardancy and washing durability of the FR cotton were improved synergistically. The durability improvement may be caused by the covalent bond formation of the FR with cellulose and the high degree of polymerization of DCTDCP, which can be verified by the pyrolysis and combustion behaviors analyzed by LOI, TGA, and microcalorimeter.

• Textile Coloration and Finishing
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• v.34 no.1
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• pp.1-9
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• 2022

The durable FR treatments such Pyrovatex and Proban have been used for cotton fibers, while the finishes involve toxic ammonia or formaldehyde release during finishing process or finished products. In this study, ecofriendly flame-retardant treatment of cotton fabrics was carried out using UV-curable formulations of Vinyl bisphosphonic acid (VBPA), Acrylaminide and Triacryloylhexahydro-1,3,5-triazine, as a monomer, a comonomer and a cross-linking agent respectively, which can introduce a cross-linked copolymer networks. With an optimal finish formulation, the flame retardancy of LOI 29.8 was maintained even after 10 laundering cycles. In TGA analysis, the DTGA peak decreased from 389℃ to 252℃ and the amount of char yield increased from 6.1% to 46.1% compared to the untreated cotton. In addition, MCC analysis showed that Peak HR and THR decreased by 59.4% and 69.2% respectively, compared to the untreated cotton. The pyrolysis and combustion behaviors of the FR-treated cotton implied a condensed-phase flame-retarding mechanism.

• Textile Coloration and Finishing
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• v.33 no.4
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• pp.230-237
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• 2021

The flame-retardant (FR) treatments of wool fibers using Hexafluorozirconate/titanate salts and tetrabromophthalic anhydride can cause skin irritation and gas toxicity due to Zr and Br compounds respectively. A water-soluble polyfunctional cyclophosphazene derivative, synthesized through substitution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] metacrylamide, was applied as a durable flame-retardant for wool fabrics. Also, a crosslinked structure was introduced to improve washing durability of the FR-wool, up to 10 laundering cycles, using Acrylamide(AAm) and Triacryloylhexahydrotriazine (TAHT) as a comonomer and a crosslinker respectively. The mole ratios of the TAHT and AAm concentrations compared to the Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) were optimized to 1.33 and 7.5 respectively. In addition, the pyrolysis and combustion properties of the FR wool were assessed using LOI, TGA and microcalorimetry suggesting a solid-phase FR mechanism.

• Proceedings of the KIPE Conference
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• 2001.07a
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• pp.600-603
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• 2001

The method of supplying a single voltage source to a drive has a weak point that we can not determine whether discharging cells of a upper panel in a PDP(Plasma display panel) operate properly or not in the step of testing a durable voltage. From this paper, we can make more reliable products by the design-method of a power-module, for testing a durable voltage, that can determine if discharging cells in a upper pannel in a PDP have something wrong in variously supplied voltage sources.

• Computational Structural Engineering
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• v.23 no.5
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• pp.23-33
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• 2010

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.147-148
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• 2019

Long-life housing should be durable enough to maintain structural safety even after long-term use by applying a durable structural system. Also, the residence space can be repaired according to the life cycle of the resident, and the space can be easily changed. The purpose of this study is to propose a plan which can increase the variability of unit space of long - lived houses in terms of architectural planning. We propose a new plan that can embody flexibility and ease of repair through the design of long life.

• Journal of Adhesion and Interface
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• v.7 no.4
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• pp.60-64
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• 2006

In modern vehicle construction the search for means of weight reduction, improving durability, increasing comfort and raising body stiffness are issues of priority to the design engineer. The intelligent usage of many materials such as high strength steel, light-alloys and plastics enables a significant vehicle weight reduction to be achieved. The classical joining techniques used in the automobile industry need to be newly-evaluated since they often do not present workable solutions for such mixed-material connections, for example aluminium/steel. Calculation/simulation methods have made progress as a key factor for broader and more cost-effective implementation of structural bonding. This will lead to reduction of spotwelds and accelerate the car development. A special focus of the paper is the use of high strength steel grades. It will be shown that adhesive bonding is a key tool for yielding the potential of advanced high strength steel for low gauging without compromising the stiffness. The latest status of adhesive development has been described. Improvements with physical strength and glass temperature as well as of process relevant properties are shown. Also the situation regarding occupational hygiene is treated, showing that by further spotweld point reduction the emission around the working area can be even lowered against the current praxis. High performing lightweight design cannot longer do without high performing crash durable adhesives.