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http://dx.doi.org/10.5764/TCF.2021.33.4.230

Eco-friendly Durable Flame-Retardant Finish of Wool Fabrics Using a UV-curable Cyclophosphazene Derivative  

Baek, Ji-Yun (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Jang, Jinho (Department of Materials Design Engineering, Kumoh National Institute of Technology)
Publication Information
Textile Coloration and Finishing / v.33, no.4, 2021 , pp. 230-237 More about this Journal
Abstract
The flame-retardant (FR) treatments of wool fibers using Hexafluorozirconate/titanate salts and tetrabromophthalic anhydride can cause skin irritation and gas toxicity due to Zr and Br compounds respectively. A water-soluble polyfunctional cyclophosphazene derivative, synthesized through substitution reaction of Hexachloro cyclophosphazene and N-[3-(Dimethylamino)propyl] metacrylamide, was applied as a durable flame-retardant for wool fabrics. Also, a crosslinked structure was introduced to improve washing durability of the FR-wool, up to 10 laundering cycles, using Acrylamide(AAm) and Triacryloylhexahydrotriazine (TAHT) as a comonomer and a crosslinker respectively. The mole ratios of the TAHT and AAm concentrations compared to the Dichloro tetrakis{N-[3-(Dimethylamino)propyl]methacrylamido} cyclcophosphazene (DCTDCP) were optimized to 1.33 and 7.5 respectively. In addition, the pyrolysis and combustion properties of the FR wool were assessed using LOI, TGA and microcalorimetry suggesting a solid-phase FR mechanism.
Keywords
durable; flame retardant; wool; crosslink; formaldehyde-free;
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  • Reference
1 K. L. Mittal and T. Bahners, "Textile Finishing: Recent Developments and Future Trends", Scrivener Publishing, USA, pp.69-127, 2017.
2 X. W. Cheng, J. P. Guan, G. Chen, X. H. Yang, and R. C. Tang, Adsorption and Flame Retardant Properties of Bio-based Phytic acid on Wool Fabric, Polymers, 8(4), 122(2016).   DOI
3 S. Basak, K. K. Samanata, S. K. Chattopadhyay, P. Pandit, and S. Maiti, Green Fire Retardant Finishing and Combined Dyeing of Proteinous Wool Fabric, Coloration Technology, 132, 135(2016).   DOI
4 H. J. Choi, D. J. Gong, C. Youn, and S. Y. Yeo, Preparation of Flammability Artificial Hair Based on Super Engineering Plastic, Textile Coloration and Finishing, 32, 103(2020).   DOI
5 F. Zhang, J. Guan, and G. Chen, Performance of Flame Retardant Wool Fabric Grafted with Vinyl Phosphate, J. Eng. Fibers Fabrics, 9, 32(2014).
6 S. Basak, K. K. Samanta, S. K. Chattopadhyay, S. Saxena, and R. Narkar, Banana Pseudostem Sap and Boric Acid - A New Green Intumescent for Making Self-extinguishing Cotton Fabric, Indian Journal of Fibre and Textile Research, 43, 36(2018).
7 J. Alongi, R. A. Carletto, A. D. Balsio, F. Cuttica, F. Carosio, F. Bosco, and G. Malucelli, Intrinsic Intumescent-like Flame Retardant Properties of DNA-treated Cotton Fabrics, Carbohydr. Polym., 96, 296(2013).   DOI
8 F. Bosco, R. A. Carletto, J. Alongi, L. Marmo, A. D. Blasio, and G. Malucelli, Thermal Stability and Flame Resistance of Cotton Fabrics Treated with Whey Proteins, Carbohydr. Polym., 94, 372(2012).   DOI
9 X. Zhang, X. Y. Zhou, X. W. Cheng, and R. C. Tang, Phytic Acid as an Eco-friendly Flame Retardant for Silk/Wool Blend: A Comparative Study with Fluorotitanate and Fluorozirconate, Journal of Cleaner Production, 198, 1044(2018).   DOI
10 G. Malucelli, F. Bosco, J. Alongi, F. Carosio, A. D. Blasio, C. Mollea, F. Cuttica, and A. Casale, Biomacromolecules as Novel Green Flame Retardant Systems for Textiles: An Overview, RSC Adv., 4, 46024(2014).   DOI
11 A. Morgan, "Non-Halogenated Flame Retardant Handbook", Scrivener Publishing, USA, pp.50-55, 2014.
12 K. A. Salmeia, S. Gaan, and G. Malucelli, Recent Advances for Flame Retardancy of Textiles Based on Phosphorus Chemistry, Polymers, 8, 319(2016).   DOI
13 X. W. Cheng, J. P. Guan, G. Chen, X. H. Yang, and R. C. Tang, Durable Flame Retardant Wool Fabric treated by Phytic Acid and TiO2 Using an Exhaustion-assisted Pad-Dry-Cure Process, Thermochimica Acta, 665, 28(2018).   DOI
14 J. H. Kim and J. Jang, Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophos phazene and Triethanolamine, Textile Coloration and Finishing, 32, 150(2020).   DOI
15 J. H. Kim and J. Jang, Durable Flame-Retardant Finish of Cotton Fabrics Using a Water-soluble Cyclophosphazene Derivative, Textile Coloration and Finishing, 33, 64(2021).   DOI
16 F. Carosio, A. D. Blasio, F. Cuttica, J. Alongi, and G. Malucelli, Flame Retardancy of Polyester and Polyester-Cotton Blends Treated with Caseins, Ind. Eng. Chem. Res., 53, 3917(2014).   DOI
17 J. Alongi and G. Malucelli, Cotton Flame Retardancy: State of the Art and Future Perspectives, RSC Adv., 5, 24239 (2015).   DOI
18 O. A. Mohamed and F. A. Abdel-Mohdy, Preparation of Flame-Retardant Leather Pretreated with Pyrovatex CP, J. Appl. Polym. Sci., 99, 2039(2006).   DOI