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Observation of Corrosion Behavior with Aluminum 5052 Alloy by Modulating Anodization Time (양극산화 공정시간에 따른 알루미늄 5052 합금의 산화피막 성장 및 내식성 관찰)

  • Ji, HyeJeong;Choi, Dongjin;Jeong, Chanyoung
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.67-67
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    • 2018
  • The 5xxx series aluminum alloys are recently used in not only marine system but also automotive area because of a low density material, good mechanical properties and better resistance to corrosion. However, Aluminum alloys are less resistant than the purest aluminum such as 1xxx aluminum alloy. Electrochemical anodization technique has attracted in the area of surface treatment because of a simple procedure, a low-cost efficiency than other techniques such as lithography and a large volume of productivity, and so on. Here, The relationship between the corrosion behavior and the thickness of aluminum anodic oxide have been studied. Prior to anodization, The 5052 aluminum sheets ($30{\times}20{\times}1mm$) were degreased by ultra-sonication in acetone and ethanol for 10 minutes and eletropolished in a mixture of perchloric acid and ethanol (1:4, volume ratio) under an applied potential of 20V for 60 seconds to obtain a regular surface. During anodization process, Aluminum alloy was used as a working electrode and a platinum was used as a counter electrode. The two electrodes were separated at a distance of 5cm. The applied voltage of anodization is conducted at 40V in a 0.3M oxalic acid solution at $0^{\circ}C$ with appropriate magnetic stirring. The surface morphology and the thickness of AAO films was observed with a Scanning Electron Microscopy (SEM). The corrosion behavior of all samples was evaluated by an open-circuit potential and potentio-dynamic polarization test in 3.5wt% NaCl solution. Thus, The corrosion resistance of 5052 aluminum alloy is improved by the formation of an anodized oxide film as function of increase anodization time which artificially develops on the metal surface. The detailed electrochemical behavior of aluminum 5052 alloy will be discussed in view of the surface structures modified by anodization conditions such as applied voltages, concentration of electrolyte, and temperature of electrolyte.

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The Effect of a Six-Week Sling Exercise on Flexibility, Balance, Muscular Strength, Pelvic Tilt Angle in Age of 20 Woman Low Back Pain (20대 여성 요통환자의 6주간 슬링운동이 유연성, 균형, 근력 및 골반경사각에 미치는 영향)

  • Seo, Dungyeol;Lee, Youngsin;Lee, Dongjin;Kim, Sangyeop
    • Journal of The Korean Society of Integrative Medicine
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    • v.1 no.2
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    • pp.1-12
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    • 2013
  • Purpose : The purpose of this study was to evaluate the effect of 6 weeks of sling exercises on female patients 20 years of age with low back pain according to flexibility, balance, muscle strength and pelvic tilt. Method : The 20 female patients who complained of back pain were divided into two groups. The experimental group exercised for 40 minutes, 3 times a week for 6 weeks. The control group did not. Both groups were measure for flexibility, balance, muscular strength, and pelvic tilt angle. Result : Curvature of the experimental flexibility, stretch, balance, muscle strength of the trunk forward, backward, left rotation, right rotation for the sling exercise group had significant differences. However, pelvic tilt did not show a significant difference. Control of the stretch of the flexibility, balance, and muscle strength of the trunk posterior showed significant differences for the sling exercise group. Conclusion : Although significant differences were found in flexibility, balance, muscular strength, there was no difference in pelvic tilt. When selecting subjects, we believe patients with regular patterns of pain will be more effective for statistical analysis of the changes in pelvic tilt.

Surface Modification of Polymer Films by Vapor Phase Photografting of Functional Monomers (기상 UV 그라프트 반응에 의한 고분자 필름의 표면 개질)

  • Oh, Seung Hee;Oh, Se Heang;Lee, Jin Ho
    • Journal of Adhesion and Interface
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    • v.1 no.1
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    • pp.23-29
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    • 2000
  • Surface modification of hydrophobic polymeric materials to be hydrophilic or to have specific functional groups is of great importance for a diversity of applications of the materials. In this study, polyethylene (PE) film surfaces were modified by vapor phase photografting of hydrophilic vinyl monomers with different functional groups. The functional monomers were introduced on PE films by introducing the monomers in vapor phase using a vapor phase photografting apparatus designed by our laboratory. Functional monomers used were acrylic acid (negatively chargeable), acrylamide and allylalcohol (neutral), and allylamine and N,N-dimethyl aminopropyl acryamide (positively charged). The functional monomer-grafted PE film surfaces were characterized by the measurement of water contact angles and the attenuated total reflectance Fourier-transform infrared spectroscopy. The vapor phase photografting seems to be effective means for introduction of various functional groups onto polymeric substrates.

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An Analysis of the Water Quality Improvement Measures and Evaluation of Wonju Stream (원주천 수질개선 방안 및 개선효과 평가)

  • Kum, Donghyuk;Shin, Minhwan;Yu, Nayeong;Lee, Seolo;Kim, Dongjin;Sung, Younsoo;Lee, Sang Soo
    • Journal of The Korean Society of Agricultural Engineers
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    • v.63 no.1
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    • pp.61-73
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    • 2021
  • Recently, the deterioration of water quality in Wonju stream has been reported due to the increase in diverse pollution sources along with community development and urbanization. Various types of attempts with a huge budget were made for better water quality so far, but its effectiveness is still doubted. In order to establish site-oriented measures for water quality improvement, the topographic and hydrologic factors were evaluated based on site inspection and survey. As the major streams merged into the Wonju stream, the Hwa and Heungyang streams were found to have higher pollution loads and contributions compared to other streams due to the scattered livestock farms and industries, and vulnerable land use. Notably, the discharge water from the Wonju Public Sewage Treatment Plant had the highest level of pollution load, impacting on the water quality of Wonju Stream. According to the SWAT model as water quality measures, the improvement effect of water quality in this treatment plant can be reached to the reductions in BOD 11.06%, T-N 23.56%, T-P 10.60% when the proper managements applied, whereas the improvement of water quality would be 3.89%, 1.23%, and 3.32% for BOD, T-N, T-P, respectively, for the industries. The reduction of the livestock industry was generally very high as a pollution source, but it was not much higher at the end of Wonju Stream than other measures. These results recommended that the water q uality improvement measures should be designated for each upper-middle-lower section in Wonju stream.

Ag Sintering Die Attach Technology for Wide-bandgap Power Semiconductor Packaging (Wide-bandgap 전력반도체 패키징을 위한 Ag 소결 다이접합 기술)

  • Min-Su Kim;Dongjin Kim
    • Journal of the Microelectronics and Packaging Society
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    • v.30 no.1
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    • pp.1-16
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    • 2023
  • Recently, the shift to next-generation wide-bandgap (WBG) power semiconductor for electric vehicle is accelerated due to the need to improve power conversion efficiency and to overcome the limitation of conventional Si power semiconductor. With the adoption of WBG semiconductor, it is also required that the packaging materials for power modules have high temperature durability. As an alternative to conventional high-temperature Pb-based solder, Ag sintering die attach, which is one of the power module packaging process, is receiving attention. In this study, we will introduce the recent research trends on the Ag sintering die attach process. The effects of sintering parameters on the bonding properties and methodology on the exact physical properties of Ag sintered layer by the realization 3D image are discussed. In addition, trends in thermal shock and power cycle reliability test results for power module are discussed.

Optical and Electrical Properties of ZnO Hybrid Structure Grown on Glass Substrate by Metal Organic Chemical Vapor Deposition (유기금속화학증착법으로 유리기판 위에 성장된 산화아연 하이브리드 구조의 광학적 전기적 특성)

  • Kim, Dae-Sik;Kang, Byung Hoon;Lee, Chang-Min;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.543-549
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    • 2014
  • A zinc oxide (ZnO) hybrid structure was successfully fabricated on a glass substrate by metal organic chemical vapor deposition (MOCVD). In-situ growth of a multi-dimensional ZnO hybrid structure was achieved by adjusting the growth temperature to determine the morphologies of either film or nanorods without any catalysts such as Au, Cu, Co, or Sn. The ZnO hybrid structure was composed of one-dimensional (1D) nanorods grown continuously on the two-dimensional (2D) ZnO film. The ZnO film of 2D mode was grown at a relatively low temperature, whereas the ZnO nanorods of 1D mode were grown at a higher temperature. The change of the morphologies of these materials led to improvements of the electrical and optical properties. The ZnO hybrid structure was characterized using various analytical tools. Scanning electron microscopy (SEM) was used to determine the surface morphology of the nanorods, which had grown well on the thin film. The structural characteristics of the polycrystalline ZnO hybrid grown on amorphous glass substrate were investigated by X-ray diffraction (XRD). Hall-effect measurement and a four-point probe were used to characterize the electrical properties. The hybrid structure was shown to be very effective at improving the electrical and the optical properties, decreasing the sheet resistance and the reflectance, and increasing the transmittance via refractive index (RI) engineering. The ZnO hybrid structure grown by MOCVD is very promising for opto-electronic devices as Photoconductive UV Detectors, anti-reflection coatings (ARC), and transparent conductive oxides (TCO).

Numerical Analysis and Simplified Mathematical Modeling of Separation Mechanism for the Ball-type Separation Bolt (볼타입 분리볼트 분리 메커니즘의 수치해석 및 간략화 모델링)

  • Hwang, Dae-Hyun;Lee, Juho;Han, Jae-Hung;Lee, Yeungjo;Kim, Dongjin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.3
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    • pp.63-70
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    • 2016
  • The pyrotechnic separation devices are widely used in space systems and guided weapons during the launching and operations, however, they generate intensive pyroshock and fragments that can cause critical damages or the malfunction of electric devices onboard. There have been proposed many types of alternative devices to avoid pyro-induced problems since 1960's. A ball-type separation bolt is the one of alternative Pyrotechnic Mechanical Devices (PMD). In this study, the detail separation behavior of the ball-type separation bolt is analyzed using ANSYS AUTODYN. A simplified one-dimensional mathematical model, consisting of a combustion model and 5-stages of differential equation of motions, is also established to effectively describe the entire separation process.

Heat Treatment of Carbonized Photoresist Mask with Ammonia for Epitaxial Lateral Overgrowth of a-plane GaN on R-plane Sapphire

  • Kim, Dae-sik;Kwon, Jun-hyuck;Jhin, Junggeun;Byun, Dongjin
    • Korean Journal of Materials Research
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    • v.28 no.4
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    • pp.208-213
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    • 2018
  • Epitaxial ($11{\bar{2}}0$) a-plane GaN films were grown on a ($1{\bar{1}}02$) R-plane sapphire substrate with photoresist (PR) masks using metal organic chemical vapor deposition (MOCVD). The PR mask with striped patterns was prepared using an ex-situ lithography process, whereas carbonization and heat treatment of the PR mask were carried out using an in-situ MOCVD. The heat treatment of the PR mask was continuously conducted in ambient $H_2/NH_3$ mixture gas at $1140^{\circ}C$ after carbonization by the pyrolysis in ambient $H_2$ at $1100^{\circ}C$. As the time of the heat treatment progressed, the striped patterns of the carbonized PR mask shrank. The heat treatment of the carbonized PR mask facilitated epitaxial lateral overgrowth (ELO) of a-plane GaN films without carbon contamination on the R-plane sapphire substrate. Thhe surface morphology of a-plane GaN films was investigated by scanning electron microscopy and atomic force microscopy. The structural characteristics of a-plane GaN films on an R-plane sapphire substrate were evaluated by ${\omega}-2{\theta}$ high-resolution X-ray diffraction. The a-plane GaN films were characterized by X-ray photoelectron spectroscopy (XPS) to determine carbon contamination from carbonized PR masks in the GaN film bulk. After $Ar^+$ ion etching, XPS spectra indicated that carbon contamination exists only in the surface region. Finally, the heat treatment of carbonized PR masks was used to grow high-quality a-plane GaN films without carbon contamination. This approach showed the promising potential of the ELO process by using a PR mask.

Seasonal Variation in Macroalgal Community Structure around the Byeonsan Peninsula, Korea (변산반도 해조류 군집구조의 계절적 변동)

  • Han, Su Jin;Lee, Ji Hee;Jeon, Da Vine;Oh, Ji Chul;Kim, Bo Yeon;Park, Seo Kyoung;Choi, Han Gil;Nam, Ki Wan
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.47 no.3
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    • pp.274-282
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    • 2014
  • We examined seasonal variation in the structure of marine macroalgal communities at five sites around the Byeonsan Peninsula, Korea, from January to October 2011. Sixty eight species were identified, including 11 green, 17 brown and 40 red algae. Species richness was highest at Gyeokpo (51 species) followed by Sambal (47), Gosapo (34), Byeonsan (33), and Habgoo (18). Seaweed biomass ranged from 12.98 to 145.33 g dry $wt/m^2$, with maximum and minimum biomasses at Gyeokpo and Habgoo, respectively. Sargassum thunbergii was the representative alga species occupying 47.89% of the total biomass. The dominant seaweeds were S. thunbergii, Corallina pilulifera, Ulva spp, Gracilaria vermiculophylla, and Carpopeltis affinis. No distinctive vertical distribution of seaweeds was found because S. thunbergii, Ulva spp, and G. vermiculophylla were all distributed from high to low shore. Community indices were as follows: dominance index (DI), 0.44-0.61; richness index (R), 6.27-10.35; evenness index (J'), 0.38-0.59; and diversity index (H'), 1.48-1.71. Gyeokpo had the most biomass and highest species richness, and the lowest percentage of Ulva species. However, species richness declined at Gyeokpo, from 78 to 51 species within 10 years, implying that eutrophication and sedimentation from Mankyeong and Dongjin rivers have reduced the stability of seaweed communities.

Factors and Recovery of Herbicide Phytotoxicity on Direct-seeded Rice - 2. Phytotoxicity of Herbicide with Nutrient Condition (직파(直播) 벼의 제초제(除草劑) 약해(藥害) 요인(要因)과 회복(回復) 연구(硏究) - 2. 영양(營養) 조건(條件)에 따른 약해(藥害))

  • Im, Il-Bin;Usui, K.
    • Korean Journal of Weed Science
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    • v.17 no.1
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    • pp.24-30
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    • 1997
  • The influence of nutrients on the phytotoxicity of herbicides (bensulfuron-methyl, pyrazosulfuron-ethyl, imazosulfuron, dimepiperate, and molinate) was investigated in controlled-environment growth chamber with direct-seeded rice (Oryza sativa L. cv. Dongjin). The phytotoxicity of bensulfuron-methyl, pyrazosulfuron-ethyl, and imazosulfuron for rice was greater in nutrient culture than in no-nutrient condition. The root growth of rice applied with these herbicides was more inhibited than the shoot growth. The most severe inhibition was obtained with pyrazosulfuron-ethyl application. The growth inhibition of rice applied by dimepiperate was increased under no-nutrient culture condition. Dimepiperate suppressed more remarkably shoot growth than root. Especially the shoot elongation was much more inhibited than the others. The shoot growth inhibition in rice applied by molinate was severer than the root. The shoot growth was reduced under nutrient culture condition, while the root growth was reduced under no-nutrient culture.

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