• Title/Summary/Keyword: Dominant Properties

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Basic Properties of Stones used for Cooking Utensils and Their Leaching Characteristics for Heavy Metal Elements (조리용구용 석재의 기초 특성과 중금속 원소의 용출 특성)

  • 진호일;김신자;김복란;민경원
    • Economic and Environmental Geology
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    • v.35 no.4
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    • pp.347-353
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    • 2002
  • Dominant rock types of stones used presently for cooking utensils in Korea are pyroxenite, breccia and biotite diorite. Pyroxenite and biotite diorite relatively abundant in mafic minerals have higher specific gravities of 3.0 than breccia of 2.5. Breccia shows the highest absorption (2.9%) among three stones used as cooking utensils and pH value of three stone types shows the alkaline range of 9.7 to 9.9. Among the studied stones used for cooking utensils, biotite diorite is the most durable against abrasion and has the highest strength and therefore, it is expected to be used effectively for the longest time except for other specific causes. Heavy metals such as Cu, Pb, Co, Cr and Ni were leached lower than their detection limit (0.1 ppm) regardless of reaction time and initial pH value of solution. But the leached contents of Fe are various with rock types and leaching conditions and those by acidic solution are generally 1.8 to 31 times higher than those by neutral solution. Breccia and biotite diorite show the highest leached content of Fe in cases of neutral and acidic solutions, respectively. Standard criteria of leached heavy metals and macrominerals should be studied thoroughly to utilize stones for cooking utensils of high quality which are harmless to the human body. Also it is required to examine mon detailed abiochemical properties of various stone types used for cooking utensils.

Soil Environmental Characteristics According to the Environmental Gradient in Seabird Breeding Sites (환경구배에 따른 바닷새 번식지 토양환경 특성)

  • Kim, Jin-Seok;Ihm, Byung-Sun;Park, Jung-Won;Myeong, Hyeon-Ho
    • Korean Journal of Ecology and Environment
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    • v.46 no.1
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    • pp.18-24
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    • 2013
  • The objective of study was to protect seabird breeding site and vegetation restoration of Chilbal and Sokugul island in Shinan county Jeonnam province, April and December 2011. We analyzed the soil properties according to the dominant communities and environmental gradient. As a result, It was highly analyzed to moisture content, organic matter, salinity, total nitrogen in Commelina communis community and low analyzed in Achyranthes japonica community. Carex boottiana community which mainly used as a seabird habitat has a wide range and Achyranthes japonica and Artemisia princeps community was narrowed to soil properties. Soil pH of Carex boottiana community in Sogugul island was the lowest on 3.14 and Peucedanum japonicum community was the highest. Soil moisture content and organic matter was analyzed by the high value in Peucedanum japonicum community. In contrast, Achyranthes japonica was the low value and Carex boottiana community was analyzed the highest on the salinity and total nitrogen. On the soil environmental characteristics according to the environmental gradient, The higher altitude, moisture content, organic matter, salinity and total nitrogen was the lower in Chilbal island. In the case of Sokugul island, the altitude difference did not show the characteristics of soil environmental factors for small area and low altitude. But moisture content is similar to soil property of Chilbal island. Soil property was strongly acid soil because of seabird dropping. This results will be helpful to manage the invasive plants.

Color Sensibility Factors for Yellowish and Reddish Natural Dyed Fabrics by 40s Middle-Aged Consumers (황색과 적색계열 천연염색 직물에 대한 사십대 중년층 소비자의 색채감성요인)

  • Yi, Eun-Jou;Choi, Jong-Myoung
    • Science of Emotion and Sensibility
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    • v.12 no.1
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    • pp.109-120
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    • 2009
  • This study was carried out in order to investigate color sensation and sensibility for yellowish natural dye fabrics and reddish ones and to establish prediction models for color sensibility factors of them by color sensation and the related physical measurements focusing on 40s middle-aged people. Eight fabric stimuli which were dyed with a variety of yellowish or reddish natural dyes was subjectively evaluated in terms of color sensation and sensibility by 40s aged participants. As results, three color sensibility factors including 'Active', 'Characteristic', and 'Relax' were extracted and they were examined in respect of their relationships with color sensation and physical color properties. Color sensibility factor 'Active', the dominant factor for the naturally dyed fabrics was explained by $L^*$ and sensation 'Deep' in its predictive model and a yellowish fabric dyed with 300% solution of armur cork unmordanted was perceived the strongest in the factor. Factor 'Characteristic' was predicted by both $a^*$ and sensation 'Light' and reddish natural dye fabrics tended to be felt more strongly for it. Color sensation 'Strong' was the only predictor for factor 'Relax' in that naturally dyed fabrics with lower values for the sensation seemed to show higher 'Relax' factor and a reddish fabric dyed with safflower 125% was the highest for the color sensibility factor. These results could be utilized to design color-sensible natural dye fabrics for middle-aged people.

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Thermoelectric Properties of Al4C3-doped α-SiC (Al4C3 첨가 α-SiC의 열전변환특성)

  • 박영석;배철훈
    • Journal of the Korean Ceramic Society
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    • v.40 no.10
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    • pp.991-997
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    • 2003
  • The effect of A1$_4$C$_3$ additive on the thermoelectric properties of SiC ceramics were studied. Porous SiC ceramics with 47∼59% relative density were fabricated by sintering the pressed $\alpha$-SiC powder compacts with A1$_4$C$_3$at 2100∼220$0^{\circ}C$ for 3 h in Ar atmosphere. Crystalline phases of the sintered bodies were identified by powder X-Ray Diffraction (XRD) and their microstructures were observed with a Scanning Electron Microscope (SEM). In the case of A1$_4$C$_3$ addition, the phase transformation of 6H-SiC to 4H-SiC could be observed during sintering. The Seebeck coefficient and electrical conductivity were measured at 550∼95$0^{\circ}C$ in Ar atmosphere. In the case of undoped specimens, the Seebeck coefficients were positive (p-type semiconducting) possibly due to a dominant effect of the acceptor impurities (Al, Fe) contained in the starting powder and electrical conductivity increased as increasing sintering temperature. Electrical conductivity of A1$_4$C$_3$doped specimen is larger than that of undoped specimen under the same condition, which might be due to the reverse phase transformation and increasing of carrier density. And the Seebeck coefficient of A1$_4$C$_3$ doped specimen is also larger than that of undoped specimen. The density of specimen, the amount of addition and sintering atmosphere had significant effects on the thermoelectric property.

The Photoluminance Properties of Blue Phosphor with Chemical Composition in BaO-MgO-$Al_2O_3$ System (BaO-MgO-$Al_2O_3$계에서 조성변화에 따른 청색 형광체의 발광특성)

  • Park, Sang-Hyun;Kong, Myung-Sun;Lee, Rhim-Youl
    • Korean Journal of Materials Research
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    • v.8 no.6
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    • pp.520-525
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    • 1998
  • The optical properties with chemical composition change in BaO- MgO-$AI_2O_3$, system activated by divalent Eu ion were investigated under 254nm ultraviolet(UV) and 147nm vacuum ultraviolet(VUV). These phosphors emitted a blue light at a dominant wavelength of $\lambda$=445nm under UV and VUV irradiations. It was found that the brightness of $BaMgAI_{14}O_{23}$ phosphor increased with Eu concentration up to 10% under UV but it showed a maximum emitting intensity at 5% Eu for VUV. The emitting intensity of blue color of $BaMgAl_{10}O_{l7}$ phosphor was higher than that of $BaMgAI_{14}O_{23}$for both excitation. A further improvement in brightness was obtained for $Ba_{o.9}Ca_{0.1}MaAl_{14}O_{23}$ and $Ba_{0.9}Sr_{0.1}MgAl_{10}O_{17}$ phosphor synthesized by the substition of $Ba^{+2}$ ion with O.lmole of $Ca^{+2}$ or $Sr^{+2}$ ions in $BaMgAl_{IO}O_{17}$: Eu phosphor.

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Synthesis and Properties of SrMoO4 Phosphors Doped with Various Rare Earth Ions for Anti-Counterfeiting Applications (위조 방지 분야에 응용 가능한 다양한 희토류 이온이 도핑된 SrMoO4 형광체의 제조 및 특성)

  • Moon, Tae-Ok;Jung, Jae-Yong;Cho, Shinho
    • Korean Journal of Materials Research
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    • v.30 no.8
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    • pp.406-412
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    • 2020
  • SrMoO4:RE3+ (RE=Dy, Sm, Tb, Eu, Dy/Sm) phosphors are prepared by co-precipitation method. The effects of the type and the molar ratio of activator ions on the structural, morphological, and optical properties of the phosphor particles are investigated. X-ray diffraction data reveal that all the phosphors have a tetragonal system with a main (112) diffraction peak. The emission spectra of the SrMoO4 phosphors doped with several activator ions indicate different multicolor emissions: strong yellow-emitting light at 573 nm for Dy3+, red light at 643 nm for Sm3+, green light at 545 nm for Tb3+, and reddish orange light at 614 nm for Eu3+ activator ions. The Dy3+ singly-doped SrMoO4 phosphor shows two dominant emission peaks at 479 and 573 nm corresponding to the 4F9/26H15/2 magnetic dipole transition and 4F9/26H13/2 electric dipole transition, respectively. For Dy3+ and Sm3+ doubly-doped SrMoO4 phosphors, two kinds of emission peaks are observed. The two emission peaks at 479 and 573 nm are attributed to 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+ and two emission bands centered at 599 and 643 nm are ascribed to 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+. As the concentration of Sm3+ increases from 1 to 5 mol%, the intensities of the emission bands of Dy3+ gradually decrease; those of Sm3+ slowly increase and reach maxima at 5 mol% of Sm3+ ions, and then rapidly decrease with increasing molar ratio of Sm3+ ions due to the concentration quenching effect. Fluorescent security inks based on as-prepared phosphors are synthesized and designed to demonstrate an anti-counterfeiting application.

An Investigation on the Magnetic Properties of Melt-Spun Fe-Pr-C Alloys (Melt-Spun Fe-Pr-C 합금의 자기적 특성 조사)

  • 장태석;조대형
    • Journal of the Korean Magnetics Society
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    • v.7 no.4
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    • pp.173-179
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    • 1997
  • Change in phases, microstructures, and magnetic properties by the variation of quench rate and heat treatment were investigated for melt-spun $Fe_{77}Pr_{15}C_8$ ribbons. The amorphization of as-spun ribbons increased as the quench rate increased. As a result, the ribbon quenched at 40 m/s was almost entirely amorphous. Similarly to cast alloys, the primary phase in crystalline ribbons quenched at 10 m/s was $\alpha$-Fe followed by the secondary $Fe_{17}Pr_2C_x$. Crystalline phases were still dominant in the ribbon spun at 20 m/s, but in this case crystallization of $Fe_{17}Pr_2C_x$ was remarkable with a little suppression of $\alpha$-Fe. At 30 m/s an amorphous phase obviously dominated in the as-spun ribbons with small fraction of crystals. Therefore, substantial amount of hard magnetic $Fe_{14}Pr_2C$ was not obtained from the as-spun state but, as in cast alloys, produced only by a solid-state transformation. Within a few minutes fine grains of $Fe_{14}Pr_2C$ were easily obtained at relatively low temperature when the degree of amorphization of as-spun ribbons was higher. The grain size of $Fe_{14}Pr_2C$ was well less than 1${\mu}{\textrm}{m}$. The ribbons quenched at 20 or 30 m/s yielded higher coercivities after heat treatment.

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Physicochemical Properties of Traditional Chonggugjang Produced in Different Regions (전통청국장의 이화학적 특성)

  • Yoo, Seon-Mi;Choe, Jeong-Sook;Park, Hong-Ju;Hong, Sun-Pyo;Chang, Chang-Moon;Kim, Jin-Sook
    • Applied Biological Chemistry
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    • v.41 no.5
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    • pp.377-383
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    • 1998
  • This study was undertaken to obtain the fundamental data for improving the quality of Korean traditional chonggugjang. To compare the physicochemical properties of traditional chonggugjang produced in different regions, sixty-seven chonggugjang samples collected at nine provinces were analyzed. The average moisture, protein, fat, non-fibrous carbohydrate, fiber, ash, amino nitrogen contents and pH value of collected chonggugjang samples were 55.0%, 17.6%, 3.3%, 13.3%, 4.9%, 5.8%, 0.23%, and 7.21, respectively. The average fatty acid compositions of chonggugjang were 53.8% for linoleic, 21.1% for oleic, 12.4% for palmitic, 9.0% for linolenic, and 3.7% for stearic acid. Traditional chonggugjang contained large amounts of glutamic acid, aspartic acid, and leucine, but less than 0.2% of cysteine and methionine. The average free sugar content was 3.3%, and the dominant free sugar among them were sucrose and galactose. The total average organic acid content of the samples analyzed was 883.0 mg% and citric, acetic, latic, malonic, succinic, formic, tartaric acid were also detected. The Hunter's color L, a, and b values of samples were 49.1, 7, 2, and hardness was $8.3\;kg/{\Phi}20\;mm$.

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Defects and Electrical Properties of NiO and Co3O4-doped ZnO-Bi2O3-Sb2O3 Ceramics (NiO와 Co3O4를 첨가한 ZnO-Bi2O3-b2O3 세라믹스의 결함과 전기적 특성)

  • Hong, Youn-Woo;Lee, Young-Jin;Kim, Sei-Ki;Kim, Jin-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.1
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    • pp.38-43
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    • 2013
  • In this study we aims to examine the effects of $Co_3O_4$ and NiO doping on the defects and electrical properties in ZnO-$Bi_2O_3-Sb_2O_3$ (Sb/Bi=0.5) varistors. It seemed to form ${Zn_i}^{{\cdot}{\cdot}}$(0.20 eV) and ${V_o}^{\cdot}$(0.33 eV) as dominant defects in Co and Ni co-doped ZBS system, however only ${V_o}^{\cdot}$ appeared in Co- or Ni-doped ZBS. Even though the same defects it was different in capacitance (1.5~4.5 nF) and resistance ($0.3{\sim}9.5k{\Omega}$). The varistor characteristics were improved with Co and Co+Ni doping (non-linear coefficient, ${\alpha}$= 36 and 29, relatively) in ZBS. The various parameters ($N_d=1.43{\sim}2.33{\times}10^{17}cm^{-3}$, $N_t=1.40{\sim}2.28{\times}10^{12}cm^{-2}$, ${\Phi}b$=1.76~2.37 V, W= 98~118 nm) calculated from the C-V characteristics in our systems did not depend greatly on the type of dopant, which were in the range of a typical ZnO varistors. It should be derived a improved C-V equation carefully for more reliable parameters because the variation of the varistor capacitance as a function of the applied dc voltage is depend on the defect, frequency, and temperature.

Optical Properties of MgMoO4:Dy3+,Eu3+ Phosphors Prepared with Different Eu3+ Molar Ratios (Eu3+ 이온의 몰 비 변화에 따른 MgMoO4:Dy3+,Eu3+ 형광체의 광학 특성)

  • Kim, Jung Dae;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.3
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    • pp.186-191
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    • 2016
  • The effects of $Eu^{3+}$ doping on the structural, morphological, and optical properties of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors prepared by solid-state reaction technique were investigated. XRD patterns exhibited that all the synthesized phosphors showed a monoclinic system with a dominant (220) diffraction peak, irrespective of the content of $Eu^{3+}$ ions. The surface morphology of $MgMoO_4:Dy^{3+},Eu^{3+}$ phosphors was studied using scanning electron microscopy and the grains showed a tendency to agglomerate as the content of $Eu^{3+}$ ions increased. The excitation spectra of the phosphor powders were composed of a strong charge transfer band centered at 294 nm in the range of 230~340 nm and two intense peaks at 354 and 389 nm, respectively, arising from the $^6H_{15/2}{\rightarrow}^6P_{7/2}$ and $^6H_{15/2}{\rightarrow}^4M_{21/2}$ transitions of $Dy^{3+}$ ions. The emission spectra of the $Mg_{0.85}MoO_4$:10 mol% $Dy^{3+}$ phosphors without incorporating $Eu^{3+}$ ions revealed a strong yellow band centered at 573 nm resulting from the $^4F_{9/2}{\rightarrow}^6H_{13/2}$ transition of $Dy^{3+}$. As the content of $Eu^{3+}$ was increased, the intensity of the yellow emission was gradually decreased, while that of red emission band located at 614 nm began to appear, approached a maximum value at 10 mol%, and then decreased at 15 mol% of $Eu^{3+}$. These results indicated that white light emission could be achieved by controlling the contents of the $Dy^{3+}$ and $Eu^{3+}$ ions incorporated into the $MgMoO_4$ host crystal.