• Journal of the Mineralogical Society of Korea
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• v.16 no.1
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• pp.33-47
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• 2003

Various applied-mineralogical characterization including measurements of surface area, size distribution, swelling index, and viscosity were done for some domestic bentonites in order to decipher the rheological properties and their controlling factors. The bentonites, which are Ca-type and relatively low-grade (rnontmorillonite contents: 30 ∼ 75 wt%), occur mostly as subhedral lamellas with the size range of 2 ∼ 4 $\mu\textrm{m}$. The size distribution of mineral fractions in bentonite suspension is dominant in the range of 10 ∼ 100 $\mu\textrm{m}$, and though rather complicated, exhibits roughly bimodal patterns. The feature is more conspicuous in the case of zeolitic bentonite. The bentonites have surface areas ranging 269 ∼ 735 $\m^2$/g, which are measured by EGME adsorption method. The EGME surface areas are nearly proportional to the rnontmorillonite contents, moisture contents, or total CEC. In the surface area measurements, zeolitic bentonites have slightly higher values than those zeolite- free types. The measured swelling index and viscosity of domestic bentonites are comparatively low in values. The swelling values of bentonites were measured to be 250∼500% at maximum by progressively mixing amounts of 2 ∼ 5 wt% Na$_2$CO$_3$, which varies depending on the contents of rnontmorillonite and other impurities, especially zeolite. Much amount of sodium carbonate is required for optimum swelling property of zeolitic bentonited which has usually strong Na- exchanged capacity. The bentonites, which are comparatively feldspar-rich and low in size and crystallinity, tend to be higher in viscosity values. Tn addition, the viscosity is largely higher in case of the bentonites with higher pH in suspension. However, the rheological properties of bentonites such as swelling index and viscosity do not show any obvious relationships with rnontmorillonite contents and mean particle size in suspension. In contrast, roughly speaking, the swelling index of bentonites is reversely proportional to the values of surface area which can be regarded as a collective physico-chemical parameter encompassing all the effects caused by mineral composition, surface charge, particle size, morphological farm, and etc. in bentonites. Thus, the rheological properties in bentonite suspension appear to be rather complicated characteristics which mainly depend on the flocculation of clay particles and the mode of particle association, i.e. quasicrystals, controlled by surface charge, morphology, size, and texture of rnon-tmorillonite, and which partly affected by the finer impurities such as zeolite.

• Journal of Soil and Groundwater Environment
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• v.7 no.1
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• pp.41-51
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• 2002

Recently, domestic waste landfills are constructed sometimes on seashore area to provide large landfill area. In order to strengthen the foundation of landfills and to prevent the infiltration of leachate through the bottom, many cases of constructing cement hardened liners on seashore clays are found. In these cases, it is possible to have cracks in the hardened liners due to settlement with waste load since the stiffness of the hardened liner Is greater than that of clay liners. In this study, the capability of Self-Sealing and Self-Healing (SSSH) liner made with a seashore clay in the metropolitan landfill to prevent the percolation of water and leachate is examined using flexible-wall permeameter test and using uniaxial compression test. Applicability of SSSH to weathered granitic soil is also examined for self-sealing capabilities. The result of Flexible permeameter test for SSSH with the seashore clay showed that permeability obtained was lower than permeability criteria of Korean waste management law. The permeability and strength characteristics of SSSH with granitic soil and bentonite showed better results than with the seashore clay.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.40-41
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• 2019

Fine dust, which is emerging as a global problem, attracted much attention recently in Korea. One of the reasons is that recent factory relocation and expansion in China affected the increase of domestic fine dust concentration due to the influence of the Yangtze river battalion and westerlies. Fine dust is a big problem not only in outdoor but also indoors. The room requires periodic ventilation and is also essential for improving indoor air quality. The fine dusts are designated as Group 1 carcinogens in WHO and the risk of fine dusts on the human body due to respiratory diseases is also increasing. In this study, the characteristics of the fine dust adsorption matrix are examined and the actual application direction is derived.

• Journal of Korea Foundry Society
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• v.4 no.1
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• pp.5-11
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• 1984

Green compressive strength, permeability, deformation, flowability, compactability and green hardness values at room temperature are dependable on the grain distribution and grain shape. The results obtained under constant moisture (4% for sand) and bentonite (8% for sand) were as follows; 1. With decreasing grain size, surface area of sand grain was increased. 2. With decreasing grain size, coefficient of angularity was increased. 3. As surface area increased from $8926.43cm^2$ to $21211.16cm^2$ , green compressive strength was increased from $210.93\;g/cm^2$ to $449.98\;g/cm^2$, hardness was increased from 76.7 to 82.3, but permeability was decreased from $411.7\;{\frac{\;cc\;{\cdot}\;cm\;}{atm\;{\cdot}\;cm^2\;{\cdot}\;min.}}$ to $113.7\;{\frac{\;cc\;{\cdot}\;mm\;}{atm\;{\cdot}\;cm^2\;{\cdot}\;min.}}$ 4. As surface area increased from $8926.43\;cm^2$ to $21211.16\;cm^2$, flowability was decreased from 82.3% to 80.8%, deformation was decreased from $67.1\;cm\;{\times}\;10^{-3}$ to $54.6\;cm\;{\times}\;10^{-3}$, but compactability was increased from 44.8% to 54.3%. 5. Room temperature properties of molding sand were affected by variation of surface area.

• Nuclear Engineering and Technology
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• v.32 no.3
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• pp.274-282
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• 2000

The simulation of water balance was conducted for suggested four alternative multi-layer cover design of near-surface radioactive waste disposal facility under domestic climate condition. The analysis was also conducted for the most favorable one out of four alternative cover design under conservative scenarios. Until 100 years after closure of disposal vault, the infiltration flux for the most favorable cover design was negligible even under doubling of the ambient precipitation condition. When the degradation of asphalt and geomembrane after 100 years of closure was considered, the infiltration flux significantly increased almost to the design criteria of cover system in I' Aube disposal facility. And it was found that the hydraulic conductivity of bentonite/sand as a bottom barrier should be no greater than 1$\times$10$^{-7}$ cm/sec recommended by U.S. EPA.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2001.11a
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• pp.163-168
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• 2001

This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-souble rubber asphalt are the follows; 1) The amount of water absorption was '0.06'g and the seepage quantity was '0'g in result. 2) The tensile strength was about 30.7kgf/$cm^2$ and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kg/$cm^2$ in low temperature and about 30.7kgf/$cm^2$ in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$cm^2$ and about 21.9kgf/$cm^2$ in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$cm^2$ and the elongation was 250% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the security and durability of waste filled land.

• Journal of the Korea Organic Resources Recycling Association
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• v.18 no.4
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• pp.38-44
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• 2010

Foundry sands are made up of silica and some coking agents, such as bentonite or resin, and used as templates for the production of various casting products. Foundry sands, which are repeatedly used, were finally transformed into the waste materials by heat, losing their proper functions. The used foundry sands have been treated as general wastes according to the contents of coking agents used. Silica, however, can be recycled through the proper treatment due to its physical property not to changed by heat. In this study, we have identified and investigated at the occurrence, treatment and recycling status of the used foundry sands, as well as for the regime and inhibitory factors of the recycling of them in domestic and foreign cases.

• Journal of the Korean GEO-environmental Society
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• v.12 no.1
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• pp.71-80
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• 2011

In period of rapid economic development, as doing river conservation work by using harmful materials environmental pollution has adversely effected humans, animals and plants frequently. For recovery of environmental pollution it needs a lot of time and cost. Therefore, in this study, in order to take an environment-friendly method which is also economical and durable both results of the laboratory model test and field test were compared and analyzed. According to the results of the laboratory model test, those methods such as concrete paving, asphalt paving, bentonite mat, stabilized soil method and mixed soil method have small amount of seepage, but on the other hand compaction soil, grassland and permeable materials have considerable amount of seepage. The results of field test show a similar tendency with laboratory test and have been satisfied to assess standard of domestic water permeability below $1.0{\times}10^{-7}cm/sec$ and unconfined compressive strength is also than 1.0MPa so it has been satisfied about standard. In conclusion, as compaction rate increased, as unconfined compression strength increased and coefficient of permeability decreased.

• Journal of the Mineralogical Society of Korea
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• v.15 no.4
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• pp.329-344
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• 2002

Mineralogical and chemical characterization of some domestic bentonites, such as quantitative XRD analysis, chemical leaching experiments, pH and CEC determinations, were done without any separation procedures to understand their relationships among mineral composition, characteristics, and cation exchange properties. XRD quantification results based on Rietveld method reveal that the bentonites contain totally more than 25 wt% of impurities, such as zeolites, opal-CT, and feldspars, in addition to montmorillonite ranging 30～75 wt%. Cation exchange properties of the zeolitic bentonites are deeply affected by the content of zeolites identified as clinoptilolite-heulandite series. Clinoptilolite is common in the silicic bentonites with lighter color. and occurs closely in association with opal-CT. Ca is mostly the dominant exchangeable cation, but some zeolitic bentonites have K as a major exchangeable cation, The values of cation exchange capacity (CEC) determined by Methylene Blue method are comparatively low and have roughly a linear relationship with the montmorillonite content of the bentonite, though the correlated data tend to be rather dispersed. Compared to this, the CEC determined by Ammonium Acetate method, i.e.‘Total CEC’, has much higher values (50～115 meq/100 g). The differences between those CEC values are much greater in zeolitic bentonites, which obviously indicates the CEC increase affected by zeolite. Other impurities such as opal-CT and feldspars seem to affect insignificantly on the CEC of bentonites. When dispersed in distilled water, the pH of bentonites roughly tends to increase up to 9.3 with increasing the alkali abundance, especially Na, in exchangeable cation composition. However, some bentonites exhibit lower pH (5～6) so as to regard as ‘acid clay’. This may be due to the presence of $H^{＋}$ in part as an exchangeable cation in the layer site of montmorillonite. All the works of this study ultimately suggest that an assesment of domestic bentonites in grade and quality should be accomplished through the quantitative XRD analysis and the ‘Total CEC’measurement.

• Journal of the Korea Institute of Building Construction
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• v.1 no.2
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• pp.165-173
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• 2001

This study examinated the application in construction field and the development of waterproofing material system by the spray water-soluble rubber asphalt to solve the problems of synthetic polymer sheet and gio membrane(A mat sheet of Bentonite) that had been used domestic waterproofing material in advance. As the result of study, characters of study water-soluble rudder asphalt are the follows: 1) The amount of water absorption was '0.06'g and the seepage quality was '0'g in result. 2) The tensile strength was about 30.7kgf/$\textrm{cm}^2 and the elongation was about 72.4% in result. 3) After reliance of temperature test had been ended, the tensile strength was about 72.4kgf/$\textrm{cm}^2 in low temperature and about 30.7kgf/$\textrm{cm}^2 in normal temperature. 4) After acid and alkaline treatment had been ended, the tensile strength was about 19.7kgf/$\textrm{cm}^2$ and about 21.9kgf/$\textrm{cm}^2 in result. 5) After chlorine ion treatment had been ended, the tensile strength was 28.5kgf/$\textrm{cm}^2$ and the elongation was 250% in result. 6) The impact performance was subsided at 1.5m height. 7) After promotion weathering had been ended, the tensile and elongation was about 26.0kgf/$\textrm{cm}^2, 214% in result. So, this study can propose the spray water-soluble rubber asphalt to satisfy the and durability of waste filled land.