• Korean Journal of Weed Science
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• v.14 no.1
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• pp.23-27
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• 1994

Nutrient culture study was initiated to examine the selectivity of dithiopyr(S, S-dimethyl 2-difluoromethyl)-4-(2-methylpropyl)-6-(trifluoro methyl)-3, 5-pyridine dicarbothiate) in rice(Oryza sativa L.) and barnyardgrass(Echinochloa crusgalli Beauv.). Absorption and translocation of $^{14}C$-dithiopyr in rice and barnyardgrass were also investigated to determine their selective mechanism. Rice was very tolerant, but barnyardgrass was susceptible to dithiopyr. The absorption of dithiopyr was greater in barnyardgrass than in rice and most of them remained in the roots of both species. Dithiopyr was absorbed by roots and basal shoots of both species. Translocation of dithiopyr was very low but was higher in barnyardgrass than in rice. Therefore, this study suggest that the selectivity of dithiopyr between rice and barnyardgrass may be mainly attributed to the absorption and translocation of dithiopyr in plants.

• Korean Journal of Weed Science
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• v.14 no.2
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• pp.101-106
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• 1994

Factors affecting phytotoxicity of dithiopyr in rice such as transplanting depth, seedling age, soil texure were examined and mechanism of phytotoxicity in rice was also determined by absorption study of $^{14}C$-dithiopyr in rice seedlings under above conditions. Rice injury was occurred in shallow transplanting depth, young rice seedlings and sandy soil conditions. Higher amount of dithiopyr was absorbed in rice at shallow transplanting depth and sandy soil conditions which may related to phytotoxicity of dithiopyr.

• Korean Journal of Weed Science
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• v.9 no.3
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• pp.238-244
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• 1989

The experiment was carried out to evaluate the herbicidal properties of dithiopyr(3, 5-pyridine dicarbothioic acid-2-(difluoromethyl)-4-(2-methylpropyl)-6-(trifluoromethyl)-S,S-dimethyl ester). Weeding effect of dithiopyr was determined under various factors such as dosage, soil type, leaching amount, temperature, water depth, overflow time, and application time and method. Dithiopyr showed very high phytotoxic activity on most major annuals weeds, expecially Echinochloa crus-galli and Monochoria vaginalis. Excellent control of Echinochloa crus-galli was obtained at 0.04kg a.i./ha with preemergence application and 0.12kg a.i./ha with early post-emergence application (12 DAT ; Echinochloa crus-galli of 1.5 leaf stage). Weeding effect of dithiopyr decreased when applied at the soil surface 2days before transplanting. Soil type, leaching amount, temperature, water depth, overflow time did not affect the weeding effect.

• Korean Journal of Weed Science
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• v.11 no.3
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• pp.174-177
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• 1991

This study was conducted to determine the influence of dithiopyr on growth of transplanted rice with different transplanting depths and the amount of $^{14}C$-dithiopyr adsorpted in the root and shoot of rice plants under paddy soil conditions. The growth rate of transplanted rice was lower in 0 and 0.25cm of transplanting depths with exposed basal stem than in 1 and 2cm of the depths in control plot. In the growth of transplanted rice treated with dithiopyr, plant hight and dry weight were significantly inhibited in 0 and 0.25cm depth plots but not affected.in 0.5, 1, 2 and 4cm depth plots, and roop length were influenced in 0, 0.25 and 4cm depth plots but not in 0.5, 1 and 2cm depth plots. The amount of ratioactivity in shoot and root of rice plants as affected by $^{14}C$-dithiopyr were the highest in 0 and 0.25cm depth plots and decreased in over 0.5cm depth plots. However the extent in amount of distributed radioactivity in the plants among the different transplanting depths was narrow gradually with the growth of plants. Therefore, injury of transplanted rice by dithiopyr is little in over 0.5cm transplanting depth with burried basal stem and the inhibition on rice plants with extreme shallow transplanting such as 0 and 0.25cm depths should be due to more adsorption of dithiopyr.

• Korean Journal of Weed Science
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• v.10 no.4
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• pp.248-254
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• 1990

Initial crop injury, plant growth and yield of machine-transplanted rice of seedlings different in plant age (8-, 20-, and 35-day-old seedlings) after application of herbicides were investigated in field. The herbicides employed were butachlor, dithiopyr, pyrazolate(applied only for 8-day-old seedling), dithiopyr+pyrazolate, dithiopyr+ bensulfuron methyl), and butachlor+bensulfuron methyl(applied only for 20-and 35-day-old seedlings). There was no significant difference in plant growth, yield components and yield between the different-aged seedlings of the untreated check, except for the heading date, The heading date of 8-day-old seedling was delayed for 2 and 6 days as compared with those of 20-and 35-day-old seedlings, respectively. A very slight initial crop injury was found with the tested herbicides for all the different-aged seedlings. No significant differences in plant height and tiller number occurred between different-aged seedlings and the respective untreated check. All the herbicides used gave a good weeding effect. Yield components and yields were not affected by different-aged seedlings after application of the herbicides.

• Journal of Life Science
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• v.26 no.2
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• pp.181-189
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• 2016

The aim of this study was to identify the effects of dithiopyr (DTP), a herbicide, on behavior in zebrafish. The toxicity of DTP has rarely been investigated in fish. In the present study, zebrafish were exposed to different concentrations of DTP in the range of 10-20 μM for 48 h in a test container, in order to measure the value of median lethal concentrations (LC₅₀). Behavioral experiments were performed, including the novel tank test (NTT) and the open field test (OFT), to assess stress responses or locomotion. After exposure to the DTP solution at a sublethal concentration of 2.5–10 μM for 6 min, the behavior of the zebrafish was observed for 6 min. In the acute toxicity test, the LC₅₀ value of DTP showed as 14.49 μM in the zebrafish. The NTT showed that the duration of immobility and the velocity were significantly increased by exposure at a concentration of 5 μM of DTP, compared with a control group (p<0.05). However, compared with the control group, DTP significantly decreased the distance moved and the frequency at the top of the tank, and significantly increased the turn angle and duration at the bottom, in a concentration-dependent manner (p<0.05). In addition, in the OFT, exposure to DTP significantly decreased the distance moved and velocity compared with the control group (p<0.05). Exposure to DTP also significantly increased the duration of immobility, the turn angle, and the meandering movement, in a concentration-dependent manner (p<0.05). Further, exposure to DTP at a low concentration elevated whole-body cortisol levels in the zebrafish. The results of this study thus suggest that DTP induces a toxic response and negative effects on behavior and the endocrine system in zebrafish.

• Asian Journal of Turfgrass Science
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• v.14 no.1
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• pp.251-256
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• 2000

The purpose of this study is to select the appropriate herbicide, which is needed to control the bentgrass in kentucky bluegrass(Poa pratensis) fairway effectively. The best control of bentgrass was observed at /$0.3mL\m^2$ of dithiopyr applied on Kentucky bluegrass. A field experiment was conducted to determine the priming effects on seed germination of Kentucky bluegrass. Ground covering rates by turfgrass were investigated under field conditions for 70 treatments by thirty days after treatment. The solid matrix priming(SMP) treatments on Kentucky bluegrass reduced the number of days requited for emergence and improved final cover ratings. Primed seeds of Kentucky bluegrass (incubated for five days at $20^{\circ}C$) resulted in most rapid germination and covering rate.

• Journal of the Korean Institute of Landscape Architecture
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• v.22 no.1
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• pp.101-110
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• 1994

A field study was carried out to investigate the visual injury of zoysiagrass and creeping bentgrass by the application of various herbicides the result were as follows. 1. Trifluralin + benefin and dithiopyr did not injure creeping bentgrass and zoysiagrass. 2. Creeping bentgrass was safe while zoysiagrass was slightly injured within acceptable level with benefin. 3. Oryzalin caused injury both on creeping bentgrass and zoysiagrass. However, the injury of zoysigrass was within acceptable level while the injury of creeping bentgrass increased without acceptable level when applied at>5kg/ha. 4. Creeping bentgrass was tolerant to pendimethalin only when treated at<3.4kg/ha whereas zoysiagrass was tolerant regardless of rate. 5. Creeping bentgrass treated with fenoxaprop, oxadiazon, and bensulide were severely injured. However, turfgrasses treated with bensulide recovered rapidly when compared with fenoxaprop and oxadiazon. 6. Zoysiagrass treated with 2,4-D, dicambe, bentazon was safe when applied at mid summer.

• The Korean Journal of Pesticide Science
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• v.16 no.1
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• pp.43-53
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• 2012

In order to monitor the levels of pesticides in environment-friendly stalk and stem vegetables and leafy vegetables selling at markets in Korea. A total of 637 (395 organic agricultural products, 242 pesticide-free agricultural products) samples of 21 stalk and stem vegetables and leafy vegetables were collected twice from markets in July and August 2010 in Korea. Pesticide residues in samples were analyzed by multiresidue method for 240 pesticides using GC-ECD/NPD and HPLC-DAD/FLD. The suspected-pesticides were confirmed with a GC-MSD. As a result of analysis, six pesticides were detected from eight samples, representing a detection rate of 1.3% and amounts of pesticide residues in samples were as follows: alachlor 0.043, chlorfenapyr 0.022-0.324, diazinon 0.024, dicofol 0.009-0.138, dithiopyr 0.008, metolachlor 0.025 mg/kg. Their residue levels were below the MRLs. Estimated daily intakes (EDIs) of the pesticides detected from stalk and stem vegetables and leafy vegetables were less than 25% of their acceptable daily intakes (ADIs), representing that residue levels of the pesticides detected were evaluated as safe for consumption. However, five samples containing pesticide residues were unsuitable environment-friendly products because of pesticides detected more than their 10% MRLs in organic and pesticide-free agricultural products.

• Weed & Turfgrass Science
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• v.2 no.2
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• pp.122-130
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• 2013

The object of this study is to review the current states of the characteristics and strategies to control annual bluegrass to apply information to the circumstance of South Korea. Annual bluegrass is one of the most widespread turfgrass species which has great ability to produce seedhead and shoot growth. It also has ability to tolerate low mowing height and to form uniformity of turfgrass when it is established. Annual bluegrass is well-known as weak turfgrass for high and low temperature. High rate of nitrogen and phosphorus improves growth of annual bluegrass. To control annual bluegrass, deep and infrequent irrigation is more effective than light and frequent irrigation. Clipping removal is more effective than clipping return to control annual bluegrass. Prodiamine, bensulide, and dithiopyr are applied as pre-emergence herbicide, and ethofumesate and bisbyribac-sodium are used as post-emergence herbicide. Paclobutrazol and flurprimidol are used as plant growth regulator. Trinexapac which is one of the most popular plant growth regulators (PGRs) in South Korea is not proper to control annual bluegrass because it accelerates improve growth of annual bluegrass in summer. Although chemical control is mainly used in South Korea, combination of cultural and chemical control may be the strategy to maximize effectiveness to control annual bluegrass.