• Title/Summary/Keyword: Dispersion evaluation

Search Result 360, Processing Time 0.024 seconds

Evaluation of mechanical properties and non-flammability of Nylon6 using melamine-based halogen-free flame retardant (Melamine계 난연제를 이용한 Nylon6의 난연성 및 물리적 특성 평가)

  • Kim Dong-Hak;Ryu Kwan-Suk;Son Young-Gon
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.7 no.4
    • /
    • pp.743-748
    • /
    • 2006
  • We investigated the flame retardancy and the mechanical properties of Nylon6 by using melamine-based halogen-free flame retardants(melamine cyanurate:MC-100 and melamine phosphate:MP-100). We chose the UL-94 method for flame retardancy and measured the tensile strength, flexural strength, flexural modulus by using UTM and impact strength by using Izod impact tester. We also tested the effect of nano-clay on flammability and mechanical properties. We obtained the V0 grade when the concentration of flame retardant was over 5 wt%. The tensile strength and flexural strength decreased and flexural modulus increased with the concentration of both flame retardant systems. The results showed that MC-100 system was better than MPP-100 system. Because of poor dispersion, we did not obtain the synergistic effect of nano-clay.

  • PDF

A Numerical Analysis of Hydrogen Diffusion for Hydrogen Leakage from a Fuel Cell Vehicle in a Long Road Tunnel (장대터널에서 수소연료전지 차량의 수소 누출에 대한 수소 거동의 수치해석 연구)

  • Choi, Jongrak;Hur, Nahmkeon;Lee, Moonkyu;Chang, Hyungjin;Lee, Kwangbum;Yong, Geejoong
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.23 no.6
    • /
    • pp.588-597
    • /
    • 2012
  • In the present study, the dispersion characteristics of hydrogen leakage from a Fuel Cell Vehicle (FCV) were analyzed by numerical simulation in order to assess the risk of a hydrogen leakage incident in a long road tunnel. In order to implement the worst case of hydrogen leakage, the FCV was located at the center of a tunnel, and hydrogen was completely discharged within 63 seconds. The Leakage velocity of hydrogen was adopted sub-sonic speed because that the assumption of the blockage effect of secondary device inside a vehicle. The temporal and spatial evaluation of the hydrogen concentration as well as the flammable region in a road tunnel was reported according to change of ventilation operating conditions. The hydrogen was blended by supply air form a ventilation fan, however, the hydrogen was discharged to outside in the exhaust air. It is observed that the efficiency way to eliminate of hydrogen is supply air operating condition under the hazardous hydrogen leaking incident. The present numerical analysis can be provided useful information of ventilation under the hydrogen leaking situation.

Histomorphometric evaluation of the implant designed by shape optimization technique (성견 경골에서 최적화 기법을 이용하여 형상 개선된 임프란트의 조직계측학적 분석)

  • Kwon, Hyuk-Rak;Moon, Sang-Kwon;Shim, Joon-sung;Ahn, Sei-young;Lee, Hun;Kim, Han-Sung;Choi, Seong-ho;Kim, Chong-Kwan
    • Journal of Periodontal and Implant Science
    • /
    • v.34 no.1
    • /
    • pp.35-48
    • /
    • 2004
  • Since the occlusal loading is transmitted to the surrounding bone, the success of an implant treatment is closely related to the distribution of the stress on the implant. The finite element analysis method is often used in order to produce a model for dispersion of stress. Assessment of the success of the implant is usually based on the degree of osseointegration which is a bone and implant surface interface. Implant used in this research was designed through the method of shape optimization after the stress on implant was anaylzed by the finite element analysis method. This study was pertinently assessed by a clinical, histologic, histomorphometric analysis after the shape optimized implant was installed on beagle dog tibia. The results are as follows 1. It clinically showed a good result without mobility and imflammatory reaction. 2. Implant was supported by dense bone and bone remodeling showed on the surrounding area of the implant 3. The average percentage of bone-implant contact was 58.1%.The percentage of bone density was 57.6%. Having above results, shape optimized implant showed the pertinence through clinical and histologic aspects. However, to use the shape optimized implant, the further experiment is required for finding problems, improvement.

The Evaluation of the Preparation and Characterization of Inks based on Surface-modified Specialty Carbon Black(SCB) (표면개질 스페셜티 카본블랙의 제조 및 잉크 특성 평가)

  • Park, Dong Jun;Kim, Song Hui;Park, Soo Youl
    • Textile Coloration and Finishing
    • /
    • v.30 no.3
    • /
    • pp.168-179
    • /
    • 2018
  • The modified surface of specialty carbon black(SCB) is one of the main technical factors for producing a uniform color and stable dispersion. In this work, the carboxylation or sulfonation process of SCB was used to improve the dispersive properties of hydrophilic solvents such as 1,6-hexanediol and propylene glycol monomethyl ether acetate(PGMEA). The results showed that the color strength of SCB DC2500G changed little with a range of 0.128~0.941(${\Delta}E$) compared to other SCB DC2500G material. In contrast, in the case of SCB EG410, there was a uniform color value with a range of 0.144~0.252(${\Delta}E$). Also, in our experiments, a modified SCB was confirmed by printing ink material as a melt coating paper. It may be possible that the SCB EG410 material can be advantageous as a gravure ink product. Finally, the modified SCB obtained from this research will have a large impact on the industry as a potential material for toners, paint, rubber, fillers, and other carbon black additives.

A Study of the Guided Wave Propagation in the Water Supplying Pipes with Scale (스케일이 있는 급수관내의 유도초음파의 전파 특성에 관한 연구)

  • Song, Sung-Jin;Lee, Dong-Hoon;Lee, Hyun-Dong;Bae, Cheol-Ho;Park, Jung-Hoon;Kim, Young-H.
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.23 no.1
    • /
    • pp.1-6
    • /
    • 2003
  • Since the scale in pipes reduces the flow rate, a quantitative evaluation of the scale is essential for the proper maintenance of pipes. Guided waves were employed to estimate the amount of scale in water supplying pipes. Using variable angle wedge, several modes of guided waves wire generated and their propagation charcteristics along the pipes with stale were analyzed. It was experimentally observed that the amplitude of F(M,2) modes at $f{\times}d=1.5MHz\;mm$ decreased significantly with increasing amount of scale. The present study showed that F(M,2) modes were optima) to evaluate the scale in water supplying pipes.

A Study on Thermal Characteristics of Carbon-Organic Surface Heating Element with Electrodeless Lamp of a Freezer (냉동고 무전극램프 적용 탄소-유기소재 면상발열체의 열 특성에 관한 연구)

  • Lee, Min-Sang;Back, Seong-Hun;Kang, Sung-Soo
    • Journal of the Korean Society of Manufacturing Process Engineers
    • /
    • v.19 no.1
    • /
    • pp.1-10
    • /
    • 2020
  • This study deals with the fabrication and thermal characterization of planar heating elements attached to the backside of the reflector used in the electrodeless lamp of a freezer. We tried to solve the problem of the local heat generation of the linear heating element that occurs about 50℃. The homogeneous dispersion and manufacturing excellence of the planar heating element produced were confirmed through SEM and EDS. In addition, the test specimens was prepared according to the change in the ratio of carbon fiber to the basis weight of the planar heating element, and a sample having a basis weight of 50g/㎡ having a content ratio of carbon fiber of 70% was selected. That sample showed low surface resistance of 4.3Ω/sq and high temperature of about 81℃ at 6V. Durability was confirmed by performing repeated bending evaluation of 3000 cycles for the sample. Large area test specimens were prepared to be applied to the actual reflector, insulated by EVA film and analyzed for their thermal characteristics. From 13V application, the temperature of the linear heating element was higher than 50℃ and the average temperature of 68℃ was maximum at 18V.

Evaluation of Methyl Methacrylate-Butyl Methacrylate Copolymer Films and Kinetics of Nitrofurazone Release (메칠메타크릴레이트-부틸메타크릴레이트 공중합체 필름의 평가 및 니트로푸라존 방출의 속도론적 연구)

  • Chun, In-Koo
    • Journal of Pharmaceutical Investigation
    • /
    • v.17 no.3
    • /
    • pp.111-126
    • /
    • 1987
  • Methyl methacrylate-butyl methacrylate copolymer (MMBM)-dibutyl phthalate (DBP) films were investigated as a potential topical drug delivery system for the controlled release of nitrofurazone. The kinetic analysis of release data indicated that drug release followed a diffusion-controlled granular matrix model, where the quantity released per unit area is proportional to the square root of time. DBP of several hydrophobic plasticizers selected was found to give the highest release of nitrofurazone. However, hydrophilic plasticizers such as propylene glycol and polyethylene glycol 400 had no controlled release properties and acceptable film formation. The effects of changes in film composition, drug concentration, film thickness, pH of release medium, and temperature on the in vitro release of nitrofurazone were analyzed both theoretically and experimentally. The release rate constant (k') was found to be proportional to DBP content, pH, and the temperature of release medium, but independent of film thickness, and drug concentration in a range of 0.1-0.4% by weight. The linear relationship was found to exist between the log k' and DBP content. The release of nitrofurazone from MMBM-DBP (8:2) films was found to be an energy-linked process. Two energy terms were calculated ; the activation energy for matrix diffusion was 13.45 kcal/mole, and the heat of drug crystal solvation was 27.26-29.34 kcal/mole. Observation of scanning electron micrographs and microscopic photographs showed that the incorporation of DBP in films increased markedly the particle size of nitrofurazone dispersed in the film matrix, comparing with the fine dispersion of nitrofurazone in pure MMBM film alone.

  • PDF

Distribution on the Alien Plants in the Gyeong-in Ara Waterway, Korea (경인 아라뱃길의 외래식물 분포 현황)

  • An, Ji-Hong;Kim, Jung-Hyun;Park, Hwan-Joon;Kim, Sun-Yu;Park, Sung-Ae
    • Journal of Korean Society on Water Environment
    • /
    • v.33 no.3
    • /
    • pp.291-301
    • /
    • 2017
  • This study was carried out to investigate distribution on the alien plants in the Gyeong-in Ara Waterway. The alien plants were a total of 82 taxa: 17 families, 63 genera, 80 species, and 2 varieties. This number corresponds to 25.5% of alien plants identified in Korea. The proportion of alien plants in every year was increased from upstream to downstream. As the result of the analysis on vegetation stratification, bank of waterside was covered with artificial materials preventing existence of vegetation, and had step-type cross section. Floodplain was composed of waterfront area. An array of vegetation was not typical dispersion, and terrestrial and alien plants were dominated the Gyeong-in Ara Waterway. Evaluation of naturalness based on the vegetation stratification showed grade 3 or 4. In order to solve a problem, method and level of restoration should be decided based on the result of diagnostic assessment. Therefore, we need to restore the step-type cross section as pool type one. From waterside to bank in this waterway, we recommend to introduce natural plants by imitating reference species composition. Since, an invasion of alien plants is expected to be accelerated due to the continuous artificial disturbance, we recommend to quantitative investigation on the invasion of alien plants and monitoring on the change of distribution.

Fabrication of Metallic Particle Dispersed Ceramic Based Nanocomposite Powders by the Spray Pyrolysis Process Using Ultrasonic Atomizer and Reduction Process

  • Choa, Y.H.;Kim, B.H.;Jeong, Y.K.;Chae, K.W.;T.Nakayama;T. Kusunose;T.Sekino;K. Niibara
    • Journal of Powder Materials
    • /
    • v.8 no.3
    • /
    • pp.151-156
    • /
    • 2001
  • MgO based nanocomposite powder including ferromagnetic iron particle dispersions, which can be available for the magnetic and catalytic applications, was fabricated by the spray pyrolysis process using ultra-sonic atomizer and reduction processes. Liquid source was prepared from iron (Fe)-nitrate, as a source of Fe nano-dispersion, and magnesium (Mg)-nitrate, as a source of MgO materials, with pure water solvent. After the chamber were heated to given temperatures (500~$^800{\circ}C$), the mist of liquid droplets generated by ultrasonic atomizer carried into the chamber by a carrier gas of air, and the ist was decomposed into Fe-oxide and MgO nano-powder. The obtained powders were reduced by hydrogen atmosphere at 600~$^800{\circ}C$. The reduction behavior was investigated by thermal gravity and hygrometry. After reduction, the aggregated sub-micron Fe/MgO powders were obtained, and each aggregated powder composed of nano-sized Fe/MgO materials. By the difference of the chamber temperature, the particle size of Fe and MgO was changed in a few 10 nm levels. Also, the nano-porous Fe-MgO sub-micron powders were obtained. Through this preparation process and the evaluation of phase and microstructure, it was concluded that the Fe/MgO nanocomposite powders with high surface area and the higher coercive force were successfully fabricated.

  • PDF

Preparation of WO3-TiO2 Photocatalyst and Evaluation of Its Photo-activity in the Visible Light Range (가시광 활성 WO3-TiO2 복합체 광촉매의 제조 및 이의 특성 평가)

  • Yeo, In-Chul;Kang, In-Cheol
    • Journal of Powder Materials
    • /
    • v.20 no.6
    • /
    • pp.474-478
    • /
    • 2013
  • The most general photocatalyst, $TiO_2$ and $WO_3$, are acknowledged to be ineffective in range of visible light. Therefore, many efforts have been directed at improving their activity such as: band-gap narrowing with non-metal element doping and making composites with high specific surface area to effectively separate electrons and holes. In this paper, the method was introduced to prepare a photo-active catalyst to visible irradiation by making a mixture with $TiO_2$ and $WO_3$. In the $TiO_2-WO_3$ composite, $WO_3$ absorbs visible light creating excited electrons and holes while some of the excited electrons move to $TiO_2$ and the holes remain in $WO_3$. This charge separation reduces electron-hole recombination resulting in an enhancement of photocatalytic activity. Added Ag plays the role of electron acceptor, retarding the recombination rate of excited electrons and holes. In making a mixture of $TiO_2-WO_3$ composite, the mixing route affects the photocatalytic activity. The planetary ball-mill method is more effective than magnetic stirring route, owing to a more effective dispersion of aggregated powders. The volume ratio of $TiO_2(4)$ and $WO_3(6)$ shows the most effective photocatalytic activity in the range of visible light in the view point of effective separation of electrons and holes.