• Title/Summary/Keyword: Dispersion behavior

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Behavior and Geochemical Characteristics of Au and Heavy Metals in the Water System at the Abandoned Bonjeong Gold Mine (본정 함금 폐광산 주변수계 내 Au와 중금속의 거동 및 지화학적 특성)

  • Cho, Kang-Hee;Kim, Bong-Ju;Oh, Su-Ji;Choi, Nag-Choul;Park, Cheon-Young
    • The Journal of Engineering Geology
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    • v.23 no.4
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    • pp.363-373
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    • 2013
  • This study investigates the dispersion and behavior of Au and heavy metals in the water system (soil, AMD and stream sediment) at the abandoned Bonjeong gold mine, based on XRD, aqua regia, sequential extraction, and physico-chemical analyses. The XRD analyses targeted quartz and kaolinite in the mine waste soil and quartz and goethite in stream sediment. The physico-chemical analyses of AMD with increasing distance from water system showed that pH increased from 3.00 to 3.19 and Eh decreased from 450 to 396 mV. The Au content in AMD ranged from 0.68 to 0.97 mg/L upstream, but was not detected downstream. The Au content of stream sediment was 13.76 to 22.85 mg/kg. Sequential extraction from stream sediment revealed 10.84% exchangeable (STEP I), 11.09% carbonates (STEP II), 25.53% Fe-Mn oxides (STEP III), 26.62% organic matter (STEP IV), and 24.61% residual (STEP V).

Preparation of Cordierite sols in Aqueous Media and Sintering Behavior of Cordierite Ceramics (수용액 매체로부터 코디어라이트 졸의 제조 및 코디어라이트 세라믹스의 소결거동)

  • Kim, Jae-Won;Kim, Hyeon-Cheol;Kim, Du-Hyeon;Seo, Seong-Mun;Jo, Chang-Yong;Choe, Seung-Ju;Kim, Jae-Cheol
    • Korean Journal of Materials Research
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    • v.10 no.3
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    • pp.233-240
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    • 2000
  • In order to fabricate dense cordierite ceramics without sintering aid, thermal behavior of Mg-Al-Si compounds during sintering was investigated. The dispersibility of cordierite suspension in aqueous media was measured by ESA(electrokinetic sonic amplitude). To prevent aggregation and insufficient dispersion of the cordierite sol, the pH of the suspension was controlled to 1.03 and 8.30 by adding $2N\;HNO_3$ and $2N\;NH_4OH$, respectively. Magnesium-aluminum-silicate complex gel coexisted in the specimen which has been gelled at $150^{\circ}C$ fir 12 hours, however several metastable phase such as ${\mu}-cordierite(Mg_2Al_4Si_5O_{18}),\;spine(MgAl_2O_4)\;and\;mullite(Al_6Si_2O_{13})$ existed below $1300^{\circ}C$ Nucleation rates of the two suspension were similar, but densification of the gel was sensitive to the pH of the sol. Densification of the sol with the pH of 8.3 was more pronounced than that of the sol with pH of 1.63.

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Mechanical Properties of an ECC(Engineered Cementitious Composite) Designed Based on Micromechanical Principle (마이크로역학에 의하여 설계된 ECC (Engineered Cementitious Composite)의 역학적 특성)

  • Kim Yun-Yong;Kim Jeong-Su;Kim Hee-Sin;Ha Gee-Joo;Kim Jin-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.709-716
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    • 2005
  • The objective of this study is to develop a high ductile fiber reinforced mortar, ECC(Engineered Cementitious Composite) with using raw material commercially available in Korea. A single fiber pullout test and a wedge splitting test were employed to measure the bond properties in a matrix and the fracture toughness of mortar matrix respectively, which are used for designing mix proportion suitable for achieving strain-hardening behavior at a composite level. Test results showed that the properties tended to increase with decreasing water-cement ratio. A high ductile fiber reinforced mortar has been developed by employing micromechanics-based design procedure. Micromechanical analysis was initially peformed to properly select water-cement ratio, and then basic mixture proportion range was determined based on workability considerations, including desirable fiber dispersion without segregation. Subsequent direct tensile tests were performed on the composites with W/C's of 47.5% and 60% at 28 days that the fiber reinforced mortar exhibited high ductile uniaxial tension property, represented by a maximum strain capacity of 2.2%, which is around 100 times the strain capacity of normal concrete. Also, compressive tests were performed to examine high ductile fiber reinforced mortar under the compression. The test results showed that the measured value of compressive strength was from 26MPa to 34 MPa which comes under the strength of normal concrete at 28 days.

Analysis on the Safety of Structure and Economics of Replacement Method Using Rock Debris in the Soft Ground - Case Study of Miho Stream Crossing Road in Cheongju City (연약지반 암버럭 치환공법의 구조물 안정성과 경제성 분석 - 청주시 미호천 횡단도로를 대상으로)

  • Heo, Kang Kug;Park, Hyung Keun;Ahn, Byung Chul;Min, Byeong Uk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.36 no.4
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    • pp.705-713
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    • 2016
  • For the soft ground construction, the factors not considered in the design stage occurs in the construction stage so that they cause the increase of the construction cost due to the structural stability and the design change. The subject of the study is the construction section of the industrial complex access road made in the Ochang region of Chungcheongbuk-do. The study is concerned with selecting the soft ground handling method such as the replacement method using rock debris and the surcharge reflecting the service load as the soft ground handling measure and analyzing the effect of reducing the construction cost with the stability of structures and the reduction of the construction period. The soft ground in the study section consists of sandy and cohesive soil and is 2.4m to 5.5m deep. It is distributed unevenly between the 1.5m to 5.9m stratums under the ground surface. Settlement is not serious, but the future uneven settlement and difference are expected so that the future settlement behavior is estimated by analyzing the site measurement results after the soft ground treatment. Moreover, in consideration of the regional characteristics and economic efficiency, soil with good quality is replaced with rock debris as the replacement material so that 29% of the construction cost is reduced due to the increase of stability and the reduction of duration. If the estimation of the dispersion of the pore water pressure within the dam body and the change of the underground water level and the relation of the actually measured soft ground with consolidation is studied further on the basis of the study, it is expected that the behavior of the soft ground will be correctly estimated in various site conditions.

The Homogeneous Regions and Functional Regions in the Internal Structure of Seoul (서울시 등질지역과 기능지역의 구조 분석)

  • Son Seung-ho
    • Journal of the Korean Geographical Society
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    • v.39 no.4
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    • pp.562-584
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    • 2004
  • This paper intends to identify the structure of homogeneous regions and functional regions in Seoul based on B.J.L. Berry's ‘general field theory of spatial behavior’. The structure of homogeneous regions by using socio-economic variables can explain how the structural elements of the city are arranged. It can be ssid that Seoul has shifted towards more complicated and differentiated features in terms of homogeneous regions. The different patterns are found between the northern part to Han River where old torn areas are located and the southern part to Han River where newly urbanized areas are located. Usually, the concentric pattern and the sectoral pattern coexist, which is enhanced moving from CBD to the outskirt area. The distribution of different social classes shows irregular pattern similar to the variation of living environment. The social gap is expected to be more widening between new towns and old towns. The analysis of spatial movement pattern shows no clear hierarchical order because of current shifts towards both multi-nuclear pattern and spatial dispersion. The functional regions show duplicated structure overlapping their boundaries each other. The ‘general field theory of spatial behavior’ strongly suggests that spatial interactions among sub-areas in the city are differentiated from the basic characteristics and function of each sub-area. The attributes of homogeneous regions and functional regions are interrelated in the characteristics of isomorphic nature.

Prediction of Phase Behavior of ε-caprolactam Derivatives and Carbon Dioxide using a Group Contribution Method (그룹 기여 방법을 이용한 ε-caprolactam 유도체와 이산화탄소의 상거동 예측에 관한 연구)

  • Kwon, Soyoung;Bae, Won;Lee, Kyoungwon;Kim, Hwayong
    • Clean Technology
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    • v.11 no.3
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    • pp.117-122
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    • 2005
  • N-vinyl caprolactam (NVCL), a kind of N-vinyl amide monomer, must be dissolved in continuous phase ($scCO_2$) for dispersion polymerization in supercritical carbon dioxide. Phase behavior of $CO_2$+NVCL is very important and necessary for determining initial polymerization condition and for monomer extraction from final polymer. There is the limitation of experimental method for obtaining pure properties of the monomer because of the possibility of polymerization. And N-methyl caprolactam (NMCL) is the useful solvent for the gas treating process. In the viewpoint of molecular thermodynamics, NVCL and NMCL have same functional group i.e. ${\varepsilon}$-caprolactam. In the case of NVCL, hydrogen of amide group is substituted with vinyl group and for NMCL, hydrogen of amide group is substituted with methyl group. We suggested modified group contribution method for this ${\varepsilon}$-caprolactam derivatives. This new group contribution parameter was applied to correlate $CO_2$ + N-vinyl caprolactam or N-methyl caprolactam system.

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Phase Behavior of Ternary Mixture of Poly(ethylene-co-octene) - Ethylene - 1-Octene (Poly(ethylene-co-octene) - Ethylene - 1-Octene 3성분계 혼합물의 상거동)

  • Lee, Sang-Ho;Sohn, Jin-Eun;Chung, Sung-Yoon;Han, Sang-Hoon
    • Elastomers and Composites
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    • v.41 no.2
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    • pp.116-124
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    • 2006
  • Cloud-point data to $160^{\circ}C$ and 1,000 bar are presented with poly(ethylene-co-15.3 mole% octene) copolymers ($PEO_{15}$) in pure 1-octene and mixtures of ethylene - 1-octene. The cloud-point curves for $PEO_{15}$ - ethylene - 1-octene mixture dramatically increase in pressure to as high as 1,000 bar with an increasing ethylene concentration. At ethylene concentrations less than 18 wt%, the ternary mixture has bubble- and cloud-point curves. As the ethylene concentration of the ternary mixture increases, the bubble-point curve and the single-phase region reduce. The reduction in the single phase region with increasing ethylene concentrations is the result of reduced dispersion interactions between $PEO_{15}$ and the mixed solvent. The single-phase region decreases with increasing temperatures when ethylene concentrations are lower than 36 wt%, whereas the single-phase region increases with temperatures at ethylene concentrations greater than 50 wt%. At ethylene concentrations greater than 50 wt% the effect of the polar interactions of the mixed solvent, which is unfavorable to dissolve PEO, is greater than the effect of the density of the mixed solvent. Therefore, the cloud-point pressures increase with a decreasing temperature. However, at ethylene concentrations less than 50 wt%, the cloud-point pressures decrease with temperature, because the effect of the polar interactions is less than the density effect.

Flow Behavior of Polystyrene and Poly(butyl methacrylate) Composite Particles Filled with Varying Concentrations of Carbon Black (다양한 농도의 카본블랙을 함유하는 폴리스티렌 및 폴리뷰틸메타크릴레이트 복합체 입자의 유동성)

  • Park, Moon-Soo
    • Elastomers and Composites
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    • v.44 no.3
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    • pp.336-342
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    • 2009
  • We measured shear viscosity of polystyrene (PS) and poly(butyl methacrylate) (PBMA) particles, with a capillary rheometer, prepared by suspension polymerization with 1.0 wt% hydrophobic silica as a stabilizer by varying the initiator concentration at $75^{\circ}C$. PS particles with weight average molecular weight of 66,500 g/mol displayed a Newtonian behaior at low shear rates at $190^{\circ}C$. With increasing molecular weight, PS particles showed shear thinning over the entire range of shear rates. For PBMA particles, steady shear measurement was carried out at $170^{\circ}C$. PBMA particles with weight average molecular weight of 156,700 g/mol showed a Newtonian behaior only at low shear rates. PBMA particles also showed shear thinning with an increase in molecular weight and its pattern similar to that of PS. When carbon black was incorporated into PS and PBMA polymers, steady shear measurement was conducted at $170^{\circ}C$. An increase in carbon black concentration in PS and PBMA composite particles exhibited a progressive increase in shear viscosity. The increase in shear viscosity, however, was less pronounced compared to an increase as a function of molecular weight. Preparing PS composites containing carbon black by internal mixing resulted in an increase in shear viscosity. Its increase, however, was found to be less than that shown in PS composite particles. We speculate that this is caused by an enhanced dispersion of carbon black particles with an internal mixer. Yield behavior was not observed in any of the samples we selected in this experiment.

Factors Affecting Overall Satisfaction on Car Sharing Service: Satisfaction on Service Quality, Satisfaction on Service Product, Satisfaction on Service Experience (카쉐어링 서비스 종합만족도에 영향을 미치는 요인: 서비스품질 만족도, 서비스상품 만족도, 서비스체험 만족도를 중심으로)

  • Kim, Minjeong;Rhee, Hyongjae
    • Journal of Service Research and Studies
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    • v.9 no.3
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    • pp.17-38
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    • 2019
  • With recent dispersion of sharing economy, consumption culture of sharing, instead of ownership, gets wide spread in the age groups of 20-30. Even though the market of car sharing expands rapidly, little research has been done in the area of service quality and consumer behavior regarding car sharing services. Given that future market potential gets larger, it seems highly meaningful to conduct research on customer satisfaction and their usage behavior regarding car sharing services. This paper intends to analyze main factors affecting overall customer satisfaction on car sharing services; satisfaction on service quality, satisfaction on service product, and satisfaction on service experience. Each dimension of the three factors is also analyzed to see if there is any differences between major three brands. Further analysis has been done for checking any effects of gender and usage purpose of customers on the overall customer satisfaction. Key results of the analysis show all the three main factors have significant effect on overall customer satisfaction. Each dimension of service quality has significant effect on satisfaction on service quality. Dimensions of parking lot accessability and vehicle maintenance in service product evaluation, have greater effect on satisfaction on service product. In service experience, positive affect have greater effect than negative affect on satisfaction on service experience. Women users perceive larger overall customer satisfaction on car sharing services than men users. On the types of usage purpose, Users with purpose of tour and dating/meeing friends perceive larger overall customer satisfaction on car sharing services than user without it. Further managerial implications of car sharing services are also provided.

Sibutramine Release Behavior from Microspheres Prepared by Spray-Dry Method (분무건조 방법으로 제조된 미립구에서 Sibutramine의 방출거동)

  • Park, Jung-Soo;Oh, Jung-Soo;Oh, Jae-Min;Kim, Yun-Tae;Lee, Jun-Hee;Mo, Jong-Hyun;Lee, Hai-Bang;Khang, Gil-Son
    • Polymer(Korea)
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    • v.32 no.3
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    • pp.193-198
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    • 2008
  • Sibutramine is a highly crystalline and poorly water soluble drug as the appetite depressant for obesity treatment. In order to increase water solubility of sibutramine, microspheres including sibutramine were prepared by solid dispersion method using a spray dryer. The crystallinity and morphology of the prepared microspheres were confirmed by SEM and XRD. The morphology of micro spheres has gradually changed into spherical shape as increasing evaporation rate of solvent. According to XRD analysis, crystallinity of sibutramine in micro spheres was decreased by below 10%. Release behavior of microspheres was investiaged at pH 1.2, pH 6.8, and solubility of the sibutramine was significantly different depending on pH. The hard capsule showed fast release of sibutramine comparing with the tablet. These results demonstrated that the pharmaceutical preparation is able to control the release behaviors.