• Title/Summary/Keyword: Dispersion behavior

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Frequency and instability responses in nanocomposite plate assuming different distribution of CNTs

  • Farokhian, Ahmad;Kolahchi, Reza
    • Structural Engineering and Mechanics
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    • v.73 no.5
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    • pp.555-563
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    • 2020
  • The objective of present paper is assessment of dynamic buckling behavior of an embedded sandwich microplates in thermal environment in which the layers are reinforced through functionally graded carbon nanotubes (FG-CNTs). Therefore, mixture rule is taken into consideration for obtaining effective material characteristics. In order to model this structure much more realistic, Kelvin-Voigt model is presumed and the sandwich structure is rested on visco-Pasternak medium. Exponential shear deformation theory (ESDT) in addition to Eringen's nonlocal theory are utilized to obtain motion equations. Further, differential cubature method (DCM) as well as Bolotin's procedure are used to solve governing equations and achieve dynamic instability region (DIR) related to sandwich structure. Different parameters focusing on volume percent of CNTs, dispersion kinds of CNTs, thermal environment, small scale effect and structural damping and their influences upon the dynamic behavior of sandwich structure are investigated. So as to indicate the accuracy of applied theories as well as methods, the results are collated with another paper. According to results, presence of CNTs and their dispersion kind can alter system's dynamic response as well.

Enhanced Crystallization of Bisphenol-A Polycarbonate by Organoclay in the Presence of Sulfonated Polystyrene Ionomers

  • Govindaiah, Patakamuri;Lee, Jung-Min;Lee, Seung-Mo;Kim, Jung-Hyun;Subramani, Sankaraiah
    • Macromolecular Research
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    • v.17 no.11
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    • pp.842-849
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    • 2009
  • Polycarbonate (PC)/sulfonated polystyrene (SPS) ionomer/organoclay nanocomposites were prepared by a solution intercalation process using the SPS ionomer as a compatibilizer. The effect of an organoclay on the melt crystallization behavior of the ionomer compatibilized PC were examined by differential scanning calorimetry (DSC). The melt crystallization behavior of PC was dependent on the extent of organoclay dispersion. The effect of the ionomer loading and cation size on intercalation/exfoliation efficiency of the organoclay in PC/SPS ionomer matrix was also studied using wide angle X-ray diffraction (WAXD) and transmission electron microscopy (TEM). Dispersion of the organically modified clay in the polymer matrix improved with increasing ionomer compatibilizer loadings and cation size. The SPS ionomer compatibilized PC/organoclay nanocomposite showed enhanced melt crystallization compared to the SPS ionomer/PC blend. Well dispersed organoclay nanocomposites showed better crystallization than the poorly dispersed clay nanocomposites. These nanocomposites also showed better thermal stability than the SPS ionomer/PC blend.

Similarity Analysis for the Dispersion of Spiraling Modes on Metallic Nanowire to a Planar Thin Metal Layer

  • Lee, Dong-Jin;Park, Se-Geun;Lee, Seung-Gol;O, Beom-Hoan
    • Journal of the Optical Society of Korea
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    • v.17 no.6
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    • pp.538-542
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    • 2013
  • We propose a simple model to elucidate the dispersion behavior of spiraling modes on silver nanowire by finding correspondence parameters and building a simple equivalent relationship with the planar insulator-metal-insulator geometry. The characteristics approximated for the proposed structure are compared with the results from an exact solution obtained by solving Maxwell's equation in cylindrical coordinates. The effective refractive index for our proposed equivalent model is in good agreement with that for the exact solution in the 400-2000 nm wavelength range. In particular, when the radius of the silver nanowire is 100 nm, the calculated index shows typical improvements; the average percentage error for the real part of the effective refractive index is reduced to only 5% for the $0^{th}$ order mode (11.9% in previous results) and 1.5% for the $1^{st}$ order mode (24.8% in previous results) in the 400-800 nm wavelength range. This equivalent model approach is expected to provide further insight into understanding the important behavior of nanowire waveguides.

Analysis on Milling Behavior of Oxide Dispersion Strengthened Ni-based Atomizing Powder with Ni5Y Intermetallic Phase (Ni5Y 합금상이 형성된 Ni계 산화물 분산강화 아토마이징 분말의 밀링 거동 분석)

  • Park, Chun Woong;Byun, Jong Min;Choi, Won June;Kim, Young Do
    • Journal of Powder Materials
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    • v.26 no.2
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    • pp.101-106
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    • 2019
  • Ni-based oxide dispersion strengthened (ODS) alloys have a higher usable temperature and better high-temperature mechanical properties than conventional superalloys. They are therefore being explored for applications in various fields such as those of aerospace and gas turbines. In general, ODS alloys are manufactured from alloy powders by mechanical alloying of element powders. However, our research team produces alloy powders in which the $Ni_5Y$ intermetallic phase is formed by an atomizing process. In this study, mechanical alloying was performed using a planetary mill to analyze the milling behavior of Ni-based oxide dispersions strengthened alloy powder in which the $Ni_5Y$ is the intermetallic phase. As the milling time increased, the $Ni_5Y$ intermetallic phase was refined. These results are confirmed by SEM and EPMA analysis on microstructure. In addition, it is confirmed that as the milling increased, the mechanical properties of Ni-based ODS alloy powder improve due to grain refinement by plastic deformation.

IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

  • Meyer, M.K.;Gan, J.;Jue, J.F.;Keiser, D.D.;Perez, E.;Robinson, A.;Wachs, D.M.;Woolstenhulme, N.;Hofman, G.L.;Kim, Y.S.
    • Nuclear Engineering and Technology
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    • v.46 no.2
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    • pp.169-182
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    • 2014
  • High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. U-Mo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

Wave dispersion analysis of rotating heterogeneous nanobeams in thermal environment

  • Ebrahimi, Farzad;Haghi, Parisa
    • Advances in nano research
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    • v.6 no.1
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    • pp.21-37
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    • 2018
  • In the present article, wave dispersion behavior of a temperature-dependent functionally graded (FG) nanobeam undergoing rotation subjected to thermal loading is investigated according to nonlocal strain gradient theory, in which the stress numerates for both nonlocal stress field and the strain gradient stress field. The small size effects are taken into account by using the nonlocal strain gradient theory which contains two scale parameters. Mori-Tanaka distribution model is considered to express the gradually variation of material properties across the thickness. The governing equations are derived as a function of axial force due to centrifugal stiffening and displacements by applying Hamilton's principle according to Euler-Bernoulli beam theory. By applying an analytical solution, the dispersion relations of rotating FG nanobeam are obtained by solving an eigenvalue problem. Obviously, numerical results indicate that various parameters such as angular velocity, gradient index, temperature change, wave number and nonlocality parameter have significant influences on the wave characteristics of rotating FG nanobeams. Hence, the results of this research can provide useful information for the next generation studies and accurate deigns of nanomachines including nanoscale molecular bearings and nanogears, etc.

Electrorhelological Properties of Monodispersed Submicron-sized Hollow Polyaniline Adipate Suspension

  • Sung, Bo-Hyun;Choi, Ung-Su
    • KSTLE International Journal
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    • v.6 no.1
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    • pp.28-32
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    • 2005
  • The electrorheoloRical (ER) fluids are composed of a colloidal dispersion of polarizable particles in insulating oil, and it's the rheological property changes by the applied electric field. These changed are reversible and occur fast within a fewmilliseconds. The ER properties of the ER fluid such as increment of viscosity and yield stress come from the particle chain structure induced by electric fleld. When formulating the ER fluid for a speciflc application, some requirement must besatisfled, which are high yield stress under electric field, rapid response, and dispersion stability. While this characteristic makes valuable ER fluids in valious industrial applications, their lung term and quiescent application has been limited because ofproblems with particle sedimentation. In an effort to overcome sedimentation problem of ER fluids, the anhydrous ER materials of monodispersed hollow polyaniline (PANI) and adipate derivative respectively with submicron-sized suspension providing wide operating temperature range and other advantage were synthesized in a four-step procedure. The ER fluidswere characterized by FT-lR, TGA, DLS, SEM, and TEM. Stability of the suspensions was examined by an UV spectroscopy.The rheological and electrical properties of the suspension were investigated Couette-type rheometer with a high voltagegenerator, current density, and conductivity. And the behavior of ER suspensions was observed by a video camera attached toan optical microscope under 3kV/mm. The suspensions showed good ER properties, durability, and particle dispersion.

Influence of Nanodispersed Organoclay on Rheological and Swelling Properties of Ethylene Propylene Diene Terpolymer

  • Acharya Himadri;Srivastava Suneel K.
    • Macromolecular Research
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    • v.14 no.2
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    • pp.132-139
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    • 2006
  • The dispersion of organoclay in ethylene propylene diene terpolymer (EPDM) matrix was correlated with the rheological and swelling properties of nanocomposites. X-ray diffraction pattern (XRD) and transmission electron microscopic (TEM) analysis exhibited the disordered-intercalated structure of EPDM/organoclay nanocomposite. The extent of the disordered phase increased with increasing organoclay content up to a limiting value of 3 wt% after which equilibrium tended towards intercalation. The dispersion effect of organoclay in EPDM matrix was clarified by the physicochemical properties like rheological response and swelling thermodynamics in toluene. The increase in viscoelastic properties of EPDM nanocomposite with increasing organoclay content up to 3 wt%, followed by a subsequent decrease up to 4 wt%, was correlated in terms of the disordered and ordered states of the dispersed nano-clay sheets. Swelling measurements revealed that the change in entropy of the swelling increased with the increase in disorder level but decreased with the increase in intercalation level of organoclay in the disordered-intercalated nanocomposite. The increase in solvent uptake was comparable with the free volume in EPDM matrix upon inclusion of silicate particles, whereas the inhibition in solvent uptake for higher organoclay loading was described by bridging flocculation.

Particle Dispersion and Fine Scale Eddies in Wall Turbulence (벽면난류에 대한 미세와 구조와 입자분산)

  • Kang, Shin-Jeong;Tanahashi, Mamoru;Miyauchi, Toshio
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.11 s.254
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    • pp.1101-1106
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    • 2006
  • To investigate a relation between fine scale eddies and particle dispersion in a near-wall turbulence, direct numerical simulations of turbulent channel flow laden particle are performed for $Re_{\tau}$=180. The motions of 0,8 million particles are calculated for several particle response times ($t_p$) which is the particle response time based on stokes’ friction law. The number density of particles has a tendency to increase with approaching the near-wall regions ($y^+$<20) except for cases of very small and large particle response times (i.e. $t_p$=0.02 and 15). Near the wall, the behavior and distribution of particles are deeply associated with the fine scale eddies, and are dependent on particle response times and a distance from the wall. The Stokes number that causes preferential distribution in turbulence is changed by a distance from the wall. The influential Stokes number based on the Burgers' vortex model is derived by using the time scale of the fine scale eddies. The influential Stokes number is also dependent on a distance from the wall and shows large value in the buffer layer.

A nonlocal strain gradient theory for scale-dependent wave dispersion analysis of rotating nanobeams considering physical field effects

  • Ebrahimi, Farzad;Haghi, Parisa
    • Coupled systems mechanics
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    • v.7 no.4
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    • pp.373-393
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    • 2018
  • This paper is concerned with the wave propagation behavior of rotating functionally graded temperature-dependent nanoscale beams subjected to thermal loading based on nonlocal strain gradient stress field. Uniform, linear and nonlinear temperature distributions across the thickness are investigated. Thermo-elastic properties of FG beam change gradually according to the Mori-Tanaka distribution model in the spatial coordinate. The nanobeam is modeled via a higher-order shear deformable refined beam theory which has a trigonometric shear stress function. The governing equations are derived by Hamilton's principle as a function of axial force due to centrifugal stiffening and displacement. By applying an analytical solution and solving an eigenvalue problem, the dispersion relations of rotating FG nanobeam are obtained. Numerical results illustrate that various parameters including temperature change, angular velocity, nonlocality parameter, wave number and gradient index have significant effect on the wave dispersion characteristics of the understudy nanobeam. The outcome of this study can provide beneficial information for the next generation researches and exact design of nano-machines including nanoscale molecular bearings and nanogears, etc.