• Journal of the Korean Society for Industrial and Applied Mathematics
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• 제17권2호
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• pp.129-138
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• 2013

A spatio-temporal models as systems of ODE which describe two-species Beddington - DeAngelis type predator-prey system living in a habitat of two identical patches linked by migration is investigated. It is assumed in the model that the per capita migration rate of each species is influenced not only by its own but also by the other one's density, i.e. there is cross diffusion present. We show that a standard (self-diffusion) system may be either stable or unstable, a cross-diffusion response can stabilize an unstable standard system and destabilize a stable standard system. For the diffusively stable model, numerical studies show that at a critical value of the bifurcation parameter the system undergoes a Turing bifurcation and the cross migration response is an important factor that should not be ignored when pattern emerges.

• Bulletin of the Korean Chemical Society
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• 제12권6호
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• pp.625-628
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• 1991

Using uniform flat plate-like samples of ZSM-5 zeolites, diffusion coefficients were measured volumetrically for the diffusion of xylene, ethyltoluene and diethylbenzene by direct measurement of sorption rate. Toluene disproportionation over H(100)-, K(72)-and Cs(82)-ZSM-5 at 773 K and toluene methylation, toluene ethylation and ethylbenzene ethylation over Cs(75)-ZSM-5 at 623 K were carried out. The selective formation of para xylene during the toluene disproportionation, presumably due to the increased tortuosity over Cs-ZSM-5, could be explained by smaller diffusion coefficient in Cs-ZSM-5 than in K-and H-ZSM-5. The para selectivity increased in the order; toluene methylation < toluene ethylation < ethylbenzene ethylation. As the chain length of the alkyl substituent in dialkylbenzenes is increased, the para selectivity of the products was improved. It may be attributed to the differences in the ratios of diffusion coefficient of para products to that of ortho ones. Diffusion coefficient of m-xylene was about 1 order of magnitude smaller than that of o-xylene.

• 한국데이타베이스학회:학술대회논문집
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• 한국데이타베이스학회 2010년도 춘계국제학술대회
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• pp.165-180
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• 2010

This study takes a holistic approach to understanding the diffusion of IPTV services by combining the adoption-diffusion model and the use-diffusion model of innovation. IPTV service, a leading Digital converged application coupling media content with telecom, has been recently launched commercially in Korea. We created a structural model of adoption-diffusion, using the perceived ease-of-use and usefulness of TAM(Technology Acceptance Model) as mediating variables, and a structural model of use-diffusion, with the rate of use and the variety of use as mediating variables. To empirically analyze these models, non-users of IPTV were surveyed using the adoption-diffusion model to identity factors influencing their intention to subscribe to the service. Meanwhile, users of IPTV were surveyed using the use-diffusion model to determine the factors that influence their satisfaction with the service and their intention to fe-use it. Under the adoption-diffusion model, we found that trialability, household innovativeness and perceived risk were the determinants of user satisfaction with IPTV, and perceived ease-of-use, the mediating factors. Under the use-diffusion model, complementarity and communication were shown to be the determinants of users' satisfaction with IPTV, and variety of use, the mediating factor. We also found that consumers' intention to re-use IPTV was strongly influenced by its relative advantage and perceived risk.

• 한국경영과학회지
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• 제40권4호
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• pp.107-121
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• 2015

Diffusion of innovation is the process in which an innovation is communicated through certain channels over time among the members of a social system. The literatures have emphasized the importance of interpersonal network influences on individuals in convincing them to adopt innovations and thereby promoting its diffusion. In particular, the behavior of opinion leaders who lead in influencing others' opinion is important in determining the rate of adoption of innovation in a system. Centrality has been recognized as a good indicator that quantifies a node's influences on others in a given network. However, recent studies have questioned its relevance on various different types of diffusion processes. In this regard, this study aims at examining the effect of a node exhibiting high centrality on expediting diffusion of innovations. In particular, we considered the situation where two innovations compete with each other to be adopted by potential adopters who are personally connected with each other. In order to analyze this competitive diffusion process, we developed a simulation model and conducted regression analyses on the outcomes of the simulations performed. The results suggest that the effect of a node with high centrality can be substantially reduced depending upon the type of a network structure or the adoption thresholds of potential adopters in a network.

• 한국결정성장학회지
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• 제19권5호
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• pp.237-241
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• 2009

Dislocation dipoles were formed in the early stage of deformation of Y-CSZ single crystal at high temperatures. And the dipoles were pinched off to break into dipoles loops by dislocation climb. Dislocation loop annealing was peformed in Y-CSZ single crystal to evaluate the diffusivity of cation which was the rate-controlling ion.

• Bulletin of the Korean Chemical Society
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• 제12권6호
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• pp.692-698
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• 1991

The reaction path Smoluchowski equation approach developed in a recent work to calculate the rate constant for a diffusive multidimensional barrier crossing process is extended to incorporate the configuration-dependent diffusion matrix. The resulting formalism is then applied to the investigation of stilbene photoisomerization dynamics. Adapting a model two-dimensional potential and a model diffusion matrix proposed by Agmon and Kosloff [J. Phys. Chem.,91 (1987) 1988], we derive an eigenvalue equlation for the relaxation rate constant of the stilbene photoisomerization. This eigenvalue equation is solved numerically by using the finite element method. The advantages and limitations of the present method are discussed.

• 분석과학
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• 제9권3호
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• pp.292-301
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• 1996

산화환원반응 탐침제로, poly ether 꼬리가 결합된 Cobalt(II)bipyridine 착물을 합성 하였고, 이들 화합물의 느린 확산계수와 불균일 전자이동을 설명하였다. $Co(bpy(ppgm)_2)_{3^-}(ClO_4)_2$에 전해질 $LiClO_4$가 혼합된 neat 상태의 산화반응에 대한 확산계수는 $1.5{\times}10^{-15}cm^2/s$ 였다. 이 화합물들의 불균일 전자이동 속도상수들은 확산계수와 관련이 있었다. 확산계수의 감소에 따라 속도상수(k)의 감소가 일어났다. 강한 이온쌍을 형성하는 $ClO{_4}^-$의 화합물은 약한 이온 쌍을 형성하는 $CF_3COO^-$ 화합물보다 확산계수가 훨씬 작았다.

• Transactions on Electrical and Electronic Materials
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• 제13권6호
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• pp.273-277
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• 2012

The vacuum drying process for drying of paper in current transformers was modeled with an aim to develop an understanding of the drying mechanism involved and also to predict the water collection rates. A molecular as well as macroscopic approach was adopted for the prediction of drying rate. Ficks law of diffusion was adopted for the prediction of drying rates at macroscopic levels. A steady state and dynamic mass transfer simulation was performed. The bulk diffusion coefficient was calculated using weight loss experiments. The accuracy of the solution was a strong function of the relation developed to determine the equilibrium moisture content. The actually observed diffusion constant was also important to predict the plant water removal rate. Thermo gravimetric studies helped in calculating the diffusion constant. In addition, simulation studies revealed the formation of perpetual moisture traps (loops) inside the CT. These loops can only be broken by changing the temperature or pressure of the system. The change in temperature or pressure changes the kinetic or potential energy of the effusing vapor resulting in breaking of the loop. The cycle was developed based on this mechanism. Additionally, simulation studies also revealed that the actual mechanism of moisture diffusion in CT's is by surface jumps initiated by surface diffusion balanced against the surrounding pressure. Every subsequent step in the cycle was to break such loops. The effect of change in drying time on the electrical properties of the insulation was also assessed. The measurement of capacitance at the rated voltage and one third of the rated voltage demonstrated that the capacitance change is within the acceptance limit. Hence, the new cycle does not affect the electrical performance of the CT.

• Communications for Statistical Applications and Methods
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• 제14권1호
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• pp.241-254
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• 2007

This paper propose a new short-term interest rate model having a different nonlinear drift function and the same diffusion coefficient with Chan et al. (1992) model. The fractional polynomial power of the drift function in our model is linked to the local volatility elasticity of the diffusion coefficient. While the nonlinear drift function estimated by $A\"{\i}t$-Sahalia (1996a) and others has a feature that higher interest rates tend to revert downward and low rates upward, the drift function estimated by our nonlinear model shows that higher interest rate mean-reverts strongly, but, medium rates has almost zero drift and low rates has a very small drift. This characteristic coincides the empirical result based on the nonparametric methodology by Stanton (1997) and the implication by the scatter plot of the short rate data.

• International Journal of Safety
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• 제2권1호
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• pp.12-16
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• 2003

In Part 1, the flame structure of the counterflow nonpremixed flames computed by using Fire Dynamics Simulator was compared with that of OPPDIF for different concentrations of methane in the fuel stream. In this study, comparisons were made for the global strain rate that is an important parameter for diffusion flames for further evaluation of FDS. At each of the three fuel concentrations, $20% CH_4＋ 80% N_2, 50% CH_4 ＋ 50% N_2, 90% CH_4 ＋ 10% N_2$ in the fuel stream, the temperature and axial velocity profiles were investigated for the global strain rate in the range from 20 to $100s^{-1}$. Changes in flame thickness and radius were also compared with OPPDIF. There was good agreement in the temperature and axial velocity profiles between the axisymmetric simulations and the one-dimensional computations except for the regions where the flame temperature reach its peak and the axial velocity rapidly changes. The simulations of the axisymmetric flames with FDS showed that the flame thickness decreases and the flame radius increases with increasing global strain rate.