• Journal of the Korean Ceramic Society
• /
• v.55 no.3
• /
• pp.244-260
• /
• 2018

Issues in the electrical characterization of semiconducting photoanodes in a photoelectrochemical (PEC) cell, such as the cell geometry dependence, scan rate dependence in DC measurements, and the frequency dependence in AC measurements, are addressed, using the example of a $TiO_2$ photoanode. Contrary to conventional constant phase element (CPE) modeling, the capacitive behavior associated with Mott-Schottky (MS) response was successfully modeled by a Havriliak-Negami (HN) capacitance function-which allowed the determination of frequency-independent Schottky capacitance parameters to be explained by a trapping mechanism. Additional polarization can be successfully described by the parallel connection of a Bisquert transmission line (TL) model for the diffusion-recombination process in the nanostructured $TiO_2$ electrode. Instead of shunt CPEs generally employed for the non-ideal TL feature, TL models with ideal shunt capacitors can describe the experimental data in the presence of an infinite-length Warburg element as internal interfacial impedance - a characteristic suggested to be a generic feature of many electrochemical cells. Fully parametrized impedance spectra finally allow in-depth physicochemical interpretations.

• Proceedings of the KSME Conference
• /
• 2001.06e
• /
• pp.386-391
• /
• 2001

A finite element code based on P2P1 tetra element has been developed for the large eddy simulation (LES) of turbulent flows around a complex geometry. Fractional 4-step algorithm is employed to obtain time accurate solution since it is less expensive than the integrated formulation, in which the velocity and pressure fields are solved at the same time. Crank-Nicolson method is used for second order temporal discretization and Galerkin method is adopted for spatial discretization. For very high Reynolds number flows, which would require a formidable number of nodes to resolve the flow field, SUPG (Streamline Upwind Petrov-Galerkin) method is applied to the quadratic interpolation function for velocity variables, Noting that the calculation of intrinsic time scale is very complicated when using SUPG for quadratic tetra element of velocity variables, the present study uses a unique intrinsic time scale proposed by Codina et al. since it makes the present three-dimensional unstructured code much simpler in terms of implementing SUPG. In order to see the effect of numerical diffusion caused by using an upwind scheme (SUPG), those obtained from P2P1 Galerkin method and P2P1 Petrov-Galerkin approach are compared for the flow around a sphere at some Reynolds number. Smagorinsky model is adopted as subgrid scale models in the context of P2P1 finite element method. As a benchmark problem for code validation, turbulent flows around a sphere and a MIRA model have been studied at various Reynolds numbers.

• Journal of Ocean Engineering and Technology
• /
• v.20 no.1 s.68
• /
• pp.55-62
• /
• 2006

Recently, pollution by development in coastal areas is going from bad to worse. The Korean government is attempting to make policies that prevent water pollution, but it is still difficult to say whether such measures are lowering pollution to an acceptable level. More specifically, the general investigation that has been done in KOREA does not accurately reflect the actual conditions of pollution in coastal areas. An investigation that quantitatively assesses water quality management using rational prediction technology must be attempted, and the ecosystem model, which incorporates both the 3-dimensional hydrodynamic and material cycle models, is the only one with a broad enough scope to obtain accurate results. The hydrodynamic model, which includes advection and diffusion, accounts for the ever-changing flow and (quality) of water in coastal areas, while the material cycle model accounts for pollutants and components of decomposition as sources of the carbon, phosphorus, and nitrogen cycles. In this paper, we simulated the rates of dissolved oxygen (DO), chemical oxygen demand (COD), total nitrogen(T-N) and total-phosphorous(T-P) in Korea's Ulsan Area. Using the ecosystem model, we did simulations using a specific set of parameters and did comparative analysis to determine those most appropriate for the actual environmental characteristics of Ulsan Area. The simulation was successful, making it now possible to predict the likelihood of coastal construction projects causing ecological damage, such as eutrophication and red tide. Our model can also be used in the environmental impact assessment (EIA) of future development projects in the ocean.

• Journal of the Korean earth science society
• /
• v.35 no.4
• /
• pp.237-248
• /
• 2014

To analyze the characteristics of deposition and dispersion of volcanic ash emitted from Mt. Kirishima on January 26, 2011, several numerical simulations were carried out by using the numerical models including Weather and Research Forecast (WRF) and FLEXPART. The dispersion of ash located under 1 km high tends to be concentrated along the prevailing wind direction on January 26 2011. On the other hand, volcanic ash released on the following day spreads to Kirishima bay due to the intensified high pressure air mass in southern Kyushu. When Siberian air mass was intensified January 26, 2011, the deposition of volcanic ash is concentrated restrictedly in the narrow area along the wind direction of the downwind side of Mt. Kirishima. The development of high pressure air mass over the eruption area tends to induce the intensified horizontal diffusion of volcanic ash. Since the estimated deposition of volcanic ash is agreed well with observed values, the proposed numerical simulation is reasonable to use the assessment on the behavior of volcanic ash.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.6 no.1
• /
• pp.40-50
• /
• 1994

For an accurate prediction of the temperature field induced by heated water discharged into a shallow crossflow, a two-dimensional near-field numerical model is developed. It is based on a 4-equation turbulence model in which the transport equations for mean of the temperature fluctuation squared and its dissipation rate are added to those of a 2-equation turbulence model which cannot give the information of the thermal time scale ratio. Vertical diffusion is also considered by including buoyancy production and turbulence heat flux terms. The developed model is applied to a steady flow in an open channel with simple geometry and the results are compared with existing experimental data and those of the already established 2-equation turbulence model. Numerical results of the model agree with the experimental data better than those of the 2-equation model. The present model also simulates quite adequately the physical characteristics of thermal discharge in the jet entrainment and stable regions.

• Proceedings of the Korea Inteligent Information System Society Conference
• /
• 2001.01a
• /
• pp.37-44
• /
• 2001

This paper describes the modeling of work environment for the extraction of abstract operation rules for cooperative work with multiple agent. We propose the modeling method using a potential field. In the method, it is applied to a box pushing problem, which is to move a box from a start to a goal b multiple agent. The agents follow the potential value when they move and work in the work environment. The work environment is represented as the grid space. The potential field is generated by Genetic Algorithm(GA) for each agent. GA explores the positions of a potential peak value in the grid space, and then the potential value stretching in the grid space is spread by a potential diffusion function in each grid. However it is difficult to explore suitable setting using hand coding of the position of peak potential value. Thus, we use an evlolutionary computation way because it is possible to explore the large search space. So we make experiments the environment modeling using the proposed method and verify the performance of the exploration by GA. And we classify some types from acquired the environment model and extract the abstract operation rule, As results, we find out some types of the environment models and operation rules by the observation, and the performance of GA exploration is almost same as the hand coding set because these are nearly same performance on the evaluation of the consumption of agent's energy and the work step from point to the goal point.

• Korean Management Science Review
• /
• v.22 no.1
• /
• pp.103-125
• /
• 2005

Korean government is planning to adopt double entry bookkeeping with accrual basis in the government accounting system. This paper attempts to identify influencing attitudes of information producers toward the acceptance of the new service system. Several models are introduced, including Luder's Contingency Model, Cheng's Politico-Economic Model of Accounting Policy Choice, Roger's Diffusion of innovation, and Davis's Technology Acceptance Model(TAM). A set of constructs are developed as fellows : information producers' knowledges, experiences, altitudes toward the reform, characteristics of cash based accounting system and new accrual based system, a chief executive officer's willingness to support, availability of supporting systems, and social Influences from external environment. This study also incudes hey factors used in TAM, such as perceived usefulness and ease of use. Survey responses are gathered from accounting officers in government ministries and agencies as well as from local governments. Regression analysis shows that, for information producers, both 'perceived ease of use' and 'perceived usefulness' of the new system are the best explanatory variable for the dependent variable. It has also found that 'perceived usefulness' is explained best by individual characteristics such as knowledge and experiences, quality of current cash based s1n91e entry bookkeeping system, chief executive's support, Positive supporting systems and social influences. The useful guidelines for implementing double-entry bookkeeping system with accrual basis are also provided.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.41 no.8
• /
• pp.597-604
• /
• 2013

A coupled thermomechanical analysis of composite structures in pyrolysis and ablation environments is performed. The pyrolysis and ablation models include the effects of mass loss, pore gas diffusion, endothermic reaction energy, surface recession, etc. The thermal and structural analysis interface is based upon a staggered coupling algorithm by using a commercial finite element code. The characteristics of the proposed method are investigated through numerical experiments with carbon/phenolic composites. The numerical studies are carried out to examine the surface recession rate by chemical and mechanical ablation. In addition, the effects of shrinkage or intumescence during the pyrolysis process are shown.

• Journal of Pharmaceutical Investigation
• /
• v.37 no.2
• /
• pp.73-78
• /
• 2007

The aim of this study was to investigate the absorption properties of ketoprofen. The in-situ perfusion model has advantages over in vitro models as it provides intact lymphatic and blood flow circulation. The absorption properties of six different concentrations of ketoprofen have been studied in single pass in-situ rat intestine model. $^{14}C-PEG$ 4000 was used as a permeability marker and the possibility of an energy dependent contribution to ketoprofen absorption was also Investigated using the metabolic inhibitor sodium azide. Three different concentrations of sodium azide were studied to examine its effect on absorption of ketoprofen from the rat intestine. The findings of this study suggest that mono-carboxylic type drugs like ketoprofen cause permeability changes in the intestine. This is shown by the increase in absorption of $^{14}C-PEG$ 4000 as the concentration of ketoprofen is increased. However, the trend for ketoprofen permeability is to decrease over the concentration ranges. It was observed that the Papp values for ketoprofen with sodium azide shows a trend towards reduction in the amount of ketoprofen absorbed from the rat intestine which was significantly different (p<0.05) from that of ketoprofen with sodium azide 3.0mM. This indicates that sodium azide has an affect on the absorption of ketoprofen. The pH of all the perfusion solutions was altered to ${\sim}pH\;6.7$ by the buffering capacity of the small intestine secretions. The results suggest that mechanisms other than passive diffusion may be involved in ketoprofen absorption. This would be consistent with the involvement of active transport or saturatable processes in the absorption of drugs containing monocarboxylic acid group, as has been previously suggested from in vitro data.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.4 no.4
• /
• pp.203-212
• /
• 2002

This study was conducted to remove the urban heat island effects embedded in the interpolated surfaces of daily minimum temperature in the Korean Peninsula. Fifty six standard weather stations are usually used to generate the gridded temperature surface in South Korea. Since most of the weather stations are located in heavily populated and urbanized areas, the observed minimum temperature data are contaminated with the so-called urban heat island effect. Without an appropriate correction, temperature estimates over rural area or forests might deviate significantly from the actual values. We simulated the spatial pattern of population distribution within any single population reporting district (city or country) by allocating the reported population to the "urban" pixels of a land cover map with a 30 by 30 m spacing. By using this "digital population model" (DPM), we can simulate the horizontal diffusion of urban effect, which is not possible with the spatially discontinuous nature of the population statistics fer each city or county. The temperature estimation error from the existing interpolation scheme, which considers both the distance and the altitude effects, was regressed to the DPMs smoothed at 5 different scales, i.e., the radial extent of 0.5, 1.5, 2.5, 3.5 and 5.0 km. Optimum regression models were used in conjunction with the distance-altitude interpolation to predict monthly normals of daily minimum temperature in South Korea far 1971-2000 period. Cross validation showed around 50% reduction in terms of RMSE and MAE over all months compared with those by the conventional method.conventional method.