• Title/Summary/Keyword: Diffusion Term

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Development and Evaluation of Bipolar Plates Coated with Noble Metals for Polymer Electrolyte Membrane Fuel Cells (Noble Metal이 코팅된 금속분리판 개발 및 성능 평가)

  • Seo, Hakyu;Han, In-Su;Jung, Jeehoon;Kim, Minsung;Shin, Hyungil;Hur, Taeuk;Cho, Sungbaek
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.90.2-90.2
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    • 2010
  • The coated metallic bipolar plates are getting attractive due to their good feasibility of mass production, low contact resistance, high electrical/thermal conductivity, low gas permeability and good mechanical strength comparing with graphite materials. Yet, metallic bipolar plates for polymer electrolyte membrane(PEM) fuel cells typically require coatings for corrosion protection. Other requirements for the corrosion protective coatings include low electrical contact resistance between metallic bipolar plate and gas diffusion layer, good mechanical robustness, low mechanical and fabrication cost. The authors have evaluated a number of protective coatings deposited on stainless steel substrate by electroplating. The coated metallic bipolar plates are investigated with an electrochemical polarization tests, salt dipping tests, adhesion tests for corrosion resistance and then the contact resistance was measured. The results showed that the selective samples electroplated with optimized method, satisfied the DOE target for corrosion resistance and contact resistance, and also were very stabilized in the typical fuel cell environments in the long-term.

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Invasive alien plant Characteristics and Management Measures in Mt. Inwang, Seoul (서울 인왕산의 침입외래식물 특성 및 관리방안)

  • Cha, Doo-Won;Ban, Su-Hong;Oh, Choong-Hyeon
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.22 no.6
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    • pp.89-96
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    • 2019
  • This study was carried out for management of the invasive alien plants in Mt. Inwang located in central Seoul. The invasive alien plants are 11 families, 34 genera, 30 taxa, and they are 10.8% of the total vascular plants(314 taxa). The ecosystem disturbed plants designated by the Korea environment ministry are 6 taxa : Rumex acetosella, Lactuca scariola, Ambrosia trifida var. trifida, Ambrosia artemisiifolia, Aster pilosus and Eupatorium rugosum. In the life-form, herbaceous perennials are 13 taxa(35.3%). In the continent of origin, the species from America are 20 taxa(58.8%). In the introduction time, the species of third period are 14 taxa(41.2%). In the diffusion grade, 5 grade species are 14 taxa(41.2%) and they are wide spread species. Mt. Inwang was designated as ecological scenery conservation area of Seoul in 2007. But Mt. Inwang is in high danger by the spread of invasive alien plants and ecosystem disturbed plants, due to artificial factors such as development pressure and the occurrence of byway trail. Therefore, Mt. Inwang needs systematic management of invasive alien plants and monitoring of long-term changes.

Characterization and antimicrobial efficacy of Portland cement impregnated with silver nanoparticles

  • Nam, Ki Young
    • The Journal of Advanced Prosthodontics
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    • v.9 no.3
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    • pp.217-223
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    • 2017
  • PURPOSE. This study investigated the effects of silver nanoparticle (SN) loading into hydraulic calcium silicate-based Portland cement on its mechanical, antibacterial behavior and biocompatibility as a novel dental bone substitute. MATERIALS AND METHODS. Chemically reduced colloidal SN were combined with Portland cement (PC) by the concentrations of 0 (control), 1.0, 3.0, and 5.0 wt%. The physico-mechanical properties of silver-Portland cement nanocomposites (SPNC) were investigated through X-ray diffraction (XRD), setting time, compressive strength, solubility, and silver ion elution. Antimicrobial properties of SPNC were tested by agar diffusion against Streptococcus mutans and Streptococcus sobrinus. Cytotoxic evaluation for human gingival fibroblast (HGF) was performed by MTS assay. RESULTS. XRD certified that SN was successfully impregnated in PC. SPNC at above 3.0 wt% significantly reduced both initial and final setting times compared to control PC. No statistical differences of the compressive strength values were detected after SN loadings, and solubility rates of SPNC were below 3.0%, which are acceptable by ADA guidelines. Ag ion elutions from SPNC were confirmed with dose-dependence on the concentrations of SN added. SPNC of 5.0 wt% inhibited the growth of Streptococci, whereas no antimicrobial activity was shown in control PC. SPNC revealed no cytotoxic effects to HGF following ISO 10993 (cell viability > 70%). CONCLUSION. Addition of SN promoted the antibacterial activity and favored the bio-mechanical properties of PC; thus, SPNC could be a candidate for the futuristic dental biomaterial. For clinical warrant, further studies including the inhibitory mechanism, in vivo and long-term researches are still required.

-A Study on a Mathematical Model for Water Quality Prediction for Rivers- (하천(河川)의 수질예측(水質豫測)을 위한 수치모형(數値模型)에 관한 연구(硏究))

  • Kim, Sung-Soon;Lee, Yang-Kyoo;Kim, Gap-Jin
    • Journal of Korean Society of Water and Wastewater
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    • v.9 no.4
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    • pp.73-86
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    • 1995
  • The propriety of the numerical model application was examined on Paldang resevoir and its inflow tributaries located in the center of the Korean peninsula and the long term water quality forecast of the oxygen profile was carried out in this syduy. The input data of the model was the capacity of the reservoir, catchment area, percolation, diffusion rate, vertical mixing rate, dissolution rate from the bottom of the reservoir, outflow of the resevoir, water quality measurement and meteorology data of the drainage basin, and the output result was the annual estimation value of the dissolved oxygen concentration and the biochemical oxygen demand. The modeling method is based on the measured or calculated boundary condition dividing the water area into several blocks from the macorscopic aspect and considering the mass balance in these blocks. As the result of the water quality forecast, it was expected that the water quality in Northern Han River and Paldang reservoir would maintain the recent level, but that the water quality in the Southern Han River and its inflow tributary would worsen below the grade 4 of the life environmental standard from around 2000 owing to the decrease of DO concentration and the increase of BOD concentration.

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Performance Analysis for Open-loop Geothermal System with Spill-way technology by Real-scale Experiment (관정간 도수통로를 설치한 개방형 지열 시스템의 냉방성능 실험)

  • Kim, Hong kyo;Bae, Sangmu;Nam, Yujin;Jeoun, Oun;Oh, Jong Hyun;Lee, Byong Ho
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.30 no.4
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    • pp.186-194
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    • 2018
  • A ground-source heat pump system (GSHP) is more energy efficient than other heat-source systems because it uses annual constant underground and water temperatures. Especially, two-well geothermal systems using groundwater as the heat source can achieve higher performance than closed-loop geothermal systems. However, performance of two-well geothermal systems is decreased by occurring overflow according to scale during long-term operations. Therefore, this study presents a two-well pairing geothermal system that controls the groundwater level of a diffusion well. In addition, a two-well pairing geothermal system and an SCW geothermal system were installed, and a comparative analysis of cooling performance depending on system operation under the same load conditions was conducted. The result was that the average heat pump coefficient of performance (COP) of the two-well pairing system was 6.5, and the entire system COP was 4.3.

Characterization and Release Behavior of Polymersomes of PEG-Poly(fumaric-sebacic acids)-PEG Triblock Copolymer in Aqueous Solution (PEG-Poly(fumaric-sebacic acids)-PEG 삼중 블록 공중합체로 수용액에서 만들어진 폴리머솜의 분석과 방출특성)

  • Pourhosseini, Pouneh S.;Saboury, Ali A.;Najafi, Farhood;Divsalar, Adeleh;Sarbolouki, Mohammad N.
    • Polymer(Korea)
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    • v.37 no.3
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    • pp.294-301
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    • 2013
  • Polymersomes made of biodegradable triblock copolymers based on poly(fumaric acid-co-sebacoyl chloride)/PEG (PEG-co-P(FA/SC)-co-PEG) were prepared and studied in aqueous solutions. TEM confirmed the formation of vesicles in aqueous media. Aggregation behavior of the copolymers was studied by fluorescence spectroscopy of 8-anilino-1-naphthalenesulfonic acid, and the critical aggregation concentration (c.a.c.) of the copolymer was found to be ${\sim}26.2{\mu}M$ indicating desirable stability of the vesicles. Dynamic light scattering revealed that the size of the vesicles was distributed within the range of 170-270 nm. Turbidity measurements confirmed the relative short-term stability of the polymersomes. Carboxyfluorescein, a hydrophilic compound, was simply encapsulated in the vesicles during polymersome preparation. The release of encapsulant from the polymersomes at 25 and $37^{\circ}C$ lasted about 3 weeks, and the rate of release followed a first-order kinetics. The release is speculated to be primarily carried out through diffusion. These results confirm that these polymersomes are promising as controlled-release carriers of various drugs.

Review of Basics Reverse Osmosis Process Modeling: A New Combined Fouling Index Proposed (역삼투 공정을 위한 모델링 총설 및 새로운 복합적 막오염도의 제안)

  • Kim, Albert S.
    • Membrane Journal
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    • v.27 no.4
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    • pp.291-312
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    • 2017
  • Seawater desalination is currently considered to be one of the primary technologies to resolve the global water scarcity problem. A basic understanding of membrane filtration phenomena is significant not only for further technological development but also for integrated design, optimal control, and long-term maintenance. In this vein, the present work reviews the major transport and filtration models, specifically related to reverse osmosis phenomena, provides theoretical insights based on statistical mechanics, and discusses model-based physical meanings as related to their practical implications.

Resistance to Corrosion of Reinforcement of High Volume Fly Ash Concrete

  • Kwon, S.O.;Bae, S.H.;Lee, H.J.;Lee, K.M.;Jung, S.H.
    • Corrosion Science and Technology
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    • v.13 no.6
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    • pp.209-213
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    • 2014
  • Due to the increasing of interest about the eco-friendly concrete, it is increased to use concretes containing by-products of industry such as fly ash(FA), ground granulated blast furnace slag(GGBFS), silica fume(SF), and etc. Especially, these are well known for improving the resistances to reinforcement corrosion in concrete and decreasing chloride ion penetration. The purpose of this experimental research is to evaluate the resistance against corrosion of reinforcement of high volume fly ash(HVFA) concrete which is replaced with high volume fly ash for cement volume. For this purpose, the concrete test specimens were made for various strength level and replacement ratio of FA, and then the compressive strength and diffusion coefficient for chloride ion of them were measured for 28, 91, and 182 days, respectively. Also, corrosion monitoring by half cell potential method was carried out for the made lollypop concrete test specimens to detect the time of corrosion initiation for reinforcement in concrete. As a result, it was observed from the test results that the compressive strength of HVFA concrete was decreased with increasing replacement ratio of FA but long-term resistances against reinforcement corrosion and chloride ion penetration of that were increased.

Two-Dimensional Numerical Simulation of Saltwater intrusion in Estuary with Sigma-Coordinate Transformation (연직좌표변환을 이용한 하구에서의 염수침투에 관한 2차원 수치모의)

  • Bae, Yong-Hoon;Park, Seong-Soo;Lee, Seung-Oh;Cho, Yong-Sik
    • Proceedings of the Korea Water Resources Association Conference
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    • 2007.05a
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    • pp.1263-1267
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    • 2007
  • A more complete two-dimensional vertical numerical model has been developed to describe the saltwater intrusion in an estuary. The model is based on the previous studies in order to obtain a better accuracy. The non-linear terms of the governing equations are analyzed and the $\sigma$-coordinate system is employed in the vertical direction with full transformation which is recently issued in several studies because numerical errors can be generated during the coordinate transformation of the diffusion term. The advection terms of the governing equations are discretized by an upwind scheme in second-order of accuracy. By employing an explicit scheme for the longitudinal direction and an implicit scheme for the vertical direction, the numerical model is free from the restriction of temporal step size caused by a relatively small grid ratio. In previous researches, some terms induced from the transformation have been intentionally excluded since they are asked the complicate discretization of the numerical model. However, the lack of these terms introduces significant errors during the numerical simulation of scalar transport problems, such as saltwater intrusion and sediment transport in an estuary. The numerical accuracy attributable to the full transformation is verified by comparing results with a previous model in a simply sloped topography. The numerical model is applied to the Han River estuary. Very reasonable agreements for salinity intrusion are observed.

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High Performance Wearable/Flexible Energy Storage Devices Based on Ultrathin $Ni(OH)_2$ Coated ZnO Nanowires

  • Shakir, Imran;Park, Jong-Jin;Kang, Dae-Joon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.597-597
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    • 2012
  • A simple solution-based method is developed to deposit crystalline ultrathin (2 nm) nickel hydroxide on vertically grown ZnO nanowires to achieve high specific capacitance and long-term life for flexible and wearable energy storage devices. Ultrathin crystalline $Ni(OH)_2$ enables fast and reversible redox reaction to improve the specific capacitance by utilizing maximum number of active sites for the redox reaction while vertically grown ZnO nanowires on wearable textile fiber effectively transport electrolytes and shorten the ion diffusion path. Under the highly flexible state $Ni(OH)_2$ coated ZnO nanowires electrode shows a high specific capacitance of 2150 F/g (based on pristine $Ni(OH)_2$ in 1 M LiOH aqueous solution with negligible decrease in specific capacitance after 1000 cycles. The synthesized energy-storage electrodes are easy-to-assemble which can provide unprecedented design ingenuity for a variety of wearable and flexible electronic devices.

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