• Title/Summary/Keyword: Differential reaction

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Reaction of Bacterial-Polyesters Containing Unsaturated Groups (불포화 기를 함유하는 미생물 폴리에스터의 반응)

  • Jung, Taek-Kyu;Kim, Young-Baek;Yim, Going;Cho, Sung-Joon;Youn, In-Kwon
    • The Journal of Engineering Research
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    • v.3 no.1
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    • pp.235-242
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    • 1998
  • Hydrosilylation and vromination of vacterial poly($\beta$-Hydroxyalkanoates) containing carbon-carbon double bond or triple bond were carried out. The produced polymers were characterized by IR-spectroscopy and differential scnning calorimetry. Hydrosilylated polymers were characterized crystallinity while brominated polymers had lower degree of crystallinity with increased glass transition temperatures. Mixing polymers containing carbon-carbon triple bonds with Co(II) AND Pt(II) resulted crosslinked polymers.

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Studies on the hematological and blood chemical findings for dry and lactating periods (건유(乾乳)와 필유(泌乳)에 따른 유우(乳牛)의 혈액(血液) 및 혈액화학상(血液化學像)의 변화에 관한 연구)

  • Kang, Chung-boo;Lee, Kuk-cheon;Lee, Soon-sun;Cho, Hee-taek;Ahn, Dong-won
    • Korean Journal of Veterinary Research
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    • v.29 no.4
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    • pp.437-443
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    • 1989
  • This experiment was carried out to investigate the hematological and blood chemical values in dairy cattle during the dry and lactating period. Blood was collected from six healthy dairy cattle in Gyeongnam province. Leucocytes count, hemoglobin concentrations and the percentage of packed cell volume were lowest at the early lactation period. Leucocytes count was not affected during dry the to lactating period. The differential count of eosinophilic leucocytes was low at the late lactation period, while the basophilic leucocytes was high at the dry period. Inorganic phosphorus value was below under normal level. Creatinine value was from 1 to 2mg/100ml of serum. Positive reaction to CRP was shown in normal dairy cattle. The values of AST and ALT were higher during the dry than lactating period. r-GTP and total cholesterol tend to be decreased during the lactating period. CPK value was not affected for dry and lactating period.

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Property of the HPHT Diamonds Using Stack Cell and Zn Coating with Pressure (적층형 셀과 아연도금층을 이용한 고온고압 합성다이아몬드의 압력변화에 따른 물성 연구)

  • Shen, Yun;Song, Oh-Sung
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.167-172
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    • 2012
  • Fine diamond powders are synthesized with a 420 ${\phi}$ cubic press and stack-cell composed of Kovar ($Fe_{54}Ni_{29}Co_{17}$) (or Kovar+7 ${\mu}m$-thick Zn electroplated) alloy and graphite disks. The high pressure high temperature (HPHT) process condition was executed at $1500^{\circ}C$ for 280 seconds by varying the nominal pressure of 5.7~10.6 GPa. The density of formation, size, shape, and phase of diamonds are determined by optical microscopy, field emission scanning electron microscopy, thermal gravimetric analysis-differential thermal ammnlysis (TGA-DTA), X-ray diffraction (XRD), and micro-Raman spectroscopy. Through the microscopy analyses, we found that 1.5 ${\mu}m$ super-fine tetrahedral diamonds were synthesized for Zn coated Kovar cell with whole range of pressure while ~3 ${\mu}m$ super-fine diamond for conventional Kovar cell with < 10.6 GPa. Based on $750^{\circ}C$ exothermic reaction of diamonds in TGA-DTA, and characteristic peaks of the diamonds in XRD and micro-Raman analysis, we could confirm that the diamonds were successfully formed with the whole pressure range in this research. Finally, we propose a new process for super-fine diamonds by lowering the pressure condition and employing Zn electroplated Kovar disks.

Induction of Lysozyme Gene Expression During Involution of Mouse Mammary Gland

  • Lee, M.J.;Han, O.;Back, K.;Choi, Y.J.;Baik, M.G.
    • Asian-Australasian Journal of Animal Sciences
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    • v.14 no.4
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    • pp.462-466
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    • 2001
  • To understand molecular mechanisms of mouse mammary gland involution, clones were isolated by differential screening of a cDNA library. Partial sequences of a clone showed 100% identity to cDNA sequences of mouse lysozyme P gene. Northern analysis was performed to examine expression levels of lysozyme mRNA in mammary gland at several physiological states. Expression of lysozyme gene was induced at involution day 5 compared with lactating stage. High levels of lysozyme mRNA were also detected at virgin tissues. Two types of separate genes, P and M lysozyme, have been known in mouse, and we found that both lysozyme P and M genes were expressed in mammary tissues by reverse transcriptase-polymerase chain reaction. The lysozyme enzyme activity determined by lysoplate assay was also higher in involuted mammary tissues compared with lactating tissues, showing a similar trend to its mRNA levels. Lysozyme is an antimicrobial protein and involved in host defense mechanism. The increase in lysozyme gene expression may help to prevent microbial infection during mammary gland involution at which stage the residual milk in the mammary gland provides good nutritional sources for microbial growth.

Solid Waste from Swine Wastewater as a Fuel Source for Heat Production

  • Park, Myung-Ho;Kumar, Sanjay;Ra, ChangSix
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.11
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    • pp.1627-1633
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    • 2012
  • This study was to evaluate the feasibility of recycling the solids separated from swine wastewater treatment process as a fuel source for heat production and to provide a data set on the gas emissions and combustion properties. Also, in this study, the heavy metals in ash content were analyzed for its possible use as a fertilizer. Proximate analysis of the solid recovered from the swine wastewater after flocculation with organic polymer showed high calorific (5,330.50 kcal/kg) and low moisture (15.38%) content, indicating that the solid separated from swine wastewater can be used as an alternative fuel source. CO and NOx emissions were found to increase with increasing temperature. Combustion efficiency of the solids was found to be stable (95 to 98%) with varied temperatures. Thermogravimetry (TG) and differential thermal analysis (DTA) showed five thermal effects (four exothermic and one endothermic), and these effects were distinguished in three stages, water evaporation, heterogeneous combustion of hydrocarbons and decomposition reaction. Based on the calorific value and combustion stability results, solid separated from swine manure can be used as an alternative source of fuel, however further research is still warranted regarding regulation of CO and NOx emissions. Furthermore, the heavy metal content in ash was below the legal limits required for its usage as fertilizer.

Clinical Effects of Preoperative treated-Methylprednisolone in Pediatric Cardiac Surgery with Cardiopulmonary Bypass

  • Choi Seok-Cheol;Kim Yang-Weon;Jang Jung Hoon
    • Biomedical Science Letters
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    • v.11 no.3
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    • pp.407-416
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    • 2005
  • Cardiopulmonary bypass (CPB) for cardiac surgery induces the production and release of numerous chemotactic substances and cytokines, ensuing systemic inflammatory response that causes postoperative major organ dysfunctions. We performed a randomized, prospective study to investigate clinical effects of preoperative treated-methylprednisolone for preventing inflammation in pediatric cardiac surgery with CPB. Thirty pediatric patients scheduled for elective cardiac surgery were randomized to either control(n=15) or steroid group (n=15, 10 mg/kg of methylprednisolone). Arterial blood samples were taken before and after the operations for measuring total leukocyte (T-WBC) and differential counts, platelet counts, interleukin-6 (IL-6), myeloperoxidase (MPO), neuron specific enolase (NSE), troponin-I (TNI), aspartate aminotransferase (AST), alanine aminotransferase (ALT), blood urea nitrogen (BUN), and creatinine levels. Postoperative parameters such as pulmonary index (PI, $PaO_2/FiO_2$), 24 hrs and total bleeding volumes, mechanical ventilating (MVP) and intensive care unit (ICU)-staying periods, and hospitalization were assessed. T-WBC, neutrophil fraction, IL-6, MPO, NSE, TNI, AST and creatinine levels, bleeding volumes, PI, and MVP at the postoperative periods were lower or shorter in steroid group than in control group (P<0.05). These findings indicated that preoperative administration of methylprednisolone attenuated CPB-induced inflammatory reactions, contributing to postoperative recovery of patients underwent cardiac surgery.

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Developing numerical method to predict the removal of Microcystin-LR in a clear well

  • Yeo, Inhee;Park, Yong-Gyun;Kim, Dooil
    • Membrane and Water Treatment
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    • v.9 no.3
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    • pp.173-179
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    • 2018
  • Microcystin-LR, one of algal toxins induced by the eutrophication of a reservoir, is known to be harmful to human by adversely affecting our liver and brain. Hypochlorous acid is very efficient to remove Microcystin-LR in a clear well. The previous researches showed that CT, pH and temperature affected removal rate in batch tests. It was noted that hydrodynamic properties of clear well could also influence its removal rate. A mathematical model was built using an axial dispersion reactor model and software was used to simulate the removal rate. The model consisted of the second order differential equations including dispersion, convection, Microcystin-LR reaction with chlorine. Kinetic constants were obtained through batch tests with chlorine. They were $0.430{\times}10^{-3}L/mg/sec$ and $0.143{\times}10^{-3}L/mg/sec$ for pH 7.0 and 8.1, respectively. The axial dispersion reactor model was shown to be useful for the numerical model through conservative tracer tests. The numerical model successfully estimated the removal rate of Microcyctin-LR in a clear well. Numerical simulations showed that a small dispersion number, low pH and long hydraulic retention time were critical for higher removal rate with same chlorine dosage. This model could be used to optimize the operation of a clear well during an eutrophication season.

Characterization for Pyrolysis of Thermoplastic Polyurethane by Thermal Analyses

  • Kang Suk-Hwan;Ku Dong-Cheol;Lim Jung-Hun;Yang Yun-Kyu;Kwak Noh-Seok;Hwang Taek-Sung
    • Macromolecular Research
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    • v.13 no.3
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    • pp.212-217
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    • 2005
  • The pyrolysis kinetics of polyurethanes synthesized from polycaprolactone diol (PCL) and diisocyanate (HDI, $H_{12}MDI$) using catalysts such as dibutyltin dilaurate (DBTDL) were studied by a thermogravimetric (TG) technique, which involved heating the sample at the rates of 10, 20 and $30^{\circ}C$/min. The effect of the kind of diisocyanate and the hard segment contents on the activation energy and reaction order were examined at conversions ranging from 1 to $100\%$. The activation energies at first increased slowly with increasing conversion. Also, differential scanning calorimetry (DSC) was used to investigate the structural differences in each polyurethane. DSC can reveal the melting behavior, in terms of the glass transition temperature ($T_g$), which is known to vary as a function of the stoichiometry and processing conditions.

Effect of Mechanical Alloying Atmosphere on Formation of AlN (AlN의 형성에 미치는 기계적 합금화 분위기의 영향)

  • Yu Seung-Hoon;Lee Young Sung;Shin Kwang-Seon
    • Journal of Powder Materials
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    • v.12 no.3
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    • pp.214-219
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    • 2005
  • In order to investigate the formation of AlN, mechanical alloying was carried out in $N_2$ and $NH_3$ atmosphere. Differential thermal analysis (DTA), x-ray diffraction (XRD) and chemical analysis were carried out to examine the formation behavior of aluminum nitrides. No diffraction pattern of AlN was observed in XRD analysis of the as-milled powders in $NH_3\;or\;N_2$ atmosphere. However, DTA and chemical analysis indicated that the precursors for AlN were formed in the Al powders milled in $NH_3$ atmosphere. The AlN precursors transformed to AlN after heat treatment at and above $600^{\circ}C$. It was considered that the reaction between Al and $NH_3$ was possible by the formation of fresh Al surface during mechanical alloying of Al powders.

Performance Evaluation of SCR System for Generator Engine on Training Ship KAYA (가야호 발전기용 SCR System의 성능 평가)

  • Jung, Suk-Ho;Jeong, Tae-Young;Hwang, Sung-Chul
    • Journal of Power System Engineering
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    • v.19 no.6
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    • pp.68-74
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    • 2015
  • NOx emission has been controlled because it is a major cause of the acid rain and effects considerably on formation and destruction of ozone. A SCR system on diesel engine is necessary to clear TierIII, because IMO(International Maritime Organization) plans on tightening regulations to TierIII at $1^{st}$ January 2016. In this study, flow analysis was accomplished with ANSYS Fluent program so that the SCR system would be retrofitted in training ship KAYA and the temperature distributions of exhaust gas in SCR sytem were investigated after it was installed. As a result, it was confirmed that pressure and velocity distributions in SCR system were depended on pipe line shapes, then it was designed as the pressure was lower. The temperature differential between 1 and 3 point was $15^{\circ}C$ because of evaporative latent heat of urea and the temperature of 4 point after catalyst was increased by $5^{\circ}C$ than 3 point because of exothermic reaction.