• Title/Summary/Keyword: Dielectric phenomena

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Dielectric passivation effects on the electromigration phenomena in Al-1%Si thin film interconnections (A1-1%Si 박막배선에서 엘렉트로마이그레이션 현상에 미치는 절연보호막 효과)

  • 김경수;김진영
    • Journal of the Korean Vacuum Society
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    • v.10 no.1
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    • pp.27-30
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    • 2001
  • Electromigration Phenomena in Al-1%Si thin film interconnections under DC and PDC conditions were investigated. Thin film interconnections with $SiO_2$ and PSG/$SiO_2$ dielectric passivation layer were formed by a standard photolithography process method and test line lengths were 100, 400, 800, 1200, and 1600 $\mu\textrm{m}$. The current density of $1.19\times10^7\textrm{A/cm}^2$ was stressed in Al-1%Si thin film interconnections under DC condition. The current density of $1.19\times10^7\textrm{A/cm}^2$ was also applied under PDC condition at the frequency of 1 Hz with the duty factor of 0.5. The electromigration resistance of PSG/SiO2 dielectric passivation test line was stronger than $SiO_2$ dielectric passivation test line. The lifetime under PDC was 2-4 times longer than DC condition. As the thin film interconnection line increased, the lifetime decreased and saturated over the critical length. Failure patterns by an electromigration were dominated by void-induced electrical open and hillock-induced electrical short.

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Dielectric Relaxation Time for Alkyl Chain of Phospolipid Organic Monolayers Film (인지질 유기단분자막의 알킬체인에 의한 유전완화시간)

  • Song, Jin-Won;Cho, Su-Young;Kim, Young-Keun;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04b
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    • pp.111-115
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    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed $\alpha$ and molecule area $A_m$ By according to the linear relationship relation get that frictional constant $\xi$, DLPC was $1.89{\times}10^{-19}$[Js] and DMPC was $0.722{\times}10^{-19}$[Js]. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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A Comparison of the Dielectric Behavior of Aromatic and Aliphatic Polyurethanes in Relation to Transitional Phenomena

  • Kim, Chy Hyung
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.211-216
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    • 2017
  • The dielectric properties of two polyurethanes (PUs) with different hard segments, i.e., aromatic methylene di-p-phenyl diisocyanate (MDI) and aliphatic hexamethylene diisocyanate (HDI), were investigated in the temperature range of -100 to $100^{\circ}C$ and in the frequency range of 1 Hz to 3 kHz. The ${\alpha}$-relaxations induced by the glass transition of the equivalent soft segments in the two PUs occurred at relaxation times of ${\tau}=3.46{\times}10^{-3}s$ for MDI-PU and ${\tau}=3.39{\times}10^{-2}s$ for HDI-PU at $-20^{\circ}C$, in accord with the temperature-frequency superposition principle, resulting in similar shifting factors. However, different I-relaxations were observed for the two PUs. The I-relaxation of MDI-PU occurred due to the mobility of the chain extenders near $80^{\circ}C$ with a slower shifting rate than the ${\alpha}$-relaxation. On the other hand, I-relaxation arising from both the extender and the unconstrained hard segments of HDI-PU occurred at $70{\sim}100^{\circ}C$, indicating complicated dielectric behavior due to partial interaction with the ${\alpha}$-relaxation at high frequencies. Thus, the I-relaxation of HDI-PU did not follow the superposition principle. The dielectric behaviors of the PUs were mainly influenced by their phase transitions, which were affected by the structure and components of the materials.

Cryogenic Insulation Technique for HTS Transformer (고온초전도 변압기용 극저온 절연기술)

  • Kim, Sang-Hyun;Cheon, Hyeon-Gweon
    • Progress in Superconductivity and Cryogenics
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    • v.8 no.1
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    • pp.45-48
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    • 2006
  • In the response to the demand for electrical energy , much effort was given to develop and commercialize high temperature superconducting (HTS) power equipments has been made around the world. Especially, HTS transformer is one of the most promising devices . but the cryogenic insulation technology should be established during development Hence many types of dielectric tests should be carried out to understand the dielectric phenomena at cryogenic temperature and to gather various dielectric data. Among the many types dielectric tests . the characteristic of barrier effect were conducted using simulated electrode after analysing the insulating configuration of HTS transformer main winding. The influence of a barrier on the dielectric strength was measured according to the position of the harriet the number of the barrier and thickness or the barrier. It was shown that the effectiveness . namely the ratio of the breakdown voltage in presence of barrier to the voltage without barrier, is highest when the barrier is placed at the needle electrode side. On the contrary, in the case of having the barrier between the electrodes, the harrier was placed between the electrodes the characteristic was even improved slightly.

A study on Dielectric Properties using PMN Ceramics with La substitution (La치환된 PMN계 세라믹스의 유전특성에 관한 연구)

  • Ji, S.H.;Lee, N.H.;Kim, Y.H.;Kim, J.S.;Lee, D.C.
    • Proceedings of the KIEE Conference
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    • 1995.07c
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    • pp.1242-1244
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    • 1995
  • The dielectric and polarizable properties of $0.9Pb_{1-x}La_x({Mg}_{1/3}Nb_{2/3})O_3-0.1PbTiO_3$ (x=0,1,2,3,4,5) have been investigated. The temperature-dependant electrostictive characteristics of 0.9PMN-0.1PT relaxor ferroelectric system were improved by enhencing the extent of the diffuse phase transition(DPT). This was achieved using PMN-PTceramics by the partial substitution of La at the Pb site. The curie temperature and the maximum dielectric permittivity decreased by substituting La and the electric field-related hysteresis phenomena decreased with increasing La substitution amount.

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The Dielectric and Piezoelectric Properties of (Pb1-1.5xLax)(Ti1-yMny) System ((Pb1-1.5xLax)(Ti1-yMny)O3계의 유전 및 압전성질)

  • 맹성재;정형진
    • Journal of the Korean Ceramic Society
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    • v.25 no.4
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    • pp.321-328
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    • 1988
  • The sintering phenomena, electrical resistivity, dielectric and piezoelectric properties of lead titanate ceramics modified by the partial substitution of La for Pb and Mn for Ti, (Pb1-1.5xLax)(Ti1-yMny)O3 ceramics, have been investigated. In (Pb1-1.5xLax)(Ti1-yMny)O3 system, with increasing lanthanum content, the realtive bulk density increased, but the Curie point and tetragonality (c/a) decreased. The tetragonal-to-cubic phase transition boundary existed in the range of 0.20

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Linear Dielectric Relaxations in Copolymers of Vinylidence Cyanide (VDCN계(系) 공중합체(共重合體)의 선형(線刑) 유전특성(誘電特性))

  • Kang, Dae-Ha;Lee, Duck-Chool
    • Proceedings of the KIEE Conference
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    • 1988.11a
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    • pp.186-188
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    • 1988
  • Relaxation spectra of the linear dielectric constants $\varepsilon=\varepsilon'-j{\varepsilon}"$ have been measured as functions of temperature and frequency for alternating copolymers of vinylidene cyanide (VDCN/VAc, VDCN/VPr, VDCN/VBz and VDCN/St) It is found that the linear dielectric constants e show characteristics of the temperature dependence that the real part have a large peak related to the glass transition point(Tg), and of the frequency dependence that the real port increases with decreasing frequency and the imaginary part increases largely in low frequency range. These phenomena mean Debye-type relaxation due to the micro-Brownian moi ions of non-crystalline seqments.

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Relaxation and Freezing in Pb-based Relaxer Ferroelectrics (Pb계 완화형 강유전체에서의 relaxation 및 freezing거동)

  • 박재환;김윤호;박재관
    • Korean Journal of Crystallography
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    • v.12 no.3
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    • pp.157-161
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    • 2001
  • The observe relaxation phenomena and freezing behavior in Pb(Mg/sub ⅓/Nb/sub ⅔/O₃, relaxor ferroelectrics, weak electric-field properties as well as strong electric-field properties were investigated. The temperature dependence of the dielectric properties obtained using the low electric-field of 1 V/w was investigated. The dielectric properties obtained from the slope of the dielectric hysteresis loop and the temperature dependence of the pyroelectric properties were also investigated. When fitting all the experimental data with the Vogel-Filcher relation, a close agreement between the experimental data and equation was observed. The freezing temperature could be consistently calculated by the various methods.

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Environmentally Assisted Cracking of Alloys at Temperatures near and above the Critical Temperature of Water

  • Watanabe, Yutaka
    • Corrosion Science and Technology
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    • v.7 no.4
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    • pp.237-242
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    • 2008
  • Physical properties of water, such as dielectric constant and ionic product, significantly vary with the density of water. In the supercritical conditions, since density of water widely varies with pressure, pressure has a strong influence on physical properties of water. Dielectric constant represents a character of water as a solvent, which determines solubility of an inorganic compound including metal oxides. Dissociation equilibrium of an acid is also strongly dependent on water density. Dissociation constant of acid rises with increased density of water, resulting in drop of pH. Density of water and the density-related physical properties of water, therefore, are the major governing factors of corrosion and environmentally assisted cracking of metals in supercritical aqueous solutions. This paper discusses importance of "physical properties of water" in understanding corrosion and cracking behavior of alloys in supercritical water environments, based on experimental data and estimated solubility of metal oxides. It has been pointed out that the water density can have significant effects on stress corrosion cracking (SCC) susceptibility of metals in supercritical water, when dissolution of metal plays the key role in the cracking phenomena.

Dielectric Characteristics of Subcooled $LN_2$ for Insulation Design of HTS Fault Current Limiters (고온초전도 한류기의 절연설계를 위한 과냉각 액체질소의 절연내력 특성)

  • 백승명;정종만;김상현
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.2
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    • pp.46-50
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    • 2003
  • In the dielectric insulation design of any high temperature superconducting (HTS) apparatus as well as HTS fault current limiter in the electrical power systems, the breakdown characteristics of cryogenic coolants such as liquid nitrogen ($LN_2$) are an important factor of the insulating engineering. Previous reports concerned with the breakdown characteristics of liquid nitrogen have pointed out that bubbles and gaseous nitrogen have a treat influence on their breakdown phenomena, However, useful data for practical insulation design of HTS fault CUITent limiter operating at subcooled L$N_2$ have not been obtained enough. Therefore, this paper presents an experimental investigate of breakdown phenomena in liquid nitrogen under AC voltage, And, we observed the breakdown voltage (BDV) of liquid nitrogen with lowering temperature. The Weibull plots of the breakdown voltage of subcooled $LN_2$ for the needle-plane electrode with d= 10 mm are studied, The dependence of breakdown voltage for needle-plane and pancake coil-pancake coil electrode on temperature is illustrated, The relationship between the AC breakdown characteristics and the temperature were clarified.