• Title/Summary/Keyword: Determination technology

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Determination of mandipropamid residues in agricultural commodities using high-performance liquid chromatography with mass spectrometry (고성능액체크로마토그래피를 이용한 농산물 중 Mandipropamid의 잔류분석법 확립)

  • Kwon, Chan Hyeok;Chang, Moon Ik;Im, Moo Hyeog;Choi, Hoon;Jung, Da I;Lee, Su Chan;Yu, Jin Young;Lee, Young Deuk;Lee, Jong Ok;Hong, Moo Ki
    • Analytical Science and Technology
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    • v.21 no.6
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    • pp.518-525
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    • 2008
  • Mandipropamid is a new mandelamide-type fungicide to control foliar Oomycete pathogens in some vegetables. An analytical method was developed to determine mandipropamid residues in agricultural commodities using high-performance liquid chromatography (HPLC) and liquid chromatography/mass spectrometry (LC/MS). Mandipropamid was extracted with methanol from grape, tomato, green pepper, Chinese cabbage and potato samples. The extract was diluted with saturated sodium chloride solution and distilled water, and dichloromethane partition was followed to recover the mandipropamid from the aqueous phase. Florisil column chromatography was employed to further remove interfering co-extractives prior to HPLC analysis. Reverse-phased HPLC was successfully applied to determine mandipropamid in sample extracts with the detection at its ${\lambda}_{max}$ (223 nm). Overall recoveries of mandipropamid from fortified samples averaged $99.8{\pm}1.7$ (n=6), $89.3{\pm}5.3$ (n=6), $98.7{\pm}2.2$ (n=6), $99.7{\pm}6.8$ (n=6) and $91.1{\pm}3.1$ (n=6) for grape, tomato, green pepper, Chinese cabbage and potato, respectively. Limit of quantification of the method was 0.02~0.04 mg/kg for all samples. A LC/mass spectrometry with selected-ion monitoring was also provided to confirm the suspected residue. The proposed method was reproducible and sensitive enough to determine the terminal residue of mandipropamid in agricultural commodities.

Extraction of Snowmelt Parameters using NOAA AVHRR and GIS Technique for 7 Major Dam Watersheds in South Korea (NOAA AVHRR 영상 및 GIS 기법을 이용한 국내 주요 7개 댐 유역의 융설 매개변수 추출)

  • Shin, Hyung Jin;Kim, Seong Joon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.2B
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    • pp.177-185
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    • 2008
  • Accurate monitoring of snow cover is a key component for studying climate and global as well as for daily weather forecasting and snowmelt runoff modelling. The few observed data related to snowmelt was the major cause of difficulty in extracting snowmelt factors such as snow cover area, snow depth and depletion curve. Remote sensing technology is very effective to observe a wide area. Although many researchers have used remote sensing for snow observation, there were a few discussions on the characteristics of spatial and temporal variation. Snow cover maps were derived from NOAA AVHRR images for the winter seasons from 1997 to 2006. Distributed snow depth was mapped by overlapping between snow cover maps and interpolated snowfall maps from 69 meteorological observation stations. Model parameters (Snow Cover Area: SCA, snow depth, Snow cover Depletion Curve: SDC) were built for 7 major watersheds in South Korea. The decrease pattern of SCA for time (day) was expressed as exponentially decay function, and the determination coefficient was ranged from 0.46 to 0.88. The SCA decreased 70% to 100% from the maximum SCA when 10 days passed.

Development of a Practical Algorithm for en-route distance calculation (항로거리 산출을 위한 실용 알고리즘 개발)

  • GeonHwan Park;HyeJin Hong;JaeWoo Park;SungKwan Ku
    • Journal of Advanced Navigation Technology
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    • v.26 no.6
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    • pp.434-440
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    • 2022
  • The ICAO (International civil aviation organization)recommended the implementation of the GANP (global air navigation plan) for strategic decision-making and air traffic management evaluation. In this study, we proposed a new method for finding the route distance from KPI (key performance indicator) 05 actual route extension presented for air traffic management evaluation. For this purpose, we collected trajectory data for one month and calculated the en-route distances using the methods presented in ICAO and the methods presented by this author. In the ICAO method, the intersection point must be estimated through the equation of a circle for radius 40 NM and the equation of a straight line for an inner and outer point close to a circle in the track data, and four flight distances are calculated to calculate the en-route distance. In the method presented in this study, two flight distances are calculated without estimating the intersection point to calculate the en-route distance. To determine the error between the two methods, we used the performance evaluation index RMSE (root mean square error) and the determination factor R2 of the regression model.

Restoration of Missing Data in Satellite-Observed Sea Surface Temperature using Deep Learning Techniques (딥러닝 기법을 활용한 위성 관측 해수면 온도 자료의 결측부 복원에 관한 연구)

  • Won-Been Park;Heung-Bae Choi;Myeong-Soo Han;Ho-Sik Um;Yong-Sik Song
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.6
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    • pp.536-542
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    • 2023
  • Satellites represent cutting-edge technology, of ering significant advantages in spatial and temporal observations. National agencies worldwide harness satellite data to respond to marine accidents and analyze ocean fluctuations effectively. However, challenges arise with high-resolution satellite-based sea surface temperature data (Operational Sea Surface Temperature and Sea Ice Analysis, OSTIA), where gaps or empty areas may occur due to satellite instrumentation, geographical errors, and cloud cover. These issues can take several hours to rectify. This study addressed the issue of missing OSTIA data by employing LaMa, the latest deep learning-based algorithm. We evaluated its performance by comparing it to three existing image processing techniques. The results of this evaluation, using the coefficient of determination (R2) and mean absolute error (MAE) values, demonstrated the superior performance of the LaMa algorithm. It consistently achieved R2 values of 0.9 or higher and kept MAE values under 0.5 ℃ or less. This outperformed the traditional methods, including bilinear interpolation, bicubic interpolation, and DeepFill v1 techniques. We plan to evaluate the feasibility of integrating the LaMa technique into an operational satellite data provision system.

A study on the development of hydrocortisone certified reference material in cosmetic cream using isotope dilution-mass spectrometry (동위원소희석-질량분석법을 이용한 화장품 크림 중 히드로코르티손 인증표준물질 개발 연구)

  • Chae-Hong Lee;Ji-Sun Huh;Eun-Ji Jeong;Hyun-Ah Kim;Min-Young Eom
    • Analytical Science and Technology
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    • v.37 no.3
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    • pp.166-173
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    • 2024
  • Steroids have a temporary skin improvement and whitening effect by controlling vasodilation, but they also cause side effects when used for a long time. Therefore, steroids were designated and managed as raw materials that cannot be used in cosmetics in Korea. However, steroids are continuously being detected in cosmetics, causing social issues. In this study, we developed a certified reference material (CRM) for the determination of steroids such as hydrocortisone in cosmetics. A cream-type cosmetic CRM was manufactured and subsequently certified following the guidelines outlined in ISO Guide 35. Homogeneity, short-term stability, and long-term stability were evaluated using isotope dilution mass spectrometry (ID-MS). The certified values were determined by using NIST's primary reference material to ensure traceability. From now on, we intend to supply the certified reference material as a cosmetic CRM to national and international companies, as well as research institutes after certification as certified reference material from KOLAS and registering on COMAR.

A Foundational Study on Developing a Structural Model for AI-based Sentencing Prediciton Based on Violent Crime Judgment (인공지능기술 적용을 위한 강력범죄 판결문 기반 양형 예측 구조모델 개발 기초 연구)

  • Woongil Park;Eunbi Cho;Jeong-Hyeon Chang;Joo-chang Kim
    • Journal of Internet Computing and Services
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    • v.25 no.1
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    • pp.91-98
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    • 2024
  • With the advancement of ICT (Information and Communication Technology), searching for judgments through the internet has become increasingly convenient. However, predicting sentencing based on judgments remains a challenging task for individuals. This is because sentencing involves a complex process of applying aggravating and mitigating factors within the framework of legal provisions, and it often depends on the subjective judgment of the judge. Therefore, this research aimed to develop a model for predicting sentencing using artificial intelligence by focusing on structuring the data from judgments, making it suitable for AI applications. Through theoretical and statistical analysis of previous studies, we identified variables with high explanatory power for predicting sentencing. Additionally, by analyzing 50 legal judgments related to serious crimes that are publicly available, we presented a framework for extracting essential information from judgments. This framework encompasses basic case information, sentencing details, reasons for sentencing, the reasons for the determination of the sentence, as well as information about offenders, victims, and accomplices evident within the specific content of the judgments. This research is expected to contribute to the development of artificial intelligence technologies in the field of law in the future.

Full-waveform Inversion of Ground-penetrating Radar Data for Deterioration Assessment of Reinforced Concrete Bridge (철근 콘크리트 교량의 열화 평가를 위한 지표투과레이더 자료의 완전파형역산)

  • Youngdon Ahn;Yongkyu Choi;Hannuree Jang;Dongkweon Lee;Hangilro Jang;Changsoo Shin
    • Journal of the Korean GEO-environmental Society
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    • v.25 no.2
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    • pp.5-14
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    • 2024
  • Reinforced concrete bridge decks are the first to be damaged by vehicle loads and rain infiltration. Concrete deterioration primarily occurs owing to the corrosion of rebars and other metal components by chlorides used for snow and ice melting. The structural condition and concrete deterioration of the bridge decks within the pavement were evaluated using ground-penetrating radar (GPR) survey data. To evaluate concrete deterioration in bridges, it is necessary to develop GPR data analysis techniques to accurately identify deteriorated locations and rebar positions. GPR exploration involves the acquisition of reflection and diffraction wave signals due to differences in radar wave propagation velocity in geotechnical media. Therefore, a full-waveform inversion (FWI) method was developed to evaluate the deterioration of reinforced concrete bridge decks by estimating the radar wave propagation velocity in geotechnical media using GPR data. Numerical experiments using a GPR velocity model confirmed the deterioration phenomena of bridge decks, such as concrete delamination and rebar corrosion, verifying the applicability of the developed technology. Moreover, using the synthetic GPR data, FWI facilitates the determination of rebar positions and concrete deterioration locations using inverted velocity images.

Evaluation of radioactivity and radiological parameters in soil samples in Isparta, Türkiye

  • Mehmet Ertan Kurkcuoglu;Fatih Caglar Kahraman;Serdar Dizman;Gulcin Bilgici Cengiz
    • Nuclear Engineering and Technology
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    • v.56 no.10
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    • pp.4007-4017
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    • 2024
  • In the city centre of Isparta, located in the southwestern part of Türkiye, indoor radon concentrations and gamma dose rate levels were observed above the world and country averages. For this reason, the determination of the natural radioactivity levels in soil samples of Isparta province is of great interest. In the present study, the activity concentrations of radionuclides (namely 226Ra,232Th, 40K and 137Cs) were investigated in the soil samples collected from 72 different points including the city centre and 12 towns of Isparta by using a gamma spectrometer with a high-purity germanium (HPGe) detector. The activity concentrations of 226Ra,232Th, 40K and 137Cs radionuclides in the samples were found in the range of 4.08 ± 0.39-69.84 ± 1.43 Bqkg-1, 2.63 ± 0.28-65.66 ± 1.41 Bqkg-1, 44.48 ± 3.17-452.38 ± 9.65 Bqkg-1 and 0.28 ± 0.18-19.10 ± 0.61 Bqkg-1 respectively. The averages of all the measurements were determined as 15.69 ± 0.72 Bqkg-1 for 226Ra, 15.40 ± 0.78 Bqkg-1 for 232Th, 210.60 ± 6.22 Bqkg-1 for 40K and 3.44 ± 0.31 Bqkg-1 for 137Cs. Although these values were below the country and world averages, it was revealed that the 226Ra and 232Th activity concentrations in the city centre exceeded the national and world averages. In addition, radiological risk maps of the analysed radionuclides were produced for the first time, covering all towns within the Isparta province. To evaluate the radiological hazards resulting from natural radionuclides, external hazard index (Hex), absorbed dose rate (D), annual effective dose equivalent (AEDE), male and female lifetime cancer risk (LCR) values were also calculated. The outcomes of this study revealed that all the radiological parameter averages for Isparta were lower than the world and country averages but the calculation results for the city centre displayed the opposite of this situation except for the external hazard index.

Development Model of the Foxglove Aphid, Aulacorthum solani (Kaltenbach) on Lettuce (상추에서의 싸리수염진딧물(Aulacorthum solani)의 발육과 발육모형)

  • Lee, Sang-Guei;Kim, Hyeong-Hwan;Kim, Tae-Heung;Park, Gil-Jun;Kim, Kwang-Ho;Kim, Ji-Soo
    • Korean journal of applied entomology
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    • v.47 no.4
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    • pp.359-364
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    • 2008
  • The development of Aulacorthum solani (Kaltenbach) was studied at temperatures ranging from 12.5 to $27.5^{\circ}C$ under $65{\pm}5%$ RH, and a photoperiod of 16:8 (L:D). Mortality of $1st{\sim}2nd$ nymph was higher than that of $3rd{\sim}4th$ nymph at the most temperature ranges whereas at high temperature of $27.5^{\circ}C$, more $3{\sim}4th$ nymph stage individuals died. The total developmental time ranged from 16.9 days at $12.5^{\circ}C$ to 6.6days at $22.5^{\circ}C$, suggesting that higher the temperature, faster the development. However, at higher temperature of $25^{\circ}C$ the development took 7.4 days. The lower developmental threshold temperature and effective accumulative temperatures for the total immature stage were $0.08^{\circ}C$ and 162.8 day-degreeslated development. The nonlinear shape of temperature rewas well described by the modified Sharpe and DeMichele model. When the normalized cumulative frequency distributions of developmental times for each life stage were fitted to the three-parameter Weibull function, attendance of shortened developmental times was apparent with in $1{\sim}2nd$ nymph, $3{\sim}4th$ nymph, and total nymph stages in descending order. The coefficient of determination $r^2$ ranged between 0.86 and 0.91.

Determination of β-Carotene and Retinol in Korean Noodles and Bread Products (가공 및 외식식품 중 면류 및 제빵류의 레티놀 및 베타카로틴 함량 조사)

  • Shin, Jung-Ah;Chun, Ji Yeon;Lee, Junsoo;Shin, Ki Yong;Lee, Soon Kyu;Lee, Ki-Teak
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.12
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    • pp.1949-1957
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    • 2013
  • The contents of ${\beta}$-carotene and retinol in processed and restaurant foods, such as Korean noodles, mandus, rice cakes and bread products, were quantified by high-performance liquid chromatography (HPLC) with UV/visible and fluorescence detector, respectively. Samples were collected from different local areas (i.e. Gangwon-do, Gyeonggi-do, Gyeongsang-do, Seoul, Jeolla-do, and Chungcheong-do). After homogenization, samples were hydrolyzed by direct alkali saponification; thereafter, fat-soluble components were extracted by a mixture of n-hexane/ethylacetate (85:15, v/v), containing 0.01% butylated hydroxytoluene (BHT). ${\beta}$-carotene and retinol contents in infant formula used as an in-house material for the analytical quality control. Among 14 Korean noodles, high contents of ${\beta}$-carotene were found in Bibim-Guksu (average 442.43 ${\mu}g/100g$) and Jjolmyeon (average 301.39 ${\mu}g/100g$). In 4 Korean mandus, the highest contents of ${\beta}$-carotene was determined in Kimchi-mandu (average 197.64 ${\mu}g/100g$), resulting in 33.3 RE of the converted vitamin A. Among 12 Korean rice cakes, Maeun-Tteokbokki and Modm-Chaltteok contained relatively high content of ${\beta}$-carotene with 205.11 and 41.33 ${\mu}g/100g$, respectively, while retinol was detected only in Maeun- Tteokbokki (1.65~10.45 ${\mu}g/100g$). In addition, among 8 bread products, 77.3 RE of pastry, 51.2 RE of buttercream- bread, and 41.4 RE of morning roll were found as the contents of the converted vitamin A.