• Bulletin of the Korean Chemical Society
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• v.20 no.3
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• pp.352-354
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• 1999

The spectrophotometric determination of Cu(Ⅱ) with α-(2-benzimidazolyl)-α',α"-(N-5-nitro-2-pyridylhydrazone)-toluene has been investigated. The optimum conditions of pH, stability, concentration of ligand and surfactant were evaluated. This method is a simple and sensitive method for determination of Cu(Ⅱ) and offers a selective separation of Cu(Ⅱ) from sample solution containin- I ppm below amount of Ni(Ⅱ), Co(Ⅱ), Zn(Ⅱ) and Sn(Ⅱ). Copper was determined by measuring the absorbance of Cu(Ⅱ)-BINPHT complex extracted with benzene in Brij 58 surfactant at 410 nm. Beer's law is obeyed over the concentration range 0∼2.5 μgmL-1 and the detection limit (S/N=2) is 0.06 μgmL-1. The relative standard deviation at the 0.3 μgmL-1 is 2.4% (N=7). The method was applied for the determination of Cu(Ⅱ) in various milks.

• Korean Journal of Biological Psychiatry
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• v.7 no.2
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• pp.180-185
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• 2000

Objective : The present study was designed to compare Global Field Power Measurement and conventional method in P300 determination. Method : The subjects were composed of patients(N=20) with schizophrenia by DSM-IV and normal controls(N=20). The auditory event related potential P300 was measured by "oddball paradigm". P300 components were determined by Global Field Power Measurement and conventional method at 5 electrodes(Fz, Cz, Pz, $T_3$, $T_4$). Results : P300 amplitudes of patients were smaller than those of controls across all electrodes and in both methods, but there was no differential power in P300 determination between two methods. Asymmetry of auditory event-related potential P300 was not shown between patients with schizophrenia and normal controls. Conclusion : It is implicated that it depends on clinical situations and research purposes what method of P300 determination will be more appropriate for patients with schizophernia.

• YAKHAK HOEJI
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• v.28 no.6
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• pp.321-325
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• 1984

A HPLC determination method of xanthinol nicotinate(I) was developed for study of its stability and characteristics in solutions. I was determined using an ${\mu}-Bondapak\;C_{18}$ column with a mobile phase of methanol: $H_2O$ (1 : 1) and UV absorbance detection at 254nm. The results revealed that the method was enough to use as stability indicating determination with the mean of 99.9% and standard deviation of ${\pm}1.42%$ when analyzed 10 times for standard solution.

• 제어로봇시스템학회:학술대회논문집
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• 2001.10a
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• pp.167.5-167
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• 2001

Single point attitude determination method provides an optimal attitude minimizing the Wahba loss function. However, for the insufficient number of measurement vectors, the conventional single point methods has no unique solution. Thus, we introduce the sequential method to and an optimal attitude minimizing the windowed loss function. In this paper, this function is de ned as the sum of square errors for all measurement vectors within the axed sliding window. For simple implementation, the proposed algorithm is rewritten as a recursive form. Moreover, the covariance matrix is derived and expressed as a recursive form. Finally, we apply this algorithm to the attitude determination system with three LOS measurement sensors.

• Journal of Korean Society of Industrial and Systems Engineering
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• v.14 no.24
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• pp.163-168
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• 1991

In the FMS design, the important points are the selection of parts and the determination of configuration. The common approach method which solve the selection of parts are the determination of configuration has improved that the two points are simultaneously. This study finds the best method which parts combination and configuration are satisfied at the same time. And the optimal replace time of equipment under limited budget on the view Point of engineering. economy.

• YAKHAK HOEJI
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• v.5 no.1
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• pp.24-26
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• 1960

Micro-determination of Lead by Dithizone Method was studied as follows: 1) Max. absorption wave length of Dithizone-pb complex in CC $l_{4}$ soln. is 510m.mu., 2) at the range of 5.gamma.-120.gamma. pb content, Bourguer-Beer's law hold good, 3) co-existence of F $e^{++}$ Z $n^{++}$, and C $u^{++}$ interfere.rfere.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.6
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• pp.587-594
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• 2008

In this paper, an efficient integer ambiguity resolution method for GNSS attitude determination system is described. The proposed method solves the integer least-squares with quadratic equality constraints(ILSQE) problem and shows an expansion of the LAMBDA method can be used to solve it. The solution of ILSQE is shown and an efficient implementation with a LAMBDA based method is given. The method is compared with some other methods. The results of static and dynamic tests show the dramatic improvement of the success rates of integer ambiguity resolution.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.2 no.1
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• pp.77-85
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• 2004

Regulations and guidelines for radioactive waste disposal require detailed information about the characteristics of radioactive waste drums prior to transport to the disposal sites. However, estimation of radionuclide concentrations in the drummed radioactive waste is difficult and unreliable. In order to overcome this difficulty, scaling factor (SF) method has been used to assess the activities of radionuclides, which could not be directly analyzed. A radioactive waste assay system has been operated at Korean nuclear power plant (KORI site) since 1996 and consolidated SF concept has played a dominant role in the determination of radionuclide concentrations. However, SFs are somewhat dispersive and limited in KORI site. Therefore establishment of the assay system using more improved SFs is planned and progressed. In this paper, the scope of research is briefly introduced. For the selection of more reliable activity determination method, the accuracy of predicted SF values for each activity determination method is compared. From the comparison of each activity determination method, it is recommended that SF determination method should be changed from the arithmetic mean to the geometrical mean for more reliable estimation of radionuclide activity. Arithmetic mean method and geometric mean method are compared based on the data set in KORI system. And, this change of SF determination method will prevent an inordinate over-estimation of radionuclide inventory in radwaste drum.

• Bulletin of the Korean Chemical Society
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• v.27 no.6
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• pp.863-868
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• 2006

The partial least squares (PLS-1) calibration model based on spectrophotometric measurement, for the simultaneous determination of sulfite and sulfide is described. This method is based on the difference between the rate of the reaction of sulfide and sulfite with Malachite Green in pH 7.0 buffer solution and at 25 ${^{\circ}C}$. The absorption kinetic profiles of the solutions were monitored by measuring the decrease in the absorbance of Malachite Green at 617 nm in the time range 10-180 s after initiation of the reactions with 2 s intervals. The experimental calibration matrix for partial least squares (PLS-1) calibration was designed with 24 samples. The cross-validation method was used for selecting the number of factors. The results showed that simultaneous determination could be performed in the range 0.030-1.5 and 0.030-1.2 $\mu$g m$L ^{-1}$ for sulfite and sulfide, respectively. The proposed method was successfully applied to simultaneous determination of sulfite and sulfide in water samples and whole human blood.

• YAKHAK HOEJI
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• v.28 no.2
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• pp.61-67
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• 1984

A method is described for the spectrophotometric determination of platinum (IV) with 2-oximino-1-indanone based on solvent extraction of Pt:2-oximino-1-indanone complex. The 2-oximino-1-indanone reacted with Pt(IV) to form a dark-orange complex which shows a characterisic maximum absorption at 342nm. The optimum PH for the platinum extraction lies between 5.4~8.0. Beer's law obeys up to 0.98-16.3ppm of platinum (IV) and the molar absorption coefficient is $1.06{\times}10^{-4}L.mol^{-1}.cm^{-1}$. The relative standard deviation of the method was $\times2.1%$. The composition of the complex is estimated to be Pt : In= 1 : 1, by the mole ratio method and ion exchange resin experiment. The optimum condition for the determination of platinum has been studied in detail. The 2-oximin-1-indanone is found to be a selectivereagent for the determination of platinum, since the synthesixed 2-oximino-1-indanone did not react with other metals such as cobalt, cadmium, copper, manganese nickel, iron, lead and zinc, to form the complex. In this studies, we have also clarified Sindhwani and Singh's spectrophotometric determination data of various metals with acenaphthenequinone monooxime (Talanta 20,248, 1973), whose results were not correct.