• Title/Summary/Keyword: Deposition reduction

검색결과 487건 처리시간 0.026초

부가증착을 이용한 마이크로 구멍의 크기감소 (Size reduction of micro-aperture using additional deposition)

  • 이준석;김규만
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.505-506
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    • 2006
  • Size reduction of micro-aperture using additional deposition is presented in this study. PECVD process was used for additional deposition. Rate of deposition is different with deposition direction because corners of shadowmask membrane have a taper. Deposition into backside showed better than deposition into frontside with size reduction. Shadowmask membrane with two materials has stress because of the difference of a coefficient of thermal expansion The cantilever of membrane bend to opposite direction of deposition. Deposition to both frontside and backside could reduce inside stress.

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매체순환식 가스연소기용 산소공여입자들의 연료별 연소특성 (Reduction Characteristics of Oxygen Carrier Particles for Chemical-looping Combustor with Different Fuels)

  • 류호정;김경수;박영성;박문희
    • 한국수소및신에너지학회논문집
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    • 제20권1호
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    • pp.45-54
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    • 2009
  • Reduction reactivity and carbon deposition characteristics of three oxygen carrier particles(OCN01, OCN02, OCN03) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all particles, the maximum conversion, the oxygen transfer capacity, and the degree of carbon deposition increased as the reactive carbon contents increased. The reduction rate and the oxygen transfer rate increased as the moles of required oxygen per input gas increased. The change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels can be explained consistently by using parameters such as the reactive carbon contents and the moles of require oxygen per input gas.

침적침전법에 의해 제조된 Cu-Mn 촉매의 활성 및 특성 (Activity and Characteristics of Cu-Mn Oxide Catalyst Prepared by the Deposition-Precipitation Method)

  • 김혜진;최성우;이창섭
    • 한국대기환경학회지
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    • 제22권3호
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    • pp.373-381
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    • 2006
  • The catalytic combustion of toluene was investigated on the Cu-Mn oxide catalysts prepared by the deposition-precipitation method. Experiment of toluene combustion was performed with a fixed bed flow reactor in the temperature range of $100{\sim}280^{\circ}C$. Among the catalysts, 1.29Cu/Mn showed the most activity at $260^{\circ}C$. The deposition-precipitation method may be showed the potential to enhance the activity of catalysts. The catalysts were characterized by BET, scanning electron microscopy (SEM), temperature-programmed reduction (TPR), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) techniques. On the basis of catalyst characterization data, the results showed that the surface of catalysts by deposition-precipitation method had uniform distribution and smaller particle size, which enhanced the reduction capability of catalysts. The XRD results showed that $Cu_{1.5}Mn_{1.5}O_{4}$ spinel phase was made by deposition-precipitation method, and increased catalyst activity and redox characteristic. It was assumed that the reduction step of $Cu_{1.5}Mn_{1.5}O_{4}$ spinel phase progressed $Cu_{1.5}Mn_{1.5}O_{4}\;to\;CuMnO_{2},\;and\;Cu_{2}O\;to\;CuMn_{2}O_{4}\;and\;Cu$.

증착 중 자외광 노광에 의한 산화 아연 박막의 특성 변화 (The Effect of in situ Ultraviolet Irradiation on the Chemical Vapor Deposited ZnO Thin Films)

  • 김보석;백승재
    • 한국전기전자재료학회논문지
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    • 제29권4호
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    • pp.241-246
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    • 2016
  • ZnO thin films have wide application areas due to its versatile properties as transparent conductors, wide-bandgap n-type semiconductors, gas sensor materials, and etc. We have performed a systematic investigation on ultraviolet-assisted CVD (chemical vapor deposition) method. Ultraviolet irradiation during the deposition of ZnO causes chemical reduction on the growing surface; which results in the reduction of the deposition rate, increase in the surface roughness, and decrease of the electrical resistivity. These effects produce larger characteristic variation with various deposition conditions in terms of surface morphology and optical/electrical properties compared to normal CVD deposited ZnO thin films. This versatile controllability of ultraviolet-assisted CVD can provide a larger processing options in the fabrication of nano-structured materials and flexible device applications.

매체순환식 가스연소기용 대량생산입자의 연료별 환원반응특성 (Reduction Characteristics of Mass Produced Particle for Chemical-Looping Combustor with Different Fuels)

  • 류호정;김경수;이승용;박영성;박문희
    • 한국수소및신에너지학회논문집
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    • 제19권4호
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    • pp.348-358
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    • 2008
  • Reduction reactivity and carbon deposition characteristics of mass produced oxygen carrier particle(OCN-650) have been investigated by using hydrogen, methane, syngas, and natural gas as fuels. For all fuels, the maximum conversion and oxygen transfer capacity increased as the temperature increase. The reduction rate and the oxygen transfer rate increased as the temperature increase for methane. However, those values showed maximum at 900$^{\circ}C$ for hydrogen, syngas, and natural gas. To explain consistently the change of maximum conversion, reduction rate, oxygen transfer capacity, oxygen transfer rate and degree of carbon deposition for different fuels, new parameters such as reactive carbon contents and require oxygen per input gas were adopted.

원환 크기의 변화에 따른 균등원통교각 주위의 세굴심 감소효과에 관한 실험적 연구 (An Experimental Study on Reduction Effect of Scour Depth arounding Uniform Cylindrical Pier with Various Size of Circular Collar)

  • 심우배;송재우
    • 한국방재학회 논문집
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    • 제3권2호
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    • pp.139-145
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    • 2003
  • 본 연구에서는 다양한 크기의 원환에 따른 균등원통교각 주위의 세굴심을 분석하여 세굴심 감소효과 및 원환의 적정 크기를 제시하였다. 이를 위하여 수리모형실험을 실시하였으며, 교각에 원환을 설치한 경우 원환을 하상 위보다 하상 아래에 설치하는 것이 더욱 효과적이었으며, 원환의 크기가 클수록 세굴심 감소 효과가 뚜렷하였다. 교각 직경에 대한 원환 직경의 비(W/D)가 2인 경우 약 67% 세굴심이 감소하였으며, 퇴적고는 약 70%정도 증가하였다. 세굴심 감소 효과, 세굴공 및 퇴적고의 분석 결과를 토대로 W/D=2인 원환을 최적 크기로 제안하였다.

Facile Preparation of Silver Nanoparticles and Application to Silver Coating Using Latent Reductant from a Silver Carbamate Complex

  • Kim, Kyung-A;Cha, Jae-Ryung;Gong, Myoung-Seon
    • Bulletin of the Korean Chemical Society
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    • 제34권2호
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    • pp.505-509
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    • 2013
  • A low temperature ($65^{\circ}C$) thermal deposition process was developed for depositing a silver coating on thermally sensitive polymeric substrates. This low temperature deposition was achieved by chemical reduction of a silver alkylcarbamate complex with latent reducing agent. The effects of acetol as a latent reducing agent for the silver 2-ethylhexylcarbamate (Ag-EHCB) complex and their blend solutions were investigated in terms of reducing mechanism, and the size and shape of silver nanoparticles (Ag-NPs) as a function of reduced temperature and time, and PVP stabilizer concentration were determined. Low temperature deposition was achieved by combining chemical reduction with thermal heating at $65^{\circ}C$. A range of polymer film, sheet and molding product was coated with silver at thicknesses of 100 nm. The effect of process parameters and heat treatment on the properties of silver coatings was investigated.

A Scheme on Reduction of NPP Liquid Effluent Activity

  • Kim, Wi-Soo;Yang, Yang-Hee;Kim, Hee-Guen
    • Nuclear Engineering and Technology
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    • 제34권1호
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    • pp.9-21
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    • 2002
  • Recently each domestic NPP has achieved zero release in liquid effluent activity. However, when looking back past experiences in world nuclear power operation, it is thought that another maximum activity reduction in the released liquid effluent just prior to falling it into environment, if possible, will bring a good effect in PA viewpoint. As the intent of applying the safety concept of diversity to conducting the above activity reduction measure, a scheme passing that effluent through the Deposition Bed just before discharging it into ocean environment was divised. Both Zeolite and "the mixed "Anthracite-sand" were derived as the main activity adsorption medium used in the Deposition Bed, and the schematic drawings of this Bed were presented.

Electrodeposition of SnO2-doped ZnO Films onto FTO Glass

  • Yoo, Hyeonseok;Park, Jiyoung;Kim, Yong-Tae;Kim, Sunkyu;Choi, Jinsub
    • Journal of Electrochemical Science and Technology
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    • 제10권1호
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    • pp.61-68
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    • 2019
  • Well aligned $SnO_2$-doped ZnO nanorods were prepared by single step or 2-step electrochemical depositions in a mixture solution of zinc nitrate hexahydrate, ammonium hydroxide solution and 0.1 M tin chloride pentahydrate. The morphologies of electrochemically deposited $SnO_2$-doped ZnO were transformed from plain (or network) structures at low reduction potential to needles on hills at high reduction potential. Well aligned ZnO was prepared at intermediate potential ranges. Reduction reagent and a high concentration of Zn precursor were required to fabricate $SnO_2$ doped ZnO nanorods. When compared to results obtained by single step electrochemical deposition, 2-step electrochemical deposition produced a much higher density of nanorods, which was ascribed to less potential being required for nucleation of nanorods by the second-step electrochemical deposition because the surface was activated in the first-step. Mechanisms of $SnO_2$ doped ZnO nanorods prepared at single step or 2-step was described in terms of applied potential ranges and mass-/charge- limited transfer.