• Title/Summary/Keyword: Degradation behavior

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Application of steel equivalent constitutive model for predicting seismic behavior of steel frame

  • Wang, Meng;Shi, Yongjiu;Wang, Yuanqing
    • Steel and Composite Structures
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    • v.19 no.5
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    • pp.1055-1075
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    • 2015
  • In order to investigate the accuracy and applicability of steel equivalent constitutive model, the calculated results were compared with typical tests of steel frames under static and dynamic loading patterns firstly. Secondly, four widely used models for time history analysis of steel frames were compared to discuss the applicability and efficiency of different methods, including shell element model, multi-scale model, equivalent constitutive model (ECM) and traditional beam element model (especially bilinear model). Four-story steel frame models of above-mentioned finite element methods were established. The structural deformation, failure modes and the computational efficiency of different models were compared. Finally, the equivalent constitutive model was applied in seismic incremental dynamic analysis of a ten-floor steel frame and compared with the cyclic hardening model without considering damage and degradation. Meanwhile, the effects of damage and degradation on the seismic performance of steel frame were discussed in depth. The analysis results showed that: damages would lead to larger deformations. Therefore, when the calculated results of steel structures subjected to rare earthquake without considering damage were close to the collapse limit, the actual story drift of structure might already exceed the limit, leading to a certain security risk. ECM could simulate the damage and degradation behaviors of steel structures more accurately, and improve the calculation accuracy of traditional beam element model with acceptable computational efficiency.

Comparison of Degradation Behaviors for Titanium-based Hard Coatings by Pulsed Laser Thermal Shock

  • Jeon, Seol;Lee, Heesoo
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.523-527
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    • 2013
  • Ti-based coatings following laser ablation were studied to compare degradation behaviors by thermomechanical stress. TiN, TiCN, and TiAlN coatings were degraded by a Nd:YAG pulsed laser with an increase in the laser pulses. A decrease in the hardness was identified as the pulses increased, and the hardness levels were in the order of TiAlN > TiCN > TiN. The TiN showed cracks on the surface, and cracks with pores formed along the cracks were observed in the TiCN. The dominant degradation behavior of the TiAlN was surface pore formation. EDS results revealed that diffusion of substrate atoms to the coating surface occurred in the TiN. Delamination occurred in the TiN and TiCN, while the TiAlN which has higher thermal stability than the TiN and TiCN maintained adhesion to the substrate. It was considered that the decrease in the hardness of the Ti-based hard coatings is attributed to surface cracking and the diffusion of substrate atoms.

Effect of tensile strain on $I_{c}$ degradation characteristics in Bi-2223 superconducting tapes under bending (Bi-2223 초전도테이프 임계전류의 굽힘하에서 인장변형률 특성)

  • 신형섭;오상수;하동우
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2003.10a
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    • pp.134-138
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    • 2003
  • The influences of mixed mode of bending-tension on the Ic degradation and their interaction on the strain effect were evaluated in this study. A test fixture which applies a mixed deformation mode of bending-tension to HTS tapes has been newly devised. When the strain induced in the tape due to the mixed deformation mode was expressed as a total tensile strain, the irreversible strain to the critical current degradation of Bi-2223 tapes increased when compared with the case of simple bending mode, and the value at both ends were larger than that at the central region of the bend part. The Ic degradation behavior at the region exceeding the irreversible strain showed quiet a rapid drop of the Ic when compared with the simple bending cases. As the applied bending strain increased namely as the diameter of mandrel adopted decreased, the apparent irreversible strain of Bi-2223 tapes increased However, the increment decreased as the mandrel diameter decreased. As a result, it could be found that the tension to be applied to the Bi-2223 tapes during cabling of HTS tapes should be smaller, as the mandrel diameter becomes smaller.

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Analysis of the ESD-Induced Degradation Behavior of Oxide VCSELs Using an Equivalent Circuit Model (ESD에 따른 산화형 VCSEL 열화 과정의 등가회로 모델을 이용한 분석)

  • Kim, Tae-Yong;Kim, Sang-Bae
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.45 no.3
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    • pp.6-21
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    • 2008
  • We have investigated the effect of the forward and reverse ESD pulse accumulation on the development of the oxide VCSEL's electrical and optical characteristics. The forward ESD-induced degradation is complicated, showing three degradation phases with increasing ESD voltage while the reverse ESD-induced degradation is divided by a sudden distinctive change in elecorl-optical characteristics. By comparing the measured L-I-V characteristics and their derivatives with the fitted characteristics using an equivalent circuit model as well as the large signal circuit model, the development of the oxide VCSEL's electro-optical characteristics under forward and reverse ESD conditions has been fully understood.

Protective Metal Oxide Coatings on Zinc-sulfide-based Phosphors and their Cathodoluminescence Properties

  • Oh, Sung-Il;Lee, Hyo-Sung;Kim, Kwang-Bok;Kang, Jun-Gill
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3723-3729
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    • 2010
  • We investigated the high-excitation voltage cathodoluminescence (CL) performance of blue light-emitting (ZnS:Ag,Al,Cl) and green light-emitting (ZnS:Cu,Al) phosphors coated with metal oxides ($SiO_2$, $Al_2O_3$, and MgO). Hydrolysis of the metal oxide precursors tetraethoxysilane, aluminum isopropoxide, and magnesium nitrate, with subsequent heat annealing at $400^{\circ}C$, produced $SiO_2$ nanoparticles, an $Al_2O_3$ thin film, and MgO scale-type film, respectively, on the surface of the phosphors. Effects of the phosphor surface coatings on CL intensities and aging behavior of the phosphors were assessed using an accelerating voltage of 12 kV. The MgO thick film coverage exhibited less reduction in initial CL intensity and was most effective in improving aging degradation. Phosphors treated with a low concentration of magnesium nitrate maintained their initial CL intensities without aging degradation for 2000 s. In contrast, the $SiO_2$ and the $Al_2O_3$ coverages were ineffective in improving aging degradation.

SP Creep Degradation of Anisotropic Materials by the Hydride (수소화물에 의한 이방성재료의 소형펀치(SP) 크리프 열화거동)

  • Oh, Dong-Joon
    • 대한공업교육학회지
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    • v.35 no.2
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    • pp.204-223
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    • 2010
  • The purpose of this study was to investigate the high temperature creep behavior of anisotropic Zr-2.4%Nb alloy which includes the hydride. To minimize the effect of the anisotropy and to achieve the bi-axial stress condition, SP creep test was performed using the Zr alloys which have the 50 ppm, 100 ppm and 200 ppm hydride. Each SP creep curve was obtained and compared. While the creep degradation of 50 ppm and 100 ppm hydride specimens was clearly found, the degradation of 200 ppm was not cleared. By the comparison of SP creep constant and stree exponent, this fact was confirmed. As the degradation of 50 ppm and 100 ppm hydride was processed, the SP creep constant was decreased and the stress exponet was increased. However, while the SP creep constant of 200 ppm hydride was decreased, the stree exponent was decreased. Finally, it was confirmed that the creep degradation of 200 ppm was not found. In conclusion, the hydride was the major parameter to control the hight temperature creep degradation of Zr alloy.

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Degradation of synthetic dye in water by solution plasma process

  • Panomsuwan, Gasidit;Morishita, Tetsunori;Kang, Jun;Rujiravanit, Ratana;Ueno, Tomonaga;Saito, Nagahiro
    • Journal of Advanced Marine Engineering and Technology
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    • v.40 no.10
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    • pp.888-893
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    • 2016
  • In this study, the solution plasma process was utilized with the aim of degrading synthetic dyes in water at atmospheric pressure. The experiments were conducted in a batch-type reactor consisting of a symmetric wire-wire electrode configuration with rhodamine B (RhB) as the target synthetic dye. The effects of the plasma treatment time and initial dye concentration on the RhB degradation were investigated by monitoring the change in absorbance of RhB solutions. The RhB solutions turned lighter in color and finally colorless with prolonged plasma treatment time, indicating the destruction of dye molecules. The RhB solutions were found to have degraded, following the first-order kinetic process. However, for high initial RhB concentrations, another kinetic process or factor seems to play a dominant role at the initial degradation stage. The fitted first-order rate constant decreased as the initial concentration increased. This result suggests that the degradation behavior and kinetic process of the RhB solution strongly depends on its initial concentration. The RhB degradation is considered to be due to a combination of factors, including the formation of chemically oxidative species, as well as the emission of intense UV radiation and high-energy electrons from the plasma. We believe that the solution plasma process may prove to be an effective and environment-friendly method for the degradation or remediation of synthetic dye in wastewater.

Preparation of Nanoflake Bi2MoO6 Photocatalyst Using CO(NH2)2 as Structure Orientation and Its Visible Light Degradation of Tetracycline Hydrochloride

  • Hu, Pengwei;Zheng, Dewen;Xian, Yuxi;Hu, Xianhai;Zhang, Qian;Wang, Shanyu;Li, Mingjun;Cheng, Congliang;Liu, Jin;Wang, Ping
    • Korean Journal of Materials Research
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    • v.31 no.6
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    • pp.325-330
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    • 2021
  • Bi2MoO6 (BMO) via the structure-directing role of CO(NH2)2 is successfully prepared via a facile solvothermal route. The structure, morphology, and photocatalytic performance of the nanoflake BMO are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), fluorescence spectrum analysis (PL), UV-vis spectroscopy (UV-vis) and electrochemical test. SEM images show that the size of nanoflake BMO is about 50 ~ 200 nm. PL and electrochemical analysis show that the nanoflake BMO has a lower recombination rate of photogenerated carriers than particle BMO. The photocatalytic degradation of tetracycline hydrochloride (TC) by nanoflake BMO under visible light is investigated. The results show that the nanoflake BMO-3 has the highest degradation efficiency under visible light, and the degradation efficiency reached 75 % within 120 min, attributed to the unique hierarchical structure, efficient carrier separation and sufficient free radicals to generate active center synergies. The photocatalytic reaction mechanism of TC degradation on the nanoflake BMO is proposed.

Synthesis and Properties of PET-PCT Copolyester I - Thermal Property and Degradation Behavior - (PET-PCT 공중합체의 합성과 물성 I - 열적성질과 분해거동 -)

  • 이원옥;김해영;백두현
    • Proceedings of the Korean Fiber Society Conference
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    • 2001.10a
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    • pp.351-354
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    • 2001
  • Poly(ethylene terephthalate) (PET)는 물리적, 기계적 성질이 우수한 엔지니어링 플라스틱의 하나로 섬유, 필름, 및 여러 가지 용도로 다양하게 사용되고 있다. PET는 DMT(dimethyl terephthalate) 또는 TPA(terephthalic acid)와 EG(ethylene glycol)를 축합 중합하여 제조한다. (중략)

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