• Title/Summary/Keyword: Defect State

Search Result 348, Processing Time 0.027 seconds

Reduction of floating Dross in the Zinc Bath (도금욕 부유드로스의 감소)

  • Chang, Seky
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 1999.05a
    • /
    • pp.97-97
    • /
    • 1999
  • Dross formation in the zinc bath is inevitable under any condition as long as coating process on steel strip continues. Thus, bath aluminum and temperature are precisely managed to suppress the increase of dross. Also, excessive dross for normal coating process is generally eliminated physically by bubbling and skimming. Total amount of dross in the bath can be sometimes high enough to cause coating defect. On the other hand, local concentration of dross can make coating defect even with satisfactory level of total amount of dross. Reduction of dross in the bath was attempted by using ceramic foam filter made of mainly alumina. Dross in molten zinc was almost reduced to the levels of solubility of iron and aluminum in molten zinc at $450~460^{\circ}C$. Their solubility levels were confirmed by thermodynamic calculations or DEAL program. Two kinds of filters were tested for dross reduction. One was #20 ppi, porous per inch, and the other #30 ppi filter. Both were effective in reducing the bath dross to the solubility levels at the static state. Bath iron was reduced by 24 wt% and 19 wt% with #20 filter, and by 35 wt% and 29 wt% with #30 filter for GI and GA pot, respectively. Also, ceramic foam filter did not make any harm to the zinc bath composition after filtering test.

  • PDF

Size and Crystal Structure Dependence of Photochromism of Nanocrystalline WO3 and MoO3 Prepared by Acid-Precipitation Method

  • Jun Young, Kwak;Young Hee, Jung;Yeong Il, Kim
    • Journal of the Korean Chemical Society
    • /
    • v.67 no.1
    • /
    • pp.33-41
    • /
    • 2023
  • Nanocrystallne WO3 and MoO3 with several different sizes and crystal structures were prepared by simple acid precipitation and subsequent heat treatment. The photochromic (PC) properties of these samples were comparatively investigated in powder state by monitoring diffuse reflectance spectral changes after bandgap irradiation. The PC effect of hexagonal WO3 and monoclinic WO3 strongly depended upon crystallite size rather than crystal structure. The smaller the crystallite size, the better the PC effect. However, orthorhombic WO·H2O and MoO3 having hexagonal and orthorhombic structures did not follow this trend. One consistent result for all WO3 and MoO3 samples is that the heat treatment in air, which changes crystallinity, whether it changes the crystal structure or only the crystallite size, reduces the PC effect. Since the thermal treatment reduces the surface oxygen defect sites, we believe that the PC effect of WO3 and MoO3 depends critically on the surface oxygen defect sites that serve as deep trap sites for photogenerated electrons and oxygen radical holes. We also found that the proton insertion claimed by double charge injection model is not critical for the PC effect.

Nexus based Quality Inspection Support Model for Defect Prevention of Architectural Finishing Works (하자예방정보 넥서스 기반 건축마감공사 품질점검 지원 모델)

  • Lee, Hye-Rin;Cho, Dong-Hyun;Park, Sang-Hun;Koo, Kyo-Jin
    • Korean Journal of Construction Engineering and Management
    • /
    • v.18 no.5
    • /
    • pp.59-67
    • /
    • 2017
  • At the completion of the construction, various finishing processes are concentrated. This imposes a burden on the on-site manager and imposes on experience based quality control, thereby causing deviations in the quality of construction depending on supervisor or worker's individual competence. In addition, the information related to quality control is frequently scattered in various types of documents such as specifications and drawings, and checkpoints are frequently omitted. It is necessary to provide a tool that can effectively provide the practitioner before or during the inspection work by systematically storing the information related to the defect prevention and linking them in a mutually referential state. This paper proposes an quality inspection support model that can systematically store necessary information on activity or room basis for the quality check of the apartment house finishing work. Establish a defect prevention information base and a information nexus by linking specifications, design standards, checklists, regulations, defect cases, and drawings to the finishing process and the rooms. Based on this, information registration and search interface are presented. It can contribute to securing a certain level of construction quality or more by suggesting a frame that can be utilized by linking various defects prevention information with the focus on closing activity and room.

Nonstoichiometric Effects in the Leakage Current and Electrical Properties of Bismuth Ferrite Ceramics

  • Woo, Jeong Wook;Baek, SeungBong;Song, Tae Kwon;Lee, Myang Hwan;Rahman, Jamil Ur;Kim, Won-Jeong;Sung, Yeon Soo;Kim, Myong-Ho;Lee, Soonil
    • Journal of the Korean Ceramic Society
    • /
    • v.54 no.4
    • /
    • pp.323-330
    • /
    • 2017
  • To understand the defect chemistry of multiferroic $BiFeO_3-based$ systems, we synthesized nonstoichiometric $Bi_{1+x}FeO_{3{\pm}{\delta}}$ ceramics by conventional solid-state reaction method and studied their structural, dielectric and high-temperature charge transport properties. Incorporation of an excess amount of $Bi_2O_3$ lowered the Bi deficiency in $BiFeO_3$. Polarization versus electric field (P-E) hysteresis loop and dielectric properties were found to be improved by the $Bi_2O_3$ addition. To better understand the defect effects on the multiferroic properties, the high temperature equilibrium electrical conductivity was measured under various oxygen partial pressures ($pO_2{^{\prime}}s$). The charge transport behavior was also examined through thermopower measurement. It was found that the oxygen vacancies contribute to high ionic conduction, showing $pO_2$ independency, and the electronic carrier is electron (n-type) in air and Ar gas atmospheres.

A Study on the Improvement for a Defect Diagnosis of Track Circuit on HSL (고속선 궤도회로 결함진단을 위한 개선방안 연구)

  • Park, Ki-Bum;Lee, Tae-Hoon;Lee, Gi-Chun
    • Proceedings of the KSR Conference
    • /
    • 2007.05a
    • /
    • pp.1656-1664
    • /
    • 2007
  • This paper introduces a study of improvement for a defect diagnosis of the UM71C track circuit using on HSL. The track circuit on HSL has long operation section. Therefore, when the worker maintain, many times and efforts are spent. So, periodically, we have operated a inspection car. However, we don't know exactly the state changed of the inspection data when track circuit has defect. Actually, We fixed a sample area within operation section on HSL and performed the simulations for short circuit current that is reflected characteristic impedance and propagation factor. We compared the measuring data with the result of the simulation. Using verified simulation program, we estimated inspection data as the malfunction number and the change of capacity of compensation capacitor. These study need to secure of the safety as the train operation. Also, It needs to make a criteria of analysis for the maintenance through comparison simulation data and inspection data.

  • PDF

Estimation of sewer deterioration by Weibull distribution function (와이블 분포함수를 이용한 하수관로 노후도 추정)

  • Kang, Byongjun;Yoo, Soonyu;Park, Kyoohong
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.34 no.4
    • /
    • pp.251-258
    • /
    • 2020
  • Sewer deterioration models are needed to forecast the remaining life expectancy of sewer networks by assessing their conditions. In this study, the serious defect (or condition state 3) occurrence probability, at which sewer rehabilitation program should be implemented, was evaluated using four probability distribution functions such as normal, lognormal, exponential, and Weibull distribution. A sample of 252 km of CCTV-inspected sewer pipe data in city Z was collected in the first place. Then the effective data (284 sewer sections of 8.15 km) with reliable information were extracted and classified into 3 groups considering the sub-catchment area, sewer material, and sewer pipe size. Anderson-Darling test was conducted to select the most fitted probability distribution of sewer defect occurrence as Weibull distribution. The shape parameters (β) and scale parameters (η) of Weibull distribution were estimated from the data set of 3 classified groups, including standard errors, 95% confidence intervals, and log-likelihood values. The plot of probability density function and cumulative distribution function were obtained using the estimated parameter values, which could be used to indicate the quantitative level of risk on occurrence of CS3. It was estimated that sewer data group 1, group 2, and group 3 has CS3 occurrence probability exceeding 50% at 13th-year, 11th-year, and 16th-year after the installation, respectively. For every data groups, the time exceeding the CS3 occurrence probability of 90% was also predicted to be 27th- to 30th-year after the installation.

Study on Surface-defect Passivation of InP System Quantum Dots by Photochemical Method (광화학적 방법을 통한 InP계 양자점 표면결함 부동태화 연구)

  • Kim, Doyeon;Park, Hyun-Su;Cho, Hye Mi;Kim, Bum-Sung;Kim, Woo-Byoung
    • Journal of Powder Materials
    • /
    • v.24 no.6
    • /
    • pp.489-493
    • /
    • 2017
  • In this study, the surface passivation process for InP-based quantum dots (QDs) is investigated. Surface coating is performed with poly(methylmethacrylate) (PMMA) and thioglycolic acid. The quantum yield (QY) of a PMMA-coated sample slightly increases by approximately 1.3% relative to that of the as-synthesized InP/ZnS QDs. The QYs of the uncoated and PMMA-coated samples drastically decrease after 16 days because of the high defect state density of the InP-based QDs. PMMA does not have a significant effect on the defect passivation. Thioglycolic acid is investigated in this study for the effective surface passivation of InP-based QDs. Surface passivation with thioglycolic acid is more effective than that with the PMMA coating, and the QY increases from 1.7% to 11.3%. ZnS formed on the surface of the InP QDs and S in thioglycolic acid show strong bonding property. Additionally, the QY is further increased up to 21.0% by the photochemical reaction. Electron-hole pairs are formed by light irradiation and lead to strong bonding between the inorganic and thioglycolic acid sulfur. The surface of the InP core QDs, which does not emit light, is passivated by the irradiated light and emits green light after the photochemical reaction.

스퍼터링 법으로 증착한 CdS 박막의 광전도도 특성 평가

  • Heo, Seong-Gi;Jang, Dong-Mi;Choe, Myeong-Sin;An, Jun-Gu;Seong, Nak-Jin;Yun, Sun-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2008.06a
    • /
    • pp.81-81
    • /
    • 2008
  • Applications of CdS films in this study are to exhibit a high conductivity when they are exposed at light with visible wavelength and sequentially to show a low conductivity in dark state. For this purpose, CdS films should have a high photosensitivity, still maintaining a high conductivity at a visible light. In this study, CdS films were prepared at room temperature on glass substrates by rf magnetron sputtering. In order to increase the photo-conductivity in visible light, various defect levels should be located within the CdS band gap. In order to nucleate the defect sites within the CdS band gap, CdS films were deposited on glass substrates at room temperature using various $H_2$/(Ar+$H_2$) flow ratios by an rf magnetron sputtering. Through the investigation of the structural and photoconductive properties of CdS films by an addition of hydrogen, the relationship between photo- and dark-resistance in CdS films was investigated in detail. 200-nm-thick CdS films for photoconductive sensor applications were prepared at various $H_2$/(Ar+$H_2$) flow ratios on glass substrates at room temperature by rf magnetron sputtering. Sulfur concentration in CdS films crystallized at room temperature with (002) preferred orientation depends directly on the hydrogen atmosphere and the surface roughness of the films gradually increases with increasing hydrogen atmosphere. Films deposited at 8% of $H_2$/(Ar+$H_2$) exhibit an abrupt decrease of dark- and photo-resistance, showing a low photo-sensitivity ($R_{dark}/R_{photo}$). Onthe other hand, films deposited at a hydrogen atmosphere of 42% exhibit a photo-sensitivity of $5\times10^3$, maintaining a photo-resistance of an approximately $2\times10^4\Omega$/square. The dark- and photo-resistance values of CdS films were related with a composition, surface roughness, and defect sites within the band gap.

  • PDF

Defects Evaluation at Lap Joint Friction Stir Welding by Lock-in Ultrasound Infrared Thermography (위상잠금 초음파 적외선열화상에 의한 겹치기 마찰교반용접부의 결함 평가)

  • Choi, Man-Yong;Park, Hee-Sang;Park, Jeong-Hak;Kang, Ki-Soo
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.30 no.2
    • /
    • pp.104-109
    • /
    • 2010
  • Lap joint friction stir welding(LFSW) is an relatively new solid state joining process. A6061-T6 aluminium alloy has gathered wide acceptance in the fabrication of light weight structures requiring a high strength to weight ratio and good corrosion resistance. Test methods used in this paper, lock-in thermography, a phase difference between the defect area and the healthy area indicates the qualitative location and size of the defect. In this paper, the defects detected from the thermal image of mechanical properties for weld were evaluated and compared by the lock-in infrared thermography technique.

Diagnosis and Monitoring of Socket Welded Pipe Damaged by Bending Fatigue Using Acoustic Emission Technique (음향방출법을 이용한 굽힘피로 손상된 소켓용접배관의 진단 및 감시)

  • Kim, C.S.;Oh, S.W.;Park, Ik-Keun
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • v.28 no.4
    • /
    • pp.323-330
    • /
    • 2008
  • High cycle bending fatigue of socket welded small bore pipe was characterized, and also the fatigue crack initiation of small bore pipe was monitored in situ by the acoustic emission (AE) technique. The STS 316L stainless steel specimens were prepared by gas tungsten arc welding (GTAW) process having the artificial defect (i.e., lack of penetration) and defect free at the root. The fatigue failure was occurred at the loc for high stress and root for relatively low stress. The crack initiation cycles ($N_i$) was defined to the abrupt increase in AE counts during the fatigue test, and then the cracks were observed by the radiographic test and electron microscope before and after the fatigue crack initiation cycles. The socket welded pipe damaged by bending fatigue was studied regarding the welding defect, failure mode, and crack initiation cycles for the diagnosis and monitoring.