• Title/Summary/Keyword: Decomposition behaviors

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The influence of perceived benefits and risks on the relational outcomes in strategically partnered firms (전략적 제휴 당사자 간의 이익 및 위험지각이 관계적 성과에 미치는 영향)

  • LIU, XINTONG;KIM, HAG-MIN
    • International Area Studies Review
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    • v.21 no.1
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    • pp.3-24
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    • 2017
  • The effects of strategic partnership can be positive or negative. This paper intends to explain why the partnership produces opposite results. This paper incorporates strategic behavioral direction and perceived values for relational performance. The conceptual model as well as empirical analysis was made and the results are as follows. First, this study uses bi-directional decomposition of two research constructs. The first construct of perceived values is classified into benefits and risks. Also, the behavioral directions are either active or passive behaviors. The critical path is found that the perceived benefits make significant effects on active behavioral direction which does on commitment. Another path is that the perceived risks make passive behavioral direction which results in opportunistic behaviors between strategically partnered firms.

Characteristics of CO2 Conversion Using Cobalt Ferrite Powders (코발트계 페라이트 분말을 이용한 이산화탄소 전환특성)

  • Park, Sungyoul
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1008-1014
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    • 2012
  • The amount of domestic carbon dioxide emissions is more than 600 million tons/year. The emitted $CO_2$ should be captured and stored, however, suitable storage sites have not been found yet. A lot of researches on the conversion of captured carbon dioxide to useful carbon source have been conducted. The purpose of this study is to convert stable carbon dioxide to useful resources using less energy. For this purpose reducing gas and metallic oxide (activator) are required. Hydrogen was used as reducing gas and cobalt ferrite was used as activator. Considering that activator has different physical properties depending on synthesis methods, activator was prepared by hydrothermal synthesis and solid method. Decomposition characteristics of carbon dioxide were investigated using synthesized powders. Temperature programmed reduction/oxidation (TPR/TPO) and thermogravimetric analyzer (TGA) device were used to observe the decomposition characteristics of carbon dioxide. Activator prepared by solid method with 5 and 10 wt% CoO content showed an excellent performance. In TGA experiments with samples prepared by the solid method, reduction by hydrogen was 29.0 wt% and oxidation by $CO_2$ was highest in 27.5 wt%. 95% of adsorbed $CO_2$ was decomposed with excellent oxidation-reduction behaviors.

Capillary Assembly of Silicon Nanowires Using the Removable Topographical Patterns

  • Hong, Juree;Lee, Seulah;Lee, Sanggeun;Seo, Jungmok;Lee, Taeyoon
    • Korean Journal of Materials Research
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    • v.24 no.10
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    • pp.509-514
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    • 2014
  • We demonstrate a simple and effective method to accurately position silicon nanowires (Si NWs) at desirable locations using drop-casting of Si NW inks; this process is suitable for applications in nanoelectronics or nanophotonics. Si NWs were assembled into a lithographically patterned sacrificial photoresist (PR) template by means of capillary interactions at the solution interface. In this process, we varied the type of solvent of the SiNW-containing solution to investigate different assembly behaviors of Si NWs in different solvents. It was found that the assembly of Si NWs was strongly dependent on the surface energy of the solvents, which leads to different evaporation modes of the Si NW solution. After Si NW assembly, the PR template was cleanly removed by thermal decomposition or chemical dissolution and the Si NWs were transferred onto the underlying substrate, preserving its position without any damage. This method enables the precise control necessary to produce highly integrated NW assemblies on all length scales since assembly template is easily fabricated with top-down lithography and removed in a simple process after bottom-up drop-casting of NWs.

System identification of a cable-stayed bridge using vibration responses measured by a wireless sensor network

  • Kim, Jeong-Tae;Ho, Duc-Duy;Nguyen, Khac-Duy;Hong, Dong-Soo;Shin, Sung Woo;Yun, Chung-Bang;Shinozuka, Masanobu
    • Smart Structures and Systems
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    • v.11 no.5
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    • pp.533-553
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    • 2013
  • In this paper, system identification of a cable-stayed bridge in Korea, the Hwamyung Bridge, is performed using vibration responses measured by a wireless sensor system. First, an acceleration based-wireless sensor system is employed for the structural health monitoring of the bridge, and wireless sensor nodes are deployed on a deck, a pylon and several selected cables. Second, modal parameters of the bridge are obtained both from measured vibration responses and finite element (FE) analysis. Frequency domain decomposition and stochastic subspace identification methods are used to obtain the modal parameters from the measured vibration responses. The FE model of the bridge is established using commercial FE software package. Third, structural properties of the bridge are updated using a modal sensitivity-based method. The updating work improves the accuracy of the FE model so that structural behaviors of the bridge can be represented better using the updated FE model. Finally, cable forces of the selected cables are also identified and compared with both design and lift-off test values.

Multi-level Optimization for Orthotropic Steel Deck Bridges (강바닥판교의 다단계 최적설계)

  • Cho, Hyo-Nam;Chung, Jee-Sung;Min, Daee-Hong;Lee, Kwang-Min
    • Proceedings of the Computational Structural Engineering Institute Conference
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    • 2000.04b
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    • pp.439-448
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    • 2000
  • A multi-level design synthesis (MLDA) algorithm for efficiently optimizing orthotropic steel deck bridges is proposed in the paper, because it is usually very difficult to optimize orthotropic steel deck bridges using a conventional single-level (CSL) algorithn since the bridges have a large number of members and show complex structural behaviors. In the proposed MLDS algorithms a coordination method is introduced to divide the bridges into main girders and orthotropic steel decks and decomposition method is also used to reduce the number of design variables of the decks for system level optimization. For efficient optimization of the bridges the MLDS algorithm incorporates the crucial approximation techliques such as constraints deletion and stress reanalysis. The constraint deletion technique for deflection is found to be very useful for the optimization problem of the bridges, since a deflection constraint is usually inactive in the design. Considering the complex system of the bridges, the proposed the efficient stress reanalysis technique may prove to be a very effective method, since it does not require expensive design sensitivity analyses. The applicability and robustness of the MLDS algorithm is demonstrated using various numerical examples and compared with other algorithm presently available so far.

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Chemistry of persulfates for the oxidation of organic contaminants in water

  • Lee, Changha;Kim, Hak-Hyeon;Park, Noh-Back
    • Membrane and Water Treatment
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    • v.9 no.6
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    • pp.405-419
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    • 2018
  • Persulfates (i.e., peroxymonosulfate and peroxydisulfate) are capable of oxidizing a wide range of organic compounds via direct reactions, as well as by indirect reactions by the radical intermediates. In aqueous solution, persulfates undergo self-decomposition, which is accelerated by thermal, photochemical and metal-catalyzed methods, which usually involve the generation of various radical species. The chemistry of persulfates has been studied since the early twentieth century. However, its environmental application has recently gained attention, as persulfates show promise in in situ chemical oxidation (ISCO) for soil and groundwater remediation. Persulfates are known to have both reactivity and persistence in the subsurface, which can provide advantages over other oxidants inclined toward either of the two properties. Besides the ISCO applications, recent studies have shown that the persulfate oxidation also has the potential for wastewater treatment and disinfection. This article reviews the chemistry regarding the hydrolysis, photolysis and catalysis of persulfates and the reactions of persulfates with organic compounds in aqueous solution. This article is intended to provide insight into interpreting the behaviors of the contaminant oxidation by persulfates, as well as developing new persulfate-based oxidation technologies.

Fabrication of Ni-AC/TiO2Composites and their Photocatalytic Activity for Degradation of Methylene Blue

  • Oh, Won-Chun;Son, Joo-Hee;Zhang, Kan;Meng, Ze-Da;Zhang, Feng-Jun;Chen, Ming-Liang
    • Journal of the Korean Ceramic Society
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    • v.46 no.1
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    • pp.1-9
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    • 2009
  • Activated carbon modified with nickel (Ni-AC) was employed the for preparation of Ni-activated carbon/$TiO_2$ (Ni-AC/$TiO_2$) composites. The $N_2$ adsorption data showed that the composites had a decreased surface area compared with pristine AC. This indicated blocking of the micropores on the surface of the AC, which was further supported by observation via SEM. XRD results showed that the Ni-AC/$TiO_2$ composite contained a mixed anatase and rutile phase while the untreated AC/$TiO_2$ contained only a typical single and clear anatase phase. EDX results showed the presence of C, O, and Ti with Ni peaks on the composites of Ni-AC/$TiO_2$. Subsequently, the photocatalytic effects on methylene blue (MB) were investigated. The improved decomposition of MB showed the combined effects of adsorptions and photo degradation. In particular, composites treated with Ni enhanced the photo degradation behaviors of MB.

Studies on Thermal Stability and Cure Behavior of Epoxy Resins using Electron-beam Curing Technique (전자선 경화를 이용한 에폭시 수지의 열안정성과 경화동력학에 관한 연구)

  • 박수진;허건영;이재락
    • Composites Research
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    • v.15 no.2
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    • pp.40-47
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    • 2002
  • The di-functional epoxy resins, i.e., diglycidylether of bisphenol A(DGEBA) and diglycidylethere of bisphenol F(DGEBF) were initiated by cationic catalyst, i.e., benzylquinoxalinium hexafluoroantimonate(BQH) using electron-beam(EB) technique. And the effect of structure of DGEBA and DGEBF on thermal stabilities and cure behaviors was investigated. According to the experimental results, the decomposed activation energy based on Horowitz-Metzger method was higher in the case of DGEBA, but intergral procedural decomposition temperature(IPDT) of DGEBA was lower than DGEBF. This could be interpreted in terms of high crosslink density resulted from hydroxyl bond of DGEBF backbone. It was confirmed in increasing the hydroxyl band at $7000\;cm^{-1}$ and $5235\;cm^{-1}$ using near-infrared spectroscopy(NIRS).

Ultra-low cycle fatigue tests of Class 1 H-shaped steel beams under cyclic pure bending

  • Zhao, Xianzhong;Tian, Yafeng;Jia, Liang-Jiu;Zhang, Tao
    • Steel and Composite Structures
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    • v.26 no.4
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    • pp.439-452
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    • 2018
  • This paper presents experimental and numerical study on buckling behaviors and hysteretic performance of Class 1 H-shaped steel beam subjected to cyclic pure bending within the scope of ultra-low cycle fatigue (ULCF). A loading device was designed to achieve the pure bending loading condition and 4 H-shaped specimens with a small width-to-thickness ratio were tested under 4 different loading histories. The emphasis of this work is on the impacts induced by local buckling and subsequent ductile fracture. The experimental and numerical results indicate that the specimen failure is mainly induced by elasto-plastic local buckling, and is closely correlated with the plastic straining history. Compared with monotonic loading, the elasto-plastic local buckling can occur at a much smaller displacement amplitude due to a number of preceding plastic reversals with relative small strain amplitudes, which is mainly correlated with decreasing tangent modulus of the material under cyclic straining. Ductile fracture is found to be a secondary factor leading to deterioration of the load-carrying capacity. In addition, a new ULCF life evaluation method is proposed for the specimens using the concept of energy decomposition, where the cumulative plastic energy is classified into two categories as isotropic hardening and kinematic hardening correlated. A linear correlation between the two energies is found and formulated, which compares well with the experimental results.

Micromechanical Computational Analysis for the Prediction of Failure Strength of Porous Composites (다공성 복합재의 파손 강도 예측을 위한 미시역학 전산 해석)

  • Yang, Dae Gyu;Shin, Eui Sup
    • Composites Research
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    • v.29 no.2
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    • pp.66-72
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    • 2016
  • Porosity in polymer matrix composites increases rapidly during thermochemical decomposition at high temperatures. The generation of pores reduces elastic moduli and failure strengths of composite materials, and gas pressures in internal pores influence thermomechanical behaviors. In this paper, micromechanical finite element analysis is carried out by using two-dimensional representative volume elements for unidirectionally fiber-reinforced composites with porous matrix. According to the state of the pores, effective elastic moduli, poroelastic parameters and failure strengths of the overall composites are investigated in detail. In particular, it is confirmed that the failure strengths in the transvers and through-thickness directions are predicted much more weakly than the strength of nonpored matrix, and decrease consistently as the porosity of matrix increases.