• Title/Summary/Keyword: Decomposition behaviors

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DECOMPOSITION OF SOME CENTRAL SEPARABLE ALGEBRAS

  • Park, Eun-Mi;Lee, Hei-Sook
    • Journal of the Korean Mathematical Society
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    • v.38 no.1
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    • pp.77-85
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    • 2001
  • If an Azumaya algebra A is a homomorphic image of a finite group ring RG where G is a direct product of subgroups then A can be decomposed into subalgebras A(sub)i which are homomorphic images of subgroup rings of RG. This result is extended to projective Schur algebras, and in this case behaviors of 2-cocycles will play major role. Moreover considering the situation that A is represented by Azumaya group ring RG, we study relationships between the representing groups for A and A(sub)i.

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Investigation of Al-Ni Alloys Deposition during Over-discharge Reaction of Na-NiCl2 Battery

  • Kim, Jeongsoo;Jo, Seung Hwan;Park, Dae-In;Bhavaraju, Sai;Kang, Sang Ook
    • Journal of the Korean Electrochemical Society
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    • v.19 no.3
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    • pp.57-62
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    • 2016
  • The over-discharging phenomena in sodium-nickel chloride batteries were investigated in relation to decomposition of molten salt electrolyte and consequent metal co-deposition. From XRD analysis, the material deposited on graphite cathode current collector was revealed to be by-product of molten salt electrolyte decomposition. In particular, the result showed that the Ni-Al alloys ($Al_3Ni_2$, $Ni_3Al$ and $Al_3Ni$) were electrochemically deposited on graphite current collectors in line with over-discharging behaviors. It is assumed that the $NiCl_2$ solubility in molten salt electrolytes leads to the co-deposition of Ni-Al alloys by increasing metal deposition potential above 1.6 V (vs. $Na/Na^+$). The cell tests have revealed that the composition of molten salt electrolytes modified by various additives makes a decisive influence on the over-discharging behaviors of the cells. It was revealed that NaOCN addition to molten salt electrolytes was advantageous to suppress over-discharge reactions by modifying the characteristics of molten salt electrolytes. NaOCN addition into molten salt electrolytes seems to suppress Ni solubility by maintaining basic melts. The cell using modified molten salt electrolyte with NaOCN (Cell D) showed relatively less cell degradation compared with other cells for long cycles.

Cure Behaviors and Thermal Stabilities of Epoxy Resins Initiated by Latent Thermal Catalyst (열잠재성 촉매 개시제를 이용한 에폭시 수지의 경화거동 및 열안정성)

  • 박수진;석수자;이재락;김영근
    • Composites Research
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    • v.17 no.5
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    • pp.47-53
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    • 2004
  • In this work, two thermal latent catalysts, i.e., N-benzylpyrazinium hexafluoroantimonate (BPH) and benzyl-2,5-dimethylpyrazinium hexafluoroantimonate (BDPH), were synthesized. The cure behaviors and thermal stabilities of diglycidylether of bisphenol A (DCEBA) epoxy resins initiated by 1 wt.% of the catalysts were investigated by DSC, NIR, TCA, and DMA Latent properties of the catalysts were examined by conversion of epoxy resins using NIR from $100^{\circ}C$ to $180^{\circ}C$ From the resultes of near-IR, DGEBA/BPH system showed higher conversion than that of DGEBA/BDPH system. The thermal stabilities of DGEBA/BDPH system based on the initial decomposition temperature (IDT) and integral procedural decomposition (IPDT) were relatively lower than those of DCEBA/BPH system. These could be attributed to the hindered structure of BDPH, resulting in decreasing the thermal stability in the DGEBA/BDPH system.

Syntheses and Thermal Behaviors of Rb(FOX-7)·H2O and Cs(FOX-7)·H2O

  • Luo, Jinan;Xu, Kangzhen;Wang, Min;Song, Jirong;Ren, Xiaolei;Chen, Yongshun;Zhao, Fengqi
    • Bulletin of the Korean Chemical Society
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    • v.31 no.10
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    • pp.2867-2872
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    • 2010
  • Two new energetic organic alkali metal salts, 1,1-diamino-2,2-dinitroethylene rubidium salt [Rb(FOX-7)${\cdot}H_2O$] and 1,1-diamino-2,2-dinitroethylene cesium salt [Cs(FOX-7)${\cdot}H_2O$], were synthesized by reacting of 1,1-diamino-2,2-dinitroethylene (FOX-7) and rubidium chloride or cesium chloride in alkali methanol aqueous solution, respectively. The thermal behaviors of Rb(FOX-7)${\cdot}H_2O$ and Cs(FOX-7)${\cdot}H_2O$ were studied with DSC and TG methods. The critical temperatures of thermal explosion of the two compounds are 216.22 and $223.73^{\circ}C$, respectively. Specific heat capacities of the two compounds were determined with a micro-DSC method, and the molar heat capacities are 217.46 and $199.47\;J\;mol^{-1}\;K^{-1}$ at 298.15 K, respectively. The adiabatic times-to-explosion were also calculated to be a certain value of 5.81 - 6.36 s for Rb(FOX-7)${\cdot}H_2O$, and 9.92 - 10.54 s for Cs(FOX-7)${\cdot}H_2O$. After FOX-7 becoming alkali metal salts, thermal decomposition temperatures of the compounds heighten with the rise of element period, but thermal decomposition processes become intense.

Large-Scale Structure of Leading-Edge Separation Bbubble with Local Forcing (국소교란이 가해지는 박리기포의 대형구조)

  • 김유익;성형진
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.4
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    • pp.1134-1147
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    • 1995
  • POD (proper orthogonal decomposition) is applied to turbulent leading-edge separation bubble to extract coherent structures. A two-dimensional leading-edge separation bubble is simulated by discrete-vortex method, where a time-dependent source forcing is incorporated. Based on the wealth of numerical data, POD is applied in a range of the forcing amplitude ( $A_{o}$ = 0, 0.5, 1.0 and 1.5) and forcing frequency (0 .leq. $f_{F}$H/ $U_{\infty}$.leq. 0.3). It is demonstrated that the structures of POD have noticeable changes with local forcings. In an effort to investigate the mechanism of decreasing reattachment length, dynamic behaviors of the expansion coefficients and contributions of the eigenfunctions of POD are scrutinized. As the forcing amplitude increases, the large-scale vortex structures are formed near the forcing amplitude increases, the large-scale vortex structures are formed near the separation point and the flow structures become more organized and more regular, accompanying with the reduction of reattachment length. By further inverstigation of POD global entropy, it is seen that the reattachment length is closely linked to the degree of organization of the flow structures.es.s.

Photocatalytic Behaviors of Transition Metal Ions Doped TiO2 Synthesized by Mechanical Alloying (기계적 합금화법을 이용한 전이금속 도핑에 따른 TiO2분말의 광촉매 특성)

  • Woo S.H.;Kim W.W.;Kim S.J.;Rhee C.K.
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.266-272
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    • 2005
  • Transition metal ions($Ni^{2+}$, $Cr^{3+}$ and $V^{5+}$) doped $TiO_2$ nanostructured powders were synthesized by mechanical alloying(MA) to shift the adsorption threshold into the visible light region. The synthesized powders were characterized by XRD, SEM, TEM and BET for structural analysis, UV-Vis and photoluminescence spectrum for the optical study. Also, photocatalytic abilities were evaluated by decomposition of 4-chlorophenol(4CP) under ultraviolet and visible light irradiations. Optical studies showed that the absorption wavelength of transition metal ions doped $TiO_2$ powders moved to visible light range, which was believed to be induced by the energy level change due to the doping. Among the prepared $TiO_2$ powders, $NiO^{2+}$ doped $TiO_2$ powders, showed excellent photooxidative ability in 4CP decomposition.

Thermal and Rheological Studies of Ricinodendron Heudelotii Wood for Its Pulp Production Potential

  • Ogunleye, Bolade Mercy;Fabiyi, James Sunday;Fuwape, Joseph A.
    • Journal of Forest and Environmental Science
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    • v.32 no.4
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    • pp.323-328
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    • 2016
  • Thermal stability and rheological behaviors of Ricinodendron heudelotii wood were investigated. Thermogravimetric analysis conducted at a heating rate of $10^{\circ}C/min$ from 20 to $600^{\circ}C$ in a nitrogen atmosphere indicated that there was no variation in the decomposition of the onset and final temperature for all the polymers. The thermal behaviours were investigated at a temperature range from 130 to $0^{\circ}C$ at $3^{\circ}C/min$, multi-frequencies of 0.1-10 Hz using dynamic mechanical analysis. N-methyl-2-pyrolidone saturated specimens were tested while submerged under the same solvent. Polymers decomposition pattern during thermogravimetric analysis are similar in the radial position of the wood. The glass transition temperature (Tg) of R. heudelotii is $45{\pm}1^{\circ}C$ at 0.1 Hz. The Tg differs from the innerwood to outerwood. The Tg showed that N-methyl-2-pyrolidone saturated R. heudelotii would require low energy consumption during chemi-thermomechanical pulping.

Vibration analysis of defected and pristine triangular single-layer graphene nanosheets

  • Mirakhory, M.;Khatibi, M.M.;Sadeghzadeh, S.
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1327-1337
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    • 2018
  • This paper investigates the vibration behavior of pristine and defected triangular graphene sheets; which has recently attracted the attention of researchers and compare these two types in natural frequencies and sensitivity. Here, the molecular dynamics method has been employed to establish a virtual laboratory for this purpose. After measuring the different parameters obtained by the molecular dynamics approach, these data have been analyzed by using the frequency domain decomposition (FDD) method, and the dominant frequencies and mode shapes of the system have been extracted. By analyzing the vibration behaviors of pristine triangular graphene sheets in four cases (right angle of 45-90-45 configuration, right angle of 60-90-30 configuration, equilateral triangle and isosceles triangle), it has been demonstrated that the natural frequencies of these sheets are higher than the natural frequency of a square sheet, with the same number of atoms, by a minimum of 7.6% and maximum of 26.6%. Therefore, for increasing the resonance range of sensors based on 2D materials, nonrectangular structures, and especially the triangular structure, can be considered as viable candidates. Although the pristine and defective equilateral triangular sheets have the highest values of resonance, the sensitivity of defective (45,90,45) triangular sheet is more than other configurations and then, defective (45,90,45) sheet is the worst choice for sensor applications.

OMA of model steel structure retrofitted with CFRP using earthquake simulator

  • Kasimzade, Azer A.;Tuhta, Sertac
    • Earthquakes and Structures
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    • v.12 no.6
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    • pp.689-697
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    • 2017
  • Nowadays, there are a great number of various structures that have been retrofitted by using different FRP Composites. Due to this, more researches need to be conducted to know more the characteristics of these structures, not only that but also a comparison among them before and after the retrofitting is needed. In this research, a model steel structure is tested using a bench-scale earthquake simulator on the shake table, using recorded micro tremor data, in order to get the dynamic behaviors. Beams of the model steel structure are then retrofitted by using CFRP composite, and then tested on the Quanser shake table by using the recorded micro tremor data. At this stage, it is needed to evaluate the dynamic behaviors of the retrofitted model steel structure. Various types of methods of OMA, such as EFDD, SSI, etc. are used to take action in the ambient responses. Having a purpose to learn more about the effects of FRP composite, experimental model analysis of both types (retrofitted and no-retrofitted models) is conducted to evaluate their dynamic behaviors. There is a provision of ambient excitation to the shake table by using recorded micro tremor ambient vibration data on ground level. Furthermore, the Enhanced Frequency Domain decomposition is used through output-only modal identification. At the end of this study, moderate correlation is obtained between mode shapes, periods and damping ratios. The aim of this research is to show and determine the effects of CFRP Composite implementation on structural responses of the model steel structure, in terms of changing its dynamical behaviors. The frequencies for model steel structure and the retrofitted model steel structure are shown to be 34.43% in average difference. Finally, it is shown that, in order to evaluate the period and rigidity of retrofitted structures, OMA might be used.

GFRP retrofitting effect on the dynamic characteristics of model steel structure

  • Tuhta, Sertac
    • Steel and Composite Structures
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    • v.28 no.2
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    • pp.223-231
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    • 2018
  • Nowadays, there are a great number of various structures that have been retrofitted by using different FRP Composites. Due to this, more researches need to be conducted to know more the characteristics of these structures, not only that but also a comparison among them before and after the retrofitting is needed. In this research, a model steel structure is tested using a bench-scale earthquake simulator on the shake table, using recorded micro tremor data, in order to get the dynamic behaviors. Columns of the model steel structure are then retrofitted by using GFRP composite, and then tested on the Quanser shake table by using the recorded micro tremor data. At this stage, it is needed to evaluate the dynamic behaviors of the retrofitted model steel structure. Various types of methods of OMA, such as EFDD, SSI, etc. are used to take action in the ambient responses. Having a purpose to learn more about the effects of GFRP composite, experimental model analysis of both types (retrofitted and no-retrofitted models) is conducted to evaluate their dynamic behaviors. There is a provision of ambient excitation to the shake table by using recorded micro tremor ambient vibration data on ground level. Furthermore, the Enhanced Frequency Domain Decomposition is used through output-only modal identification. At the end of this study, moderate correlation is obtained between mode shapes, periods and damping ratios. The aim of this research is to show and determine the effects of GFRP Composite implementation on structural responses of the model steel structure, in terms of changing its dynamical behaviors. The frequencies for model steel structure and the retrofitted model steel structure are shown to be 33.916% in average difference. Finally, it is shown that, in order to evaluate the period and rigidity of retrofitted structures, OMA might be used.