• Title/Summary/Keyword: Decomposition behaviors

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Behaviors of Decomposition products and Electrical treeing in XLPE According to Drying condition (XLPE의 가열건조에 따른 분해잔사와 전기 Tree 특성)

  • 한기만;김동욱;김영성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1994.05a
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    • pp.108-110
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    • 1994
  • Decomposition products by crosslinking reaction of PE using Dicumylperoxide(DCP) should influence on the electrical properties in XLPE. This paper studies on Behaviors of Decomposition products and Electrical Treeing ding to Drying condition. We used the Gas Chromatography for Decomposition Gases analysis FT-IR for investigating the behaviors of Decomposition products remained in XLPE Break Down Voltage Tester for Electrical Treeing measurement.

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Characteristics of DCP Decomposition Products in XLPE According to Drying condition (XLPE의 가열 건조에 따른 DCP 분해잔사 특성)

  • Hahn, K.M.;Kim, D.W.;Oh, M.W.;Kweon, H.S.;Kim, Y.S.
    • Proceedings of the KIEE Conference
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    • 1993.07b
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    • pp.1236-1238
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    • 1993
  • This paper studies on the behaviors of decomposition products from DCP according to various drying conditions of DCP. The decomposition products formed during crosslinking reaction have an harmful influence on XLPE. Especially explosive gases like methane which is one of decomposition products may cause explosion accident. We used the Gas Chromatography and Gas sensor for decomposition gases analysis, FT-IR for investigating the behaviors of decomposition products remained in XLPE.

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A study of decomposition of applied eccentric load for multi-cell trapezoidal box girders (편심하중이 작용하는 제형 다실박스거더에서의 거동분리연구)

  • Kim Seung Jun;Han Keum Ho;Park Nam hoi;Kang Young Jong
    • Proceedings of the KSR Conference
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    • 2005.11a
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    • pp.229-234
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    • 2005
  • Thin-walled multicell box girders subjected to an eccentric load can he produced the three global behaviors of flexure, torsion, and distortion. Specially in railway bridges subjected to much eccentric load, it is quite important to evaluate influences of torsion and distortion. But it is very difficult to evaluate each influences of major behaviors numerically. If we can decompose an eccentric load P into flexural, torsional, and distortional forces. we can execute quantitative analysis each influences of major behaviors. Decomposition of Applied Load for Thin-walled Rectangular multi-cell box girders is reserched by Park, Nam- Hoi(Development of a multicell Box Beam Element Including Distortional Degrees of Freedom, 2003). But researches about trapezoidal multi-cell section is insufficient. So, this paper deals with multi-cell trapezoidal box girders. An expanded method, which is based on the force decomposition method for a single cell box girder given by Nakai and Yoo, is developed herein to decompose eccentric load Pinto flexural, torsional, and distortional forces. Derive formulas by decomposition of eccentric load is verified by 3D shell-modelling numerical analysis.

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Effects of Ar-Plasma Treatment in Alkali-Decomposition of Poly(ethylene terephthalate)

  • Seo, Eun-Deock
    • Macromolecular Research
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    • v.11 no.5
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    • pp.387-392
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    • 2003
  • The ablation effects of Ar-plasma treatment and alkali-decomposition behavior in NaOH solution of polyethylene terephthalate (PET) film were investigated. The modifications were evaluated by analysis of atomic force microscopy topographical changes, and by the measurement of decomposition yield in conjunction with heats of formation and electron densities of acyl carbon calculated by Parameterization Method 3 method. It has shown that the alkali-decomposition is hampered by plasma treatment and its decomposition yield is closely related with plasma treatment conditions such as exposure time to plasma. Plasma-treated PET films exhibited lower decomposition yield, compared to that of virgin PET. Increasing plasma exposure time contributes positively to decrease the decomposition yield. It has also shown that the topography of PET surface was affected by the base-promoted hydrolysis as well as Ar-plasma treatments. These behaviors are attributed to the decreased nucleophilicity of acyl carbon damaged by the ablation of Ar-plasma.

A Study of Torsional and Distortional Analysis of Thin-walled Multicell Box Girder Using Shell Elements (쉘요소를 이용한 박판다실박스거더에서의 비틀림과 뒤틀림 해석기법 연구)

  • Kim, Seung-Jun;Park, Jong-Sub;Kim, Sung-Nam;Kang, Young-Jong
    • 한국방재학회:학술대회논문집
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    • 2007.02a
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    • pp.71-74
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    • 2007
  • Thin-walled multicell box girders subjected to an eccentric load can be produced the three global behaviors of flexure, torsion, and distortion. But it is very difficult to evaluate each influences of major behaviors numerically. If we can decompose an eccentric load P into flexural, torsional, and distortional forces, we can execute quantitative analysis each influences of major behaviors. Decomposition of Applied Load for Thin-walled Rectangular multi-cell box girders is researched by Park, Nam-Hoi(Development of a multicell Box Beam Element Including Distortional Degrees of Freedom, 2003). But researches about thin-walled trapezoidal multi-cell section is insufficient. So, this paper deals with decomposition process and independent analysis method of multi-cell box girders include trapezoidal section.

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Behaviors and Process Analyses of Spark Sintering for Powders Having a Low Sinterability

  • Matsugi, K.
    • Journal of Powder Materials
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    • v.19 no.2
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    • pp.127-133
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    • 2012
  • The sintering behaviors and process parameters of some compounds (carbides, oxides, sulfides, borides) were investigated experimentally. These compounds were successfully consolidated and showed high densities. Some unique phenomena such as retardation of grain growth, suppression of thermal decomposition and maintenance of initial non-equilibrium phases, were observed by the proper control of process in spark sintering.

Thermal Properties and Water Sorption Behaviors of Epoxy and Bismaleimide Composites

  • Seo, Jong-Chul;Jang, Won-Bong;Han, Hak-Soo
    • Macromolecular Research
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    • v.15 no.1
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    • pp.10-16
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    • 2007
  • In this work, we prepared epoxy/BMI composites by using N,N'-bismaleimide-4,4'-diphenylmethane (BMI), epoxy resin (diglycidyl ether of bisphenol-A (DGEBA)), and 4,4'-diamino diphenyl methane (DDM). The thermal properties and water sorption behaviors of the epoxy and BMI composites were investigated. For the epoxy/BMI composites, the glass transition and decomposition temperatures both increased with increasing BMI addition, which indicates the effect of BMI addition on improved thermal stability. The water sorption behaviors were gravi-metrically measured as a function of humidity, temperature, and composition. The diffusion coefficient and water uptake decreased and the activation energy for water diffusion increased with increasing BMI content, indicating that the water sorption in epoxy resin, which causes reliability problems in electronic devices, can be diminished by BMI addition. The water sorption behaviors in the epoxy/BMI composites were interpreted in terms of their chemical and morphological structures.

Influence of Maleic Anhydride Grafted onto Polyethylene on Pyrolysis Behaviors

  • Chung, Yu Yeon;Choi, Sung-Seen
    • Elastomers and Composites
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    • v.51 no.3
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    • pp.233-239
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    • 2016
  • Polyethylene (PE) and maleic anhydride-grafted PE (PE-g-MAH) were pyrolyzed, and their pyrolysis products were analyzed using gas chromatography/mass spectrometry (GC/MS) to investigate the influence of MAH grafted onto PE on pyrolysis behaviors. Major pyrolysis products of PE and PE-g-MAH were n-alkanes, 1-alkenes, ${\alpha},{\omega}$-alkadienes, and aromatic compounds. 1-Alkenes were more formed than n-alkanes, ${\alpha},{\omega}$-alkadienes, and aromatic compounds. Butadiene was more produced from PE than PE-g-MAH, whereas toluene and ethyl benzene were more generated from PE-g-MAH than PE. Difference in the pyrolysis behaviors between PE and PE-g-MAH were explained by initial decomposition of MAH moiety.

Arrhenius Parameters for the Thermal Decomposition of Trichloroethylene

  • Kim, Hack-Jin;Choo, Kwang-Yul
    • Bulletin of the Korean Chemical Society
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    • v.4 no.5
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    • pp.203-208
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    • 1983
  • A thermal decomposition of trichloroethylene was studied in the temperature range of 440-$460^{\circ}C$ by using the conventional static system. In order to investigate the pressure dependence of reaction and to eliminate free radical process, propylene was used as the bath gas. The pressure range investigated was 10∼900 Torr. The decomposition was the unimolecular dehydrochlorination and the reaction products were hydrogen chloride and dichloroacetylene. Results were interpreted in terms of the Ric-Ramsperger-Kassel-Marcus (RRKM) unimolecular rate theory and the Arrhenius parameters were determined from fall-off behaviors. The Arrhenius parameters are found to be log $A=13.8{\pm}0.2sec^{-1}$ and E = $56.6{\pm}0.7$ kcal/mole, respectively.

A Study on the Ignition Behaviors of Textiles according to Permeation Amount of Oils and Aeration (유지류의 침윤량과 공기주입에 따른 면화류의 발화거동에 관한 연구)

  • 오치훈;이창우;김정환;현성호
    • Fire Science and Engineering
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    • v.14 no.1
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    • pp.8-12
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    • 2000
  • We had investigated thermal and ignition behaviors of textiles. Decomposition of textiles with temperature was investigated using a DSC and the weight loss according to temperature using a TGA in order to find the thermal hazard of textiles, and the ignition behaviors of textiles according to species and permeation amount of oil. In addition, ignition behaviors of those permeated into oils indicating different iodine value and of those with arid without air in reaction vessel of measuring equipment were studied with constant temperature method among ignition temperature measuring methods. As results, the range of decomposition temperature of synthetic fiber was slightly broad compared with that of natural fiber, pure cotton. Besides, the initiation temperature of heat generation of both samples riced in the case of no air injection in the reaction vessel. On the other hand, in the case of air injection that was lowered according to the increase in permeative amount of oils and fats and decreased quickly as sample was permeated into drying oil.

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