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http://dx.doi.org/10.7473/EC.2016.51.3.233

Influence of Maleic Anhydride Grafted onto Polyethylene on Pyrolysis Behaviors  

Chung, Yu Yeon (Department of Chemistry, Sejong University)
Choi, Sung-Seen (Department of Chemistry, Sejong University)
Publication Information
Elastomers and Composites / v.51, no.3, 2016 , pp. 233-239 More about this Journal
Abstract
Polyethylene (PE) and maleic anhydride-grafted PE (PE-g-MAH) were pyrolyzed, and their pyrolysis products were analyzed using gas chromatography/mass spectrometry (GC/MS) to investigate the influence of MAH grafted onto PE on pyrolysis behaviors. Major pyrolysis products of PE and PE-g-MAH were n-alkanes, 1-alkenes, ${\alpha},{\omega}$-alkadienes, and aromatic compounds. 1-Alkenes were more formed than n-alkanes, ${\alpha},{\omega}$-alkadienes, and aromatic compounds. Butadiene was more produced from PE than PE-g-MAH, whereas toluene and ethyl benzene were more generated from PE-g-MAH than PE. Difference in the pyrolysis behaviors between PE and PE-g-MAH were explained by initial decomposition of MAH moiety.
Keywords
PE; PE-g-MAH; pyrolysis behaviors; mechanism;
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Times Cited By KSCI : 2  (Citation Analysis)
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