• Title/Summary/Keyword: Decolorization

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Microwave Assisted Synthesis of SnS Decorated Graphene Nanocomposite with Efficient Visible-Light-Driven Photocatalytic Applications

  • Wang, Jun-Hui;Zeng, Yi-Kai;Gu, Hao;Zhu, Lei;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.12
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    • pp.641-649
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    • 2020
  • A facile microwave assisted solvothermal process is designed for fabricating SnS nanoparticles decorated on graphene nanosheet, which used as visible light driven photocatalyst. Some typical characterization techniques such as XRD, FT-IR, SEM with EDX analysis, and TEM and BET analysis are used to analyse the physical characteristics of as-prepared samples. Spherical SnS nanoparticles are uniformly dispersed on the surface of graphene nanosheet due to ammonia, which can prevent the aggregation of graphene oxide. Meanwhile, microwave radiation provides fast energy that promotes the formation of spherical SnS nanoparticles within a short time. The visible light photocatalytic activity of as-prepared SnS-GR nanocomposites is analysed through photodegradation efficiency of methylene blue with high concentration. According to the higher photocatalytic property, the as-prepared SnS-GR nanocomposites can be expected to be an efficient visible light driven photocatalyst. After five cycles for decolorization, the rate decreases from 87 % to 78 % (about 9 %). It is obvious that the photocatalytic activity of SnS-GR nanocomposite has good repeatability.

Pilot Study on the Advanced Treatment of Combined Wastewater with Sewage as a Cosubstrate (가정하수를 cosubstrate로서 사용한 하수-염색폐수-공장폐수의 합병 고도처리 pilot plant 연구)

  • Kim, Mee-Kyung;Seo, Sang-Jun;Rhew, Doug-Hee;Jung, Dong-Il
    • Journal of Korean Society on Water Environment
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    • v.25 no.2
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    • pp.227-234
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    • 2009
  • In this research, a retrofitting process, which consists of a pretreatment system (coagulation) for dye wastewater combined with a biological nutrient system (MLE process using media), for a sewage treatment plant that has to treat dye wastewater efficiently with domestic wastewater were developed and a pilot plant was operated for verifying adoptability and performance of the developed advanced process for dye wastewater. From the results of the pilot plant operation, BOD 52.9%, $COD_{Cr}$ 55.9%, and color 71.3% were removed in pretreatment of coagulation process and the biodegradability of dye wastewater was improved to $0.32{\sim}0.59BOD/COD_{Cr}$ of the coagulated wastewater from $0.29{\sim}0.43BOD/COD_{Cr}$ of the raw dye wastewater. The final effluent concentrations were BOD of 8 mg/L, $COD_{Cr}$ of 43 mg/L, $COD_{Mn}$ of 18 mg/L, T-N of 8 mg/L, and T-P of 1.3 mg/L, respectively. Color was removed from 1655 to 468 unit by coagulation and then to 123 unit by MLE process. The HPLC analysis of aromatic amines in wastewater showed that decolorization was achieved by cometabolism while aromatic amines were produced by cleavage of azo bonds under anaerobic conditions and these products were removed in an aerobic tank subsequently. Nitrification rates of attached and suspended microorganisms were evaluated comparatively and the acclimating conditions of bacteria on media were validated by the scanning electron microscope.

Degradation of Three Aromatic Dyes by White Rot Fungi and the Production of Ligninolytic Enzymes

  • Jayasinghe, Chandana;Imtiaj, Ahmed;Lee, Geon-Woo;Im, Kyung-Hoan;Hur, Hyun;Lee, Min-Woong;Yang, Hee-Sun;Lee, Tae-Soo
    • Mycobiology
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    • v.36 no.2
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    • pp.114-120
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    • 2008
  • This study was conducted to evaluate the degradation of aromatic dyes and the production of ligninolytic enzymes by 10 white rot fungi. The results of this study revealed that Pycnoporus cinnabarinus, Pleurotus pulmonarius, Ganoderma lucidum, Trametes suaveolens, Stereum ostrea and Fomes fomentarius have the ability to efficiently degrade congo red on solid media. However, malachite green inhibited the mycelial growth of these organisms. Therefore, they did not effectively decolorize malachite green on solid media. However, P. cinnabarinus and P. pulmonarius were able to effectively decolorize malachite green on solid media. T. suaveolens and F. rosea decolorized methylene blue more effectively than any of the other fungi evaluated in this study. In liquid culture, G. lucidum, P. cinnabarinus, Naematoloma fasciculare and Pycnoporus coccineus were found to have a greater ability to decolorize congo red. In addition, P. cinnabarinus, G lucidum and T. suaveolens decolorized methylene blue in liquid media more effectively than any of the other organisms evaluated in this study. Only F. fomentarius was able to decolorize malachite green in liquid media, and its ability to do so was limited. To investigate the production of ligninolytic enzymes in media containing aromatic compounds, fungi were cultured in naphthalene supple mented liquid media. P. coccineus, Coriolus versicolor and P. cinnabarinus were found to produce a large amount of laccase when grown in medium that contained napthalene.

Biochemical and Molecular Characterization of Laccases from Wild Mushrooms

  • Ro, Hyeon-Su
    • 한국균학회소식:학술대회논문집
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    • 2014.05a
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    • pp.43-43
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    • 2014
  • White rot fungi have been useful source of enzymes for the degradation of environmental pollutants including polycyclic aromatic hydrocarbons (PAHs) and synthetic dyes. PAHs are widespread organic compounds present in fossil fuels and are routinely generated by incomplete fuel combustion. PAHs are some of the major toxic pollutants of water and soil environments. Synthetic dyes are major water-pollutants, which are toxic to organisms in water environments and interfere photosynthesis of water plants. Removal of PAHs and synthetic dyes has been of interests in the environmental science especially in the environmental microbiology. Mushrooms are fungal groups that function as primary degraders of wood polyphenolic lignin. The ligninolytic enzymes produced by mushroom, including manganese peroxidase, lignin peroxidase, and laccase, mediate the oxidative degradation of lignin. The catalytic power of these enzymes in the degradation of aromatic ring compounds has been sought for the degradation of various organic compounds. In this project, we have screened 60 wild mushroom strains for their degradation activity against two representative PAHs, naphthalene and anthracene, and five aromatic dyes, including alizarin red S, crystal violet, malachite green, methylene blue, rose bengal. The degradation of PAHs was measured by GC while the decolorization of dyes was measured by both UV spectrophotometer and HPLC. As results, 9 wild mushroom strains showed high activity in degradation of PAHs and textile dyes. We also describe the secretive enzyme activities, the transcription levels, and cloning of target genes. In conjunction with this, activities of degradative enzymes, including laccase, lignin peroxidase, and Mn peroxidase, were measured in the liquid medium in the presence of PAHs and dyes. Our results showed that the laccase activity was directed correlated with the degradation, indicating that the main enzyme acts on PAHs and dyes is the laccase. The laccase activity was further simulated by the addition of $Cu^{2+}$ ion. Detailed studies of the enzyme system should be sought for future applications.

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The Characteristics of High Ozone Concentration.Yield Multi-discharge Type Ozonizer for Water Environment Improvement (수질환경개선용 고농도.고수율 다중방전형 오존발생기의 특성)

  • Song, Hyun-Jig;Rahman, M. F.;Kim, Yeong-Hun;Kim, Geun-Young;Park, Won-Zoo;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.13 no.2
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    • pp.71-79
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    • 1999
  • In this paper, high concentration.yield trulti-discharge type ozonizer( MDO ) of new discharge type using superposed silent discharge was designed and manufactured MDO can be consisted with 3 kind of superposed silent discharge type ozmizer( SDO ) in accordance with power supply method that suwlying power, which has $180[^{\circ}]$ phase difference, to 3 electrodes and amble gap. At the rroment, discharge characteristics and ozone generation characteristics of each SDO were investigated in accordance with quantity of suwlied gas, the number of SDO, and the shapes of each SDO. In result, ozone generatioo characteristics of 17185[ppm] and 783[g/kWh] were obtained, and when ozone of 17185[ppm] was in contact with dyeing water waste, decolorization characteristics was excellent, so it confinred that MDO could be used as water environment improvement facility.cility.

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Grain Quality of Imported Steamed-Rice (수입 찐쌀의 품질 특성)

  • Chun, A-Reum;Jeong, Eung-Gi;Choi, Yoon-Hee;Kim, Kee-Jong;Lee, Jeom-Sig
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.51 no.spc1
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    • pp.7-11
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    • 2006
  • The grain quality of imported steamed-rice was investigated to improve the competitiveness of domestic .ice (Oryza sativa L.) in low price market. Eight samples of imported steamed-rice were collected during 2004 and 2005, and they were examined in appearances, physicochemical, pasting, cooking qualities and palatability. In the appearance of grain, there were many cracks, which were easily classified, on the surface of steamed-rice. And they had high protein contents, low moisture contents and very low glossiness. We could certain that there was often decolorization process after boiling according to the wide range of whiteness in steamed-rice samples. Amylograms and thermo-grams of the steamed-rice represented that they were at-ready gelatinized. Thus, we could concluded that the steamed-rice absorbed water with meager endothermic reaction and eluted more soluble solid with many breaks of the grain than milled rice during cooking process. From the sensory preference evaluation, the steamed-rice had the lowest scores among milled rice, long stored rice, and broken rice samples on all evaluation items.

Comparative Study of Antioxidant abilities on Prunus yedoensis and Betula platyphylla var. japonica (산화적 손상에 대한 화피(樺皮)의 효능 - 왕벚나무와 자작나무 수피의 항산화능 비교 평가-)

  • Hong, Sang Cheol;Jun, Ji Ae;Kim, Dong Hee
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.27 no.4
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    • pp.391-399
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    • 2013
  • The aim of the present study was to investigate the antioxidant efficacies between extracts of Prunus yedoensis(PY) and Betulae platyphyllae var. japonica(BP). HPLC pattern was different between barks and extract solvents. Content of total phenolic compound was the highest in ethanol extract of BP(382.201 mg/g ext.) and its content was 1.9 times higher than that from the water extract of PY. Total antioxidant efficacy also was the highest in ethanol extract of BP (292 copper reducing equivalents). Nitric oxide scavenging activity was almost 70% in ethanol extract of BP treated 200 ug/ml and it was higher than positive control(ascorbic acid). DPPH radical scavenging ability was up by 80% in all samples. ABTS cation decolorization from each barks was activated over 85% in all samples at 100 ug/ml concentration, especially, the activity was the highest (94.4%) in ethanol extract of BP. Hydrogen peroxide scavenging activities were also highest (45%) in ethanol extract of BP at 200 ug/ml concentration and were as high as positive control. Stimulation of the macrophages RAW 264.7 cells with lipopolysaccharide (LPS) increased intracellular ROS levels and ethanol extract of BP at 200 ug/ml concentration reduced ROS levels up to 41 %. The results indicated that the barks of PY and BP has potent antioxidant activities and ethanol extract of BP of them has the highest antioxidant activities.

Biological Activities of Scolopendrid Pharmacopuncture (수순(水醇)추출법으로 조제된 오공 약침액의 생리활성 효과)

  • Kim, Sung-Chul;Seo, Geun-Young;Lee, Sung-Won;Park, Sung-Joo;Kim, Jae-Hyo;Ahn, Seong-Hun;Hwang, Sung-Yeoun
    • Journal of Pharmacopuncture
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    • v.13 no.3
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    • pp.5-13
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    • 2010
  • Reactive Oxygen Species(ROS) are continuously produced at a high rate as a by-product of aerobic metabolism. Since tissue damage by free radical increases with age, the reactive oxygen species(ROS) such as hydrogen peroxide($H_2O_2$), nitric oxide(NO). Several lines of evidence provided that ROS appears to cause to develop aging-related various diseases such as cancer, arthritis, cardiovascular disease. Our reserch objective was to examine the in vitro biological activity of Scolopendrid Pharmacopuncture, including the total poly-phenol content, DPPH radical scavenging, ABTS radical scavenging, Superoxide dismutase(SOD)-like activity, Nitrite scavenging ability. The total poly-phenol contents of Scolopendrid Pharmacopuncture was 35.859mg/L. Elctron donation ability on DPPH was 36.82%. The 2,2'-azinobis-3-ehtlbezothiazoline-6-sulfonic acid radical decolorization (ABTS) was 84.7%. The superoxide dismutase (SOD)-like activities of Scolopendrid Pharmacopuncture was 44.33%. The nitrite scavenging effects were pH dependent, and were highest at pH 1.5(45.2%) and lowest at pH 6.0(11.3%). We conclude that Scolopendrid Pharmacopuncture may be useful as potential sources of antioxidant.

Characteristics and Antioxidative Activity of Volatile Compounds in Heated Garlic (Allium sativum)

  • Woo, Koan-Sik;Yoon, Hyang-Sik;Lee, Youn-Ri;Lee, Jun-Soo;Kim, Dae-Joong;Hong, Jin-Tae;Jeong, Heon-Sang
    • Food Science and Biotechnology
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    • v.16 no.5
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    • pp.822-827
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    • 2007
  • The aroma characteristics and antioxidative activity of volatile compounds in heat-treated garlic (Allium sativum L.) were evaluated. The garlic was heated to various temperatures (100, 110, 120, and $130^{\circ}C$) for different lengths of time (1, 2, and 3 hr). The volatile compounds of heated garlic were extracted by simultaneous steam distillation extraction (SDE). Aroma compound profiles were analyzed by gas chromatography/mass spectrometry (GC/MS) and antioxidative activity was measured by 2,2-diphenyl-2-picrylhydrazyl (DPPH) assay and 2,2'-azino-bis-(3-ethylbenzothiazoline-6-sulfonic acid (ABTS) cation decolorization assay. The major aroma compounds were sulfur compounds such as dimethyl disulfide, 2-propen-1-ol, methyl-2-propenyl disulfide, dimethyl trisulfide, diallyl disulfide, methyl-2-propenyl trisulfide, and di-2-propenyl trisulfide. DPPH radical scavenging activity (EDA, %) and the ascorbic acid equivalent antioxidant activity (AEAC) of volatile compounds in heated garlic increased significantly with the increase of temperature and time (p<0.001). The EDA (%) and AEAC of raw garlic were 26.8%/10 mg garlic and 39.05 mg ascorbic acid equivalent per g sample. After heat treatment, the highest values were 40.50%/10 mg garlic for EDA (%) and 46.43 mg ascorbic acid equivalent per g sample for ABTS.

Study on Coloring and Aging Pattern of Bongchae used for Conservation Treatment of Paper Cultural Properties (지류문화재의 보채에 쓰이는 봉채의 채색 및 열화 양상 연구)

  • Song, Jung Won;Kim, Myoung Nam;Lee, Jang Jon
    • Journal of Conservation Science
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    • v.35 no.5
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    • pp.416-429
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    • 2019
  • Bongchae is primarily employed for toning, which is the last step in the conservation treatment of paper's cultural properties. The objective of this study is to identify the coloring patterns of four types of Bongchae(Bonram, Gamboge, Yeonji, and Daeja) and determine the associated color change patterns through accelerated aging experiments. By examining the coloring patterns, it is observed that Yeonji, Bonram, and Daeja are painted as particles, whereas Gamboge indicates a close state of coating. Results obtained from X-ray diffraction analysis of Bongchae indicate that the presence of quartz, calcite, and pyrophyllite can be equally detected in Bonram, Yeonji, and Daeja. Additionally, the presence of goethite is also detected in Daeja. Gamboge becomes discolored from yellow to orange color during wet thermal aging, and Gamboge and Yeonji become decolorized during UV irradiation aging. Hence, cultural properties of paper colored with Gamboge can be predicted to become discolored to orange color by alkalis and can be darkened by UV rays because the decolorization of Gamboge and Yeonji occurs preferentially.