• Bulletin of the Korean Chemical Society
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• 제34권12호
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• pp.3709-3714
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• 2013

Based on the Debye-H$\ddot{u}$ckel equation, a semi-empirical equation for activity coefficients was derived through empirical and theoretical trial and error efforts. The obtained equation included two parameters: the proportional factor and the effective radius of an ionic sphere. These parameters were used in the empirical and regression parameter fitting of the calculated values to the experimental results. The activity coefficients calculated from the equation agreed with the data. Transforming to a semi-empirical form, the equation was expressed with one parameter, the ion radius. The ion radius, ${\alpha}$, was divided into three parameters, ${\alpha}_{cation}$, ${\alpha}_{anion}$ and ${\delta}_{cation}$, representing parameters for the cation, anion and combination, respectively. The advantage of this equation is the ability to propose a semi-empirical equation that can easily determine the activity coefficient with just one parameter, so the equation is expected to be used more widely in actual industry applications.

• 한국재료학회지
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• 제13권5호
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• pp.285-291
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• 2003

The nanosized silver and gold particles are prepared by ERC method in which metal vapors with high temperature is rapidly quenched by coolants such as liquid nitrogen or liquid argon. In order to monitor the crystal structural changes on the internal and the surface of the nanosized noble metal particles, lattice parameter, internal strain and Debye-Waller factor are investigated, and the calculation of X-ray diffraction scattering intensity is performed. The lattice parameters of silver and gold particles agree with those of bulk materials, and crystal internal strain of the metal particles is not changed by rapid cooling. The Debye-Waller factor of gold particles is increased with decreasing particle size because of the surface softening phenomenon of nanosized particles, but the crystal structural change on the surface of the particles is not detected from the comparison the calculated X-ray diffraction profile with the experimental profile on gold particles with the particle size of 4 nm.

• 한국수소및신에너지학회논문집
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• 제6권1호
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• pp.17-22
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• 1995

Thermally evaporated Pd films on substrate were hydrogenated upto 1 bar of hydrogen gas at room temperature. Temperature dependence hange of electrical resistivity on Pd films is examined in the thickness range between $60{\AA}$ and $990{\AA}$. Resistivity of Pd is fitted well with Bloch-$Gr{\ddot{u}}neisen$ formula. Debye temperatures of Pd films are about 254 K, which are 20 K lower than that of bulk Pd. Debye temperature is not sensitive to film thickness change. Temperature of substrate during evaporation changes temperature dependence of resistivity of films much. Optical phonon contribution increases with decreasing temperature of PdHx.

• 에너지공학
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• 제24권2호
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• pp.55-58
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• 2015

The mesoporous metal organic framework structure Fe-BTC was successfully synthesized by hydrothermal process with noticeable yield. The synthesis operation was conducted at intermediate temperature and for shortened operation time as compared to conventional procedures. This process approach with reduced operating temperature and shortened operation time may open an opportunity window towards process economy with reduction in energy consumption. A simple mathematical approach of diffraction indexing using X-ray diffraction patterns of synthesized powder was employed to confirm its crystalline nature and to investigate its high temperature stability. The crystallite size was calculated by using Debye-Scherrer equation.

• Nuclear Engineering and Technology
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• 제46권6호
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• pp.863-868
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• 2014

The evaluation of thermal properties of actinide oxide fuels is a problem of high importance for the development of new generation reactors. In the present study, an expression obtained for n-dimensional Debye functions is used to derive a simple analytical expression for the specific heat capacity of nuclear fuels. To test the validity and reliability of this expression, the analytical expression is applied to $UO_2$, $NpO_2$, $ThO_2$, and $PuO_2$. It is seen that the formula was in agreement with the experimental and theoretical results reported in the literature.

• Journal of the Optical Society of Korea
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• 제20권3호
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• pp.431-434
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• 2016

Tris-HCl buffer solution is extensively used in biochemistry and molecular biology to maintain a stable pH for biomolecules such as nucleic acids and proteins. Here we report on the high-precision THz dielectric spectroscopy of a 10 mM Tris-HCl buffer. Using a double Debye model, including conductivity of ionic species, we measured the complex dielectric functions of Tris-HCl buffer. The fast relaxation time of water molecules in Tris-HCl buffer is ~20% longer than that in pure water while the slow relaxation time changes little. This means that the reorientation dynamics of Tris-HCl buffer with such a low Tris concentration is quite different from that of pure water.

• 대한수학회보
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• 제57권6호
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• pp.1393-1408
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• 2020

In this paper we mainly study existence and regularity of mild solutions to the parabolic-elliptic system of drift-diffusion type with small initial data in Fourier-Besov spaces. To be more detailed, we will explain that global-in-time mild solutions are well-posed and Gevrey regular by means of multilinear singular integrals and Fourier localization argument. Furthermore, we can get time decay rate estimate of mild solutions in Fourier-Besov spaces.

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2008년도 Asian Magnetics Conference
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• pp.265.1-265.1
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• 2008

• 한국자기학회:학술대회 개요집
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• 한국자기학회 2008년도 Asian Magnetics Conference
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• pp.204.1-204.1
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• 2008

• 한국전자파학회논문지
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• 제17권7호
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• pp.684-693
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• 2006

이 논문에서는 광대역 펄스 전자파에 노출된 인체 두부를 생체 조직의 분산 특성을 고려하여 SA (Specific Absorption) 분포를 해석하였다. 생체 조직의 분산 특성은 4 차 Cole-Cole 모델로 특성지어지는 데, 현재 4 차 Cole-Cole 모델을 FDTD에 정확히 적용시킬 수 있는 분산 알고리즘이 없다. 따라서 본 논문에서는 FDTD 알고리즘에 적용 가능한 생체 조직의 분산 특성을 l 차 Cole-Cole 모텔과 3 차 Debye 모델을 적용한 FDTD 분산 알고리즘을 이용하여 SA를 해석하였다. 각 모델의 타당성을 먼저 조사한 후, 조직의 분산이 SA 분포에 미치는 영향을 연구하였다.